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An ester of an α,β-unsaturated carboxylic acid is prepared by reacting the carboxylic acid with a C6-C12-alkanol, cyclopentanol or cyclohexanol in the presence of an acidic esterification catalyst and of an entraining agent for removing the water of reaction formed in the esterification, by a proces

An ester of an α,β-unsaturated carboxylic acid is prepared by reacting the carboxylic acid with a C6-C12-alkanol, cyclopentanol or cyclohexanol in the presence of an acidic esterification catalyst and of an entraining agent for removing the water of reaction formed in the esterification, by a process in which the entraining agent used is the olefin on which the alkanol is based.

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1. A process for the preparation of an ester of an α,β-unsaturated carboxylic acid, which comprises: reacting the carboxylic acid with an alcohol which is selected from the group consisting of C6-C12-alcohols, cyclopentanol and cyclohexanol, in the presence of an acidic esterification catalyst an

1. A process for the preparation of an ester of an α,β-unsaturated carboxylic acid, which comprises: reacting the carboxylic acid with an alcohol which is selected from the group consisting of C6-C12-alcohols, cyclopentanol and cyclohexanol, in the presence of an acidic esterification catalyst and of an entraining agent which removes the water of reaction that forms in the esterification, wherein the entraining agent is the unsaturated aliphatic or cycloaliphatic hydrocarbon compound(s) obtained upon removal of water from the alcohol reactant. 2. A process as claimed in claim 1, wherein said unsaturated aliphatic or cycloaliphatic hydrocarbon compound and water are removed from the reaction mixture as a mixture by distillation, water is separated from the mixture and the unsaturated aliphatic or cycloaliphatic hydrocarbon compound is recycled to the esterification process. 3. A process as claimed in claim 1, wherein, after the end of the reaction, the volatile components are separated from the reaction mixture and the remaining, oxyester-containing product is worked up, an aspect of which is the cleavage of oxyesters, thereby resulting in a cleavage product. 4. A process as claimed in claim 1, wherein the alcohol is a linear or branched C6-C10-alkanol. 5. A process as claimed in claim 4, wherein the alcohol is 2-ethylhexan-1-ol or 2-propylheptanol. 6. A process as claimed in claim 5, wherein the entraining agent is a mixture of isomeric octenes containing 2-ethylhex-2-ene and 3-methylhept-2-ene as main components. 7. A process as claimed in claim 1, wherein the α,β-unsaturated carboxylic acid is a monounsaturated monocarboxylic acid of 3 to 6 carbon atoms. 8. A process as claimed in claim 1, wherein the α,β-unsaturated carboxylic acid is a monounsaturated dicarboxylic acid of 4 to 8 carbon atoms. 9. A process as claimed in claim 7, wherein the α,β-unsaturated carboxylic acid is acrylic acid or methacrylic acid. 10. A process as claimed in claim 3, wherein, after removal of the ester from the cleavage product, the resulting product is recycled as an entraining agent to the esterification process. 11. A process as claimed in claim 1, wherein the molar ratio of alcohol:acid ranges from 1:0.7 to 1:1.2 and the time of reaction ranges from 1 to 10 hours. 12. A process as claimed in claim 11, wherein the reaction time ranges from 1 to 6 hours. 13. A process as claimed in claim 1, wherein the esterification reaction is conducted at a temperature ranging from about 80 to 160° C. 14. A process as claimed in claim 1, wherein the amount of acid catalyst present ranges from about 0.1 to 10% by weight of the other starting materials. 15. A process as claimed in claim 1, wherein the acid catalyst is a mineral acid, a sulfonic acid or phosphoric acid. 16. A process as claimed in claim 1, wherein the esterification reaction is conducted in the presence of an inhibitor that inhibits the polymerization of unsaturated carboxylic acid reactant.