초록 ▼

The present invention relates to a novel photoinitiator system comprising one or more acylphosphine oxide photoinitiators and one or more lightfast red, blue or violet organic pigments. Low yellow color formation results upon curing ethylenically unsaturated compounds with the new photoinitiator sys

The present invention relates to a novel photoinitiator system comprising one or more acylphosphine oxide photoinitiators and one or more lightfast red, blue or violet organic pigments. Low yellow color formation results upon curing ethylenically unsaturated compounds with the new photoinitiator system. Particular applications include clear and white coatings, screen inks, gel coats, powder coatings, composites, adhesives and lenses.

대표청구항 ▼

1. A composition which undergoes minimal yellowing upon curing with ultraviolet radiation or daylight or with light sources equivalent to daylight comprisingat least one ethylenically unsaturated polymerizable compound,(a) at least one acylphosphine oxide photoinitiator of formula (I)in which R 1 a

1. A composition which undergoes minimal yellowing upon curing with ultraviolet radiation or daylight or with light sources equivalent to daylight comprisingat least one ethylenically unsaturated polymerizable compound,(a) at least one acylphosphine oxide photoinitiator of formula (I)in which R 1 and R 2 independently of one another are C 1 -C 12 alkyl, benzyl, phenyl which is unsubstituted or substituted from one to four times by halogen, C 1 -C 8 alkyl and/or C 1 -C 8 alkoxy, or are cyclohexyl or a group COR 3 ; orR 1 is —OR 4 , or a groupR 3 is phenyl which is unsubstituted or substituted from one to four times by C 1 -C 8 alkyl, C 1 -C 8 alkoxy, C 1 -C 8 alkylthio and/or halogen, or is a groupR 4 is C 1 -C 8 alkyl, phenyl or benzyl;Y is phenylene, C 1 -C 12 alkylene or cyclohexylene; andX is C 1 -C 18 alkylene or a group(b) one or more lightfast red, blue or violet organic pigmentswherein the weight ratio of component (b) to component (a) is from about 10 parts per million to about 10,000 parts per million, andwherein a dispersion of the pigment or pigments of component (b) in a liquid has a positive a value and a negative b value on the L, a, b tri-stimulus color scale,with the proviso that when one of R 1 or R 2 is C 1 -C 12 alkyl and the other is COR 3 , that R 3 is not phenyl substituted one to four times by C 1 -C 8 alkoxy. 2. A composition according to claim 1 in which component (a) is at least one acylphosphine oxide of formula (Ia)whereinR 1 is C 1 -C 12 alkyl, cyclohexyl or phenyl which is unsubstituted or substituted from one to four times by halogen and/or C 1 -C 8 alkyl,R 5 and R 6 are each independently of the other C 1 -C 8 alkyl,R 7 is hydrogen or C 1 -C 8 alkyl, andR 8 is hydrogen or methyl. 3. A composition according to claim 2, in which R 1 in the compound of formula (Ia) is C 2 -C 10 alkyl, cyclohexyl or phenyl. 4. A composition according to claim 2, in which R 5 and R 6 in the compound of formula (Ia) are C 1 -C 4 alkyl and R 7 is hydrogen or C 1 -C 4 alkyl. 5. A composition according to claim 2, in which the compound of formula (Ia) is bis(2,4,6-trimethylbenzoyl)phenylphosphine oxide. 6. A composition according to claim 1, in which component (b) is one or more organic pigments selected from the group consisting of quinacridone, carbazole dioxazine and perylene red pigments. 7. A composition according to claim 6, in which a 5 parts per million by weight dispersion of the pigment or pigments of component (b) in a liquid has an a value of about 15 to about 25 and a b value of about −15 to about −30 on the L, a, b tri-stimulus color scale. 8. A composition according to claim 1, which comprises other photoinitiators in addition to the photoinitiator or photoinitiators of formula (I). 9. A composition according to claim 1, which comprises other photoinitiators selected from the group consisting of α-hydroxycycloalkylphenylketones in addition to the photoinitiator or photoinitiators of formula (I). 10. A composition according to claim 1, in which the ethylenically unsaturated polymerizable compounds are a mixture of (i) at least one oligomeric compound and (ii) at least one monomer. 11. A composition according to claim 10, in which the ethylenically unsaturated polymerizable compounds are a mixture of (i) unsaturated polyesters and (ii) acrylates, methacrylates or styrene, or mixtures thereof. 12. A composition according to claim 10, in which the ethylenically unsaturated polymerizable compounds are a mixture of (i) polyester acrylates and (ii) acrylates or methacrylates or mixtures thereof. 13. A composition according to claim 1, in which the ethylenically unsaturated polymerizable compounds are dissolved or emulsified in water. 14. A composition according to claim 1, in which the weight ratio of component (b) to component (a) is from about 100 parts per million to about 1000 parts per million. 15. A composition according to claim 1, in which the photoinitiator or photoinitiators of component (a) are present in an amount of about 0.05 to about 15% by weight of the overall formulation. 16. A composition according to claim 1, in which the photoinitiator or photoinitiators of component (a) are present in an amount of about 0.2 to about 5% by weight of the overall formulation. 17. A composition according to claim 1, which comprises, in addition to components (a) and (b), one or more light stabilizers selected from the group consisting of hydroxyphenylbenzotriazoles, hydroxyphenyl-s-triazines and hindered amines based on 2,2,6,8-tetramethylpiperidine.