[특허]Catalyst system

[미국특허] Catalyst system 원문보기

IPC분류정보
국가/구분	United States(US) Patent 등록
국제특허분류(IPC7판)	B01J-023/00 B01J-023/40 B01J-023/42 B01J-023/60 B01J-023/72
출원번호	US-0604703 (2000-06-23)
발명자 / 주소	Spivack, James Lawrence Whisenhunt, Jr., Donald Wayne Cawse, James Norman Soloveichik, Grigorii Lev
출원인 / 주소	General Electric Company
대리인 / 주소	Caruso, Andrew J.Johnson, Noreen C.
인용정보	피인용 횟수 : 5 인용 특허 : 42

초록 ▼

A catalyst system for economically producing aromatic carbonates from aromatic hydroxy compounds. In one embodiment, the present invention provides a carbonylation catalyst system that includes a catalytic amount of an inorganic co-catalyst containing ytterbium. In various alternative embodiments, the carbonylation catalyst system can include an effective amount of a palladium source and an effective amount of a halide composition. Further alternative embodiments can include catalytic amounts of various inorganic co-catalyst combinations.

대표청구항 ▼

1. A carbonylation catalyst system, said system comprising a palladium constituent and an inorganic co-catalyst comprising a ytterbium compound, said ytterbium compound comprising a beta-diketone ligand. 2. The carbonylation catalyst system of claim 1, wherein the inorganic co-catalyst further comprises copper. 3. The carbonylation catalyst system of claim 1, wherein the inorganic co-catalyst further comprises copper and titanium. 4. The carbonylation catalyst system of claim 1, wherein the inorganic co-catalyst further comprises copper and iron. 5. The carbonylation catalyst system of claim 1, wherein the inorganic co-catalyst further comprises cerium. 6. The carbonylation catalyst system of claim 1, wherein the inorganic co-catalyst further comprises manganese. 7. The carbonylation catalyst system of claim 1, wherein the inorganic co-catalyst further comprises europium. 8. The carbonylation catalyst system of claim 1, wherein the inorganic co-catalyst further comprises nickel. 9. The carbonylation catalyst system of claim 1, wherein the inorganic co-catalyst further comprises bismuth. 10. The carbonylation catalyst system of claim 1, wherein the inorganic co-catalyst further comprises zinc. 11. The carbonylation catalyst system of claim 1, wherein the inorganic co-catalyst further comprises iron. 12. The carbonylation catalyst system of claim 1, wherein the inorganic co-catalyst further comprises cobalt. 13. The carbonylation catalyst system of claim 1, wherein the inorganic co-catalyst further comprises iridium. 14. The carbonylation catalyst system of claim 1, wherein the inorganic co-catalyst further comprises ruthenium. 15. The carbonylation catalyst system of claim 1, wherein the inorganic co-catalyst further comprises rhodium. 16. The carbonylation catalyst system of claim 1, wherein the inorganic co-catalyst further comprises chromium. 17. The carbonylation catalyst system of claim 1, wherein the palladium constituent is a Pd(II) salt or complex. 18. The carbonylation catalyst system of claim 1, wherein the palladium constituent is supported Pd. 19. The carbonylation catalyst system of claim 18, wherein the palladium constituent is palladium on carbon. 20. The carbonylation catalyst system of claim 1, further comprising a halide composition. 21. The carbonylation catalyst system of claim 1, further comprising tetraethylammonium bromide. 22. The carbonylation catalyst system of claim 1, further comprising hexaethylguanidinium bromide. 23. The carbonylation catalyst system of claim 1, wherein the ytterbium compound comprising a beta-diketone ligand is derived from an acetyl acetonate. 24. The carbonylation catalyst system of claim 1, further comprising an organic co-catalyst selected from a phosphine, quinone, terpyridine, phenanthroline, quinoline and isoquinoline.

이 특허에 인용된 특허 (42) 인용/피인용 타임라인 분석

Wegman Richard W. (South Charleston WV), Carbonylation reaction and catalyst therefor.
상세보기
James Lawrence Spivack ; Donald Wayne Whisenhunt ; James Norman Cawse ; Bruce Fletcher Johnson ; Grigorii Lev Soloveichik ; John Yaw Ofori ; Eric James Pressman, Catalyst system for producing aromatic carbonates.
상세보기
Grasselli Robert K. (Chagrin Falls OH) Miller Arthur F. (Lyndhurst OH) Hardman Harley F. (Lyndhurst OH), Catalysts and process for the ammoxidation of olefins.
상세보기
James Lawrence Spivack ; Donald Wayne Whisenhunt, Jr. ; James Norman Cawse ; Bruce Fletcher Johnson ; Grigorii Lev Soloveichik ; John Yaw Ofori ; Eric James Pressman, Catalysts system for producing aromatic carbonates.
상세보기
Chalk Alan J. (Kinnelon NJ), Catalytic aromatic carbonate process.
상세보기
King Stephen W. (Scott Depot WV), Catalytic processes for the preparation triethylenediamine.
상세보기
Tustin Gerald Charles ; Zoeller Joseph Robert ; Browning ; Jr. Horace Lawrence ; Singleton Andy Hugh, Heterogeneous vapor phase carbonylation process.
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Zoeller Joseph Robert ; Singleton Andy Hugh ; Tustin Gerald Charles ; Carver Donald Lee, Iridium catalyst for carbonylation of lower aliphatic alcohols.
상세보기
Markovitz Mark (Schenectady NY), Low viscosity epoxy resin compositions.
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Spivack James Lawrence ; Whisenhunt Donald Wayne ; Cawse James Norman ; Johnson Bruce Fletcher ; Soloveichik Grigorii Lev ; Ofori John Yaw ; Pressman Eric James, Method and catalyst system for producing.
상세보기
Spivack James Lawrence ; Whisenhunt ; Jr. Donald Wayne ; Cawse James Norman ; Johnson Bruce Fletcher, Method and catalyst system for producing aromatic carbonates.
상세보기
Spivack James Lawrence ; Whisenhunt ; Jr. Donald Wayne ; Cawse James Norman ; Johnson Bruce Fletcher ; Grade Marsha Mottel ; Soloveichik Grigorii Lev ; Ofori John Yaw ; Pressman Eric James, Method and catalyst system for producing aromatic carbonates.
상세보기
Spivack James Lawrence ; Whisenhunt ; Jr. Donald Wayne ; Cawse James Norman ; Johnson Bruce Fletcher ; Shalyaev Kirill, Method and catalyst system for producing aromatic carbonates.
상세보기
Spivack James Lawrence ; Whisenhunt ; Jr. Donald Wayne ; Cawse James Norman ; Johnson Bruce Fletcher ; Soloveichik Grigorii Lev ; Ofori John Yaw ; Pressman Eric James, Method and catalyst system for producing aromatic carbonates.
상세보기
Spivack James Lawrence ; Whisenhunt ; Jr. Donald Wayne ; Cawse James Norman ; Soloveichik Grigorii Lev, Method and catalyst system for producing aromatic carbonates.
상세보기
Zoeller Joseph Robert ; Singleton Andy Hugh ; Tustin Gerald Charles ; Carver Donald Lee, Method for carbonylation of lower aliphatic alcohols using a supported iridium and lanthanide series catalyst.
상세보기
Joyce Richard P. (East Nassau NY) King ; Jr. Joseph A. (Schenectady NY) Pressman Eric J. (East Greenbush NY), Method for making aromatic carbonates.
상세보기
Pressman Eric J. (East Greenbush NY) King ; Jr. Joseph A. (Schenectady NY), Method for making aromatic carbonates.
상세보기
King ; Jr. Joseph A. (Schenectady NY) Mackenzie Patricia D. (Clifton Park NY) Pressman Eric J. (East Greenbush NY), Method for making aromatic organic carbonates.
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Watanabe Hiroyoshi (Takaishi JPX) Hayakawa Fumie (Takaishi JPX), Method for preparing 2,3-dichloro-1-propanol and 3-chloro-1-propanol.
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Mizukami Masamichi (Tsukuba JPX) Hayashi Katsushige (Tsukuba JPX) Iura Katsuhiro (Tsukuba JPX) Kawaki Takao (Tsukuba JPX), Method for preparing aromatic carbonate.
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Pressman Eric James ; Shafer Sheldon Jay, Method for preparing diaryl carbonates with improved selectivity.
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Peng Y. Lisa ; Williams Jimmie L., Method of making activated carbon derived from pitches.
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Iwane Hiroshi (Inashiki-gun JPX) Miyagi Hidekazu (Inashiki-gun JPX) Imada Satoshi (Inashiki-gun JPX) Seo Shoichi (Inashiki-gun JPX) Yoneyama Takahiro (Inashiki-gun JPX), Method of producing aromatic carbonate.
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Takagi Masatoshi (Inashiki JPX) Miyagi Hidekazu (Inashiki JPX) Ohgomori Yuji (Inashiki JPX) Iwane Hiroshi (Inashiki JPX), Method of producing aromatic carbonate.
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Takagi Masatoshi,JPX ; Kujira Katsufumi,JPX ; Yoneyama Takahiro,JPX ; Ohgomori Yuji,JPX, Method of producing aromatic carbonate.
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Shafer Sheldon J. (Pittsfield MA), Method of recovering and purifying diphenylcarbonate from phenolic solutions thereof.
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Dismukes John P. ; Johnson Jack Wayne ; Bradley John Stewart,DEX, Nanoporous ceramics with catalytic functionality.
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Croce Louis J. (Seabrook TX) Bajars Laimonis (Princeton NJ) Gabliks Maigonis (Highland Park NJ), Oxychlorination of hydrocarbons in the presence of non-halide copper containing catalysts.
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Mueller Franz-Josef (Wachenheim DEX) Matt Dominique (Strasbourg FRX), Preparation of acetic acid and methyl acetate.
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Pimblett Gillian (Pocklington GB2), Process for preparing carboxylic acids.
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Kumazawa Takashi (Sodegaura JPX) Ishibashi Tetsuo (Sodegaura JPX) Kanzawa Mitsugu (Sodegaura JPX), Process for preparing unsaturated dicarboxylic acid diesters.
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Buysch Hans-Josef,DEX ; Hesse Carsten,DEX ; Rechner Johann,DEX, Process for producing diaryl carbonates.
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Yoneoka Mikio (Niigata JPX), Process for producing methyl formate.
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Dombek Bernard D. (Charleston WV), Process for the manufacture of alcohols using ruthenium and lanthanide catalysts.
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Arimitsu Satoshi (Sagamihara JPX) Yanagi Katsumi (Yokohama JPX) Hosono Hitomi (Yokohama JPX) Saito Toshihiro (Machida JPX) Tanaka Kazuaki (Yokkaichi JPX) Onda Yuji (Niigata JPX) Takada Kazuo (Sagamih, Process for the manufacture of ethanol.
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King Stephen W. (Scott Depot WV), Processes for the preparation of aminoethers.
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David Lawrence D. (Wappingers Falls NY), Production of microcrystalline metal oxides.
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Bogdan Paula L., Selective bifunctional multimetallic reforming catalyst.
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Uchida Hiroto ; Soyama Nobuyuki ; Kageyama Kensuke,JPX ; Ogi Katsumi,JPX ; Scott Michael C.,AUX ; McMillan Larry D. ; Paz de Araujo Carlos A., Shelf-stable liquid metal arylketone alcoholate solutions and use thereof in photoinitiated patterning of thin films.
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Buysch Hans-Josef,DEX ; Hesse Carsten,DEX ; Jentsch Jorg-Dietrich,DEX ; Rechner Johann,DEX ; Zirngiebl Eberhard,DEX, Supported catalysts containing a platinum metal and process for preparing diaryl carbonates.
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King ; Jr. Joseph A. (Schenectady NY) Brouwer Klaas (CL Bergen op Zoom NLX), Thermoplastic resin and method using heterocyclic amine catalyst.
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이 특허를 인용한 특허 (5) 인용/피인용 타임라인 분석

Holladay,Jamelyn D.; Wang,Yong; Hu,Jianli; Chin,Ya Huei; Dagle,Robert A.; Xia,Guanguang; Baker,Eddie G.; Palo,Daniel R.; Phelps,Max R.; Jung,Heon, Alcohol steam reforming catalysts and methods of alcohol steam reforming.
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Bogdan, Paula L.; Nemeth, Valeria J.; Bare, Simon R., Method of making substantially nonporous substrate supported noble metal- and lanthanide-containing catalysts.
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Alapati, Ramakanth; Niroomand, Ardavan; Sandhu, Gurtej S.; Tran, Luan C., Methods of forming semiconductor constructions.
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Bogdan, Paula L.; Nemeth, Valeria; Bare, Simon Russell, Substantially non-porous substrate supported noble metal-and lanthanide-containing catalysts.
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Bogdan, Paula L.; Nemeth, Valeria J.; Bare, Simon R., Substantially nonporous substrate supported noble metal- and lanthanide-containing catalysts for hydrogenation reactions.
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[미국특허] Catalyst system 원문보기