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특허 상세정보

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Pressure swing adsorption process for the production of hydrogen

특허상세정보
국가/구분 United States(US) Patent 등록
국제특허분류(IPC7판) B01D-053/047    B01D-053/26   
미국특허분류(USC) 95/096; 95/117; 95/130; 95/139; 95/140; 95/143
출원번호 US-0373749 (1999-08-13)
발명자 / 주소
  • Mohamed Safdar Allie Baksh
  • Mark William Ackley
대리인 / 주소
    Robert J. Follett
인용정보 피인용 횟수 : 62  인용 특허 : 23
초록
▼

This invention provides a pressure swing adsorption process for purifying a synthesis gas stream containing from 60 to 90 mole % hydrogen and impurities such as CO2, CH4, N2, and CO. The PSA process of the invention further provides a method of adsorbing substantially all of the nitrogen and other contaminants from the feed gas stream; wherein the feed stream is passed at superatmospheric pressure through a plurality of adsorbent beds and each adsorbent bed contains at least a CaX, LiA, LiX or calcium containing mixed cation zeolite having a SiO2/Al2O3 m...

대표
청구항
▼

1. A pressure swing adsorption (PSA) process for purifying a feed stream containing at least one of H2O, N2, CO2, CH4 and CO, and more than 50 mole % hydrogen, which comprises passing the feed stream at a pressure above atmospheric pressure through a multilayer adsorbent bed, wherein at least one of said H2O, CO2, CH4 and CO is adsorbed from the gas stream prior to passing the stream through a layer of a synthetic zeolite adsorbent having a SiO2/Al2O3 ratio within the range of 2.0-2.5 and selected from the group consisting of CaX, LiX and VSA6 adsorbent ...

이 특허에 인용된 특허 (23)

  1. Morris Michael,GBX ; Robinson Stuart Charles Frank,GBX ; Lander David Frederick,GBX, Adsorbents for separating nitrogen from a feed gas.
  2. Notaro Frank (Amherst NY) Mullhaupt Joseph Timothy (Williamsville NY) Leavitt Frederick Wells (Amherst NY) Ackley Mark William (East Aurora NY), Adsorption process and system using multilayer adsorbent beds.
  3. Notaro Frank ; Mullhaupt Joseph Timothy ; Leavitt Frederick Wells ; Ackley Mark William, Adsorption process and system using multilayer adsorbent beds.
  4. Scharpf Eric W. (Emmaus PA) Kumar Ravi (Allentown PA), Adsorption process to recover hydrogen from low pressure feeds.
  5. Fitch Frank R. (Bedminster NJ) Blow Martin (Basking Ridge NJ) Ojo Adeola F. (Chatham NJ), Adsorptive separation of nitrogen from other gases.
  6. Schmidt William P. (Allentown PA) Kumar Ravi (Allentown PA) Abel Alan D. (Allentown PA), Adsorptive separation utilizing multiple adsorption beds.
  7. Chao Chien-Chung (Millwood NY), Air separation process.
  8. Golden Timothy C. (Allentown PA) Kumar Ravi (Allentown PA) Kratz Wilbur C. (Macungie PA), Hydrogen purification.
  9. Sircar Shivaji ; Waldron William Emil ; Anand Madhu ; Rao Madhukar Bhaskara, Hydrogen recovery by pressure swing adsorption integrated with adsorbent membranes.
  10. Bomard Olivier,FRX ; Jutard Jerome,FRX ; Moreau Serge,FRX ; Vigor Xavier,FRX, Method for purifying hydrogen based gas mixture using a lithium- exchanged X zeolite.
  11. Chao Chien C. (Millwood NY) Sherman John D. (Chappagua NY) Mullhaupt Joseph T. (Willimasville NY) Bolinger Cornelius M. (Sugarland TX), Mixed ion-exchanged zeolites and processes for the use thereof in gas separations.
  12. Chao Chien C. (Millwood NY) Sherman John D. (Chappaqua NY) Mullhaupt Joseph T. (Williamsville NY) Bolinger Cornelius M. (Sugarland TX), Mixed ion-exchanged zeolites and processes for the use thereof in gas separations.
  13. Watson Charles F. (Orefield PA) Whitley Roger D. (Allentown PA) Meyer Michael L. (Fogelsville PA), Multiple zeolite adsorbent layers in oxygen separation.
  14. Baksh Mohamed Safdar Allie ; Notaro Frank, PSA process and system.
  15. Coe Charles G. (Macungie PA) Kuznicki Steven M. (Allentown PA), Polyvalent ion exchanged adsorbent for air separation.
  16. Kratz Wilbur C. (Macungie PA) Sircar Shivaji (Wescosville PA), Pressure swing adsorption process for a medical oxygen generator for home use.
  17. Fuentes Francois (Paris FRX), Process for restarting a receptacle for purifying hydrogen by adsorption, and its use in the treatment of certain gases.
  18. Chao Chien C. (Millwood NY), Process for separating nitrogen from mixtures thereof with less polar substances.
  19. Reiss Gerhard,DEX ; Puppe Lothar,DEX ; Hees Bruno,DEX, Process for the adsorption of nitrogen from gas mixtures by means of pressure swing adsorption with zeolites.
  20. Labasque Jacques,FRX ; Moreau Serge,FRX ; Rouge Dominique,FRX, Process for the separation of gas mixtures containing oxygen and nitrogen.
  21. Vigor Xavier (Paris FRX) Petit Pierre (Buc FRX) Moreau Serge (Velizy Villacoublay FRX) Sardan Bernard (Plaisir FRX), Process for the separation of nitrogen from a gaseous mixture by adsorption.
  22. Ojo Adeola F. (Chatham NJ) Fitch Frank R. (Bedminster NY) Blow Martin (Basking Ridge NJ), Removal of carbon dioxide from gas streams.
  23. Sircar Shivaji (Allentown PA), Separation of multicomponent gas mixtures.

이 특허를 인용한 특허 (62)

  1. Golden, Timothy Christopher; Weist, Edward Landis, Activated carbon as sole absorbent in rapid cycle hydrogen PSA.
  2. Rege, Salil Uday; Ackley, Mark William; Nowobilski, Jeffert John, Adsorbents for pressure swing adsorption systems and methods of use therefor.
  3. Golden,Timothy Christopher; Weist, Jr.,Edward Landis; Novosat,Paul Anthony, Adsorbents for rapid cycle pressure swing adsorption processes.
  4. Belanger, Paul W.; Baksh, Mohamed Safdar Allie; Chandra, Preeti; Rosinski, Andrew C., Adsorption control method and controller.
  5. Golden, Timothy Christopher; Weist, Jr., Edward Landis; Hufton, Jeffrey Raymond; Novosat, Paul Anthony, Adsorption process to recover hydrogen from feed gas mixtures having low hydrogen concentration.
  6. Cote, Adrien P.; Heuft, Matthew A., Application of porous structured organic films for gas separation.
  7. Cote, Adrien P.; Heuft, Matthew A., Application of porous structured organic films for gas storage.
  8. Moreau,Serge; Renou,Elise; Szulman,Claire, Barium-and calcium-based zeolitic adsorbent for gas purification in particular air.
  9. Côté, Adrien P.; Heuft, Matthew A., Capped structured organic film compositions.
  10. Heuft, Matthew A.; Cote, Adrien Pierre, Composite structured organic films.
  11. Baksh,Mohamed Safdar Allie; Rosinski,Andrew C., Continuous feed three-bed pressure swing adsorption system.
  12. Heuft, Matthew A.; Cote, Adrien, Electronic devices comprising structured organic films.
  13. Ackley, Mark William; Smolarek, James, Enhanced rate PSA process.
  14. Cote, Adrien P.; Heuft, Matthew A., Fluorinated structured organic film compositions.
  15. Cote, Adrien P.; Heuft, Matthew A., Fluorinated structured organic film photoreceptor layers.
  16. Vella, Sarah J.; Heuft, Matthew A.; Cote, Adrien P.; Gerroir, Paul, Fluorinated structured organic film photoreceptor layers containing fluorinated secondary components.
  17. Lee,Junbae; Cho,Seong Moon; Lee,Don Hee, Gas concentration method and its apparatus.
  18. Cote, Adrien P.; Heuft, Matthew A., High mobility periodic structured organic films.
  19. Heuft, Matthew A.; Cote, Adrien P.; Hu, Nan-Xing; Mahabadi, Hadi K., Imaging devices comprising structured organic films.
  20. Cote, Adrien P.; Heuft, Matthew A., Imaging members comprising capped structured organic film compositions.
  21. Cote, Adrien P.; Heuft, Matthew A., Imaging members comprising structured organic films.
  22. Heuft, Matthew A.; Chow, Eugene M.; Cote, Adrien P.; Hu, Nan-Xing, Imaging members for ink-based digital printing comprising structured organic films.
  23. Baksh,Mohamed Safdar Allie; Manning,Michael S.; Rosinski,Andrew C.; Smolarek,James; Stewart,Alan Barnard; Neu,Bernard Thomas, Indexing rotary dual valve for pressure swing adsorption systems.
  24. Heuft, Matthew A.; Cote, Adrien P.; Chretien, Michelle N., Ink jet faceplate coatings comprising structured organic films.
  25. Baksh, Mohamed S. A.; Simo, Marian, Large scale pressure swing adsorption systems having process cycles operating in normal and turndown modes.
  26. Golden, Timothy Christopher; Weist, Jr., Edward Landis, Layered adsorption zone for hydrogen production swing adsorption.
  27. Wigglesworth, Anthony J.; Vella, Sarah J.; Dooley, Brynn M.; Cote, Adrien P., Melt formulation process for preparing structured organic films.
  28. Keusenkothen, Paul F.; Hershkowitz, Frank; Mohr, Gary D., Method and apparatus for converting hydrocarbons into olefins.
  29. Keusenkothen, Paul F.; Hershkowitz, Frank; Davis, Jason D.; Mohr, Gary D., Method and apparatus for managing hydrogen content through the conversion of hydrocarbons into olefins.
  30. Wright, Andrew David; Hufton, Jeffrey Raymond; White, Vincent; Golden, Timothy Christopher, Method and apparatus for producing power and hydrogen.
  31. Hirano, Shigeru; Harada, Atsushi, Method for purifying hydrogen-based gas mixture.
  32. Le Bec, Remi, Method for purifying hydrogen-based gas mixtures using a calcium x-zeolite.
  33. Son, Geon Seog, Method for removing soot of combustion exhaust gas.
  34. Sumida, Toshihiko; Sasano, Hiroaki; Miyake, Masanori, Method for separating hydrogen gas.
  35. Hirano, Shigeru; Harada, Atsushi, Method of adsorptive separation of carbon dioxide.
  36. Celik, Cem E.; Ackley, Mark William; Nowobilski, Jeffert John; Rege, Salil Uday, Methods and systems for mixing material.
  37. Celik, Cem E.; Ackley, Mark William; Nowobilski, Jeffert John; Rege, Salil Uday, Methods and systems for mixing materials.
  38. Heuft, Matthew A.; Cote, Adrien P., Methods for preparing structured organic film micro-features by inkjet printing.
  39. Cote, Adrien Pierre; Heuft, Matthew A.; Skinner, David M.; Cowdery-Corvan, Jane Robinson, Mixed solvent process for preparing structured organic films.
  40. Cote, Adrien P.; Heuft, Matthew A., Periodic structured organic films.
  41. Cote, Adrien P.; Heuft, Matthew A., Porous structured organic film compositions.
  42. Cho, Soon Haeng; Bhat, Sodankoor Garadi Thirumaleshwara; Han, Sang Sup; Park, Jong Ho; Kim, Jong Nam; Jung, Heon, Pressure swing adsorption apparatus and method for hydrogen purification using the same.
  43. Baksh,Mohamed Safdar Allie; Rosinski,Andrew, Pressure swing adsorption process for large capacity oxygen production.
  44. Baksh, Mohamed Safdar Allie; Ackley, Mark William; Notaro, Frank, Process and adsorbent for hydrogen purification.
  45. Kumar, Ravi, Process and apparatus to recover high purity carbon dioxide.
  46. Heuft, Matthew A.; Cote, Adrien Pierre, Process for preparing structured organic films (SOFS) via a pre-SOF.
  47. Heuft, Matthew A.; Cote, Adrien Pierre; McGuire, Gregory M.; Gagnon, Yvan, Process for preparing structured organic films (SOFs) via a pre-SOF.
  48. Filippi, Ermanno; Baratto, Francesco; Panza, Sergio; Ostuni, Raffaele, Process for producing ammonia synthesis gas.
  49. Shah, Minish Mahendra, Recovery of carbon dioxide from flue gas.
  50. Heuft, Matthew A.; Cote, Adrien P.; McGuire, Greg; Hu, Nan-Xing; Gagnon, Yvan, Robust photoreceptor surface layer.
  51. Baksh, Mohamed S. A.; Simo, Marian, Six bed pressure swing adsorption process operating in normal and turndown modes.
  52. Baksh, Mohamed S. A.; Simo, Marian, Six bed pressure swing adsorption process operating in normal and turndown modes.
  53. White, Donald H.; Weber, William P.; McGill, Brian G., Sorption systems with naturally occurring zeolite, and methods.
  54. Heuft, Matthew A.; Cote, Adrien Pierre; De Jong, Kathy L., Structured organic films.
  55. Heuft, Matthew A.; Cote, Adrien Pierre; De Jong, Kathy L., Structured organic films.
  56. Cote, Adrien Pierre; Heuft, Matthew A., Structured organic films having an added functionality.
  57. Jewell, Richard Peter Glynn; Gaucher, Melissa; Denomme, Louis, Synthesis gas separation and reforming process.
  58. Vanzandt, Kyle; Gordon, Bryan, System and method for regenerating adsorber bed for drying compressed humidified hydrogen.
  59. Son, Geon Seog, System for removing soot of combustion exhaust gas.
  60. Baksh, Mohamed S. A.; Simo, Marian, Ten bed pressure swing adsorption process operating in normal and turndown modes.
  61. Sechrist, Paul A., Vessel, system, and process for minimizing unequal flow distribution.
  62. Grandmougin, Marie-Therese; Mayolet, Francis; Rouet, Jacques, Zeolite adsorbents, method for obtaining them and their use for removing carbonates from a gas stream.

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