초록 ▼

This thermoplastic elastomer is present in a substantially solid state suitable for use as a binder for a propellant, explosive, and/or gas generant of a supplemental restraint system. The thermoplastic elastomer is formed from a composition including A blocks which are crystalline at temperatures b

This thermoplastic elastomer is present in a substantially solid state suitable for use as a binder for a propellant, explosive, and/or gas generant of a supplemental restraint system. The thermoplastic elastomer is formed from a composition including A blocks which are crystalline at temperatures below about 75° C. and B blocks which are amorphous at temperatures above about −20° C. The A blocks are derived from oxetane derivatives and/or tetrahydrofuran derivatives. The B blocks are derived from oxetanes, tetrahydrofuran, oxiranes, and derivatives thereof. The A and B blocks are end-capped with at least one diisocyanate and linked with at least one difunctional oligomer having two functional groups which are reactive with free and unreacted isocyanate moieties of the diisocyanate.

대표청구항 ▼

1. A thermoplastic elastomer having A blocks and B blocks and being present in a solid state suitable for use as a binder for at least one of a propellant, explosive, and gasifier, the thermoplastic elastomer being formulated from a composition comprising, as constituents:A blocks terminated with is

1. A thermoplastic elastomer having A blocks and B blocks and being present in a solid state suitable for use as a binder for at least one of a propellant, explosive, and gasifier, the thermoplastic elastomer being formulated from a composition comprising, as constituents:A blocks terminated with isocyanate-reactive groups derived from monomers comprising at least one member selected from the group consisting of oxetane derivatives and tetrahydrofuran derivatives, the A blocks being crystalline below about 75° C.;B blocks terminated with isocyanate-reactive groups derived from monomers comprising at least one member selected from the group consisting of oxetane and derivatives thereof, tetrahydrofuran and derivatives thereof, and oxirane and derivatives thereof, the B blocks being amorphous above about −20° C.; andlinking groups derived from at least one diisocyanate for end-capping the A blocks and the B blocks and at least one difunctional oligomer comprising two functional groups which are reactive with isocyanate moieties of the at least one diisocyanate. 2. The thermoplastic elastomer as defined in claim 1, wherein:the at least one diisocyanate contains a first isocyanate moiety which is at least five times more reactive with terminal groups of the blocks than a second isocyanate moiety thereof, wherein the more reactive first isocyanate moiety is capable of reacting with and end-capping the terminal groups of the blocks, leaving the less reactive second isocyanate moiety free and unreacted; andthe at least one difunctional oligomer has two isocyanate-reactive hydroxyl groups which are sufficiently sterically unhindered to be reactive with the free and unreacted second isocyanate moieties of the end-capped blocks. 3. The thermoplastic elastomer as defined in claim 2, wherein the at least one diisocyanate comprises 2,4-toluene diisocyanate. 4. The thermoplastic elastomer as defined in claim 1, wherein the A blocks are crystalline below about 60° C. 5. The thermoplastic elastomer as defined in claim 1, wherein the at least one difunctional oligomer comprises a reaction product of at least one diol and at least one diisocyanate, the at least one diol being selected from the group consisting of ethylene glycol, propylene glycol, butylene glycol, and 1,4-cyclohexanedimethanol, and any combination thereof. 6. The thermoplastic elastomer as defined in claim 1, wherein the at least one difunctional oligomer comprises a reaction product of at least one diol and at least one diisocyanate, the at least one diisocyanate being selected from the group consisting of hexane diisocyanate, methylene-bis(4-phenyl isocyanate), phenylene diisocyanate, toluene diisocyanate, and xylylene diisocyanate, and any combination thereof. 7. The thermoplastic elastomer as defined in claim 1, wherein the thermoplastic elastomer has a weight average molecular weight of at least 40,000 and a number average molecular weight of at least 10,000. 8. The thermoplastic elastomer as defined in claim 1, wherein the thermoplastic elastomer has a weight average molecular weight of at least 60,000 and a number average molecular weight of at least 12,000. 9. The thermoplastic elastomer as defined in claim 1, wherein the thermoplastic elastomer has a weight average molecular weight of at least 80,000 and a number average molecular weight of at least 15,000. 10. The thermoplastic elastomer as defined in claim 1, wherein a weight ratio of A to B blocks is between about 15:85 to about 40:60. 11. The thermoplastic elastomer as defined in claim 1, wherein the isocyanate-reactive terminal groups of the A and B blocks are hydroxyl groups. 12. The thermoplastic elastomer as defined in claim 1, wherein the at least one difunctional oligomer comprises a urethane glycol. 13. A thermoplastic elastomer having A blocks and B blocks and being present in a solid state suitable for use as a binder for at least one of a propellant, explosive, and gasifier, the the rmoplastic elastomer being formulated from a composition comprising, as constituents:A blocks terminated with isocyanate-reactive groups derived from monomers comprising at least one member selected from the group consisting of 3,3-(bis(ethoxymethyl)oxetane, 3,3-bis(chloromethyl)oxetane, 3,3-bis(methoxymethyl)oxetane, 3,3-bis(fluoromethyl)oxetane), 3,3-bis(acetoxymethyl)oxetane, 3,3-bis(hydroxymethyl)oxetane, 3,3-bis(methoxyethoxymethyl)oxetane, 3,3-bis(iodomethyl)oxetane, 3,3-bis(nitratomethyl)oxetane), 3,3-bis(methylnitraminomethyl)oxetane, and 3,3-bis(azidomethyl)oxetane), the A blocks being crystalline below about 60° C.;B blocks terminated with isocyanate-reactive groups derived from monomers comprising at least one member selected from the group consisting of 3-hydroxymethyl-3-methyloxetane, 3-octoxymethyl-3-methyloxetane, 3-chloromethyl-3-methyloxetane, 3-azidomethyl-3-methyloxetane, 3-iodomethyl-3-methyloxetane, 3-propynomethylmethyloxetane, 3-nitratomethyl-3-methyloxetane, 3-methylnitraminomethyl-3-methyloxetane, tetrahydrofuran, glycidyl azide, and glycidyl nitrate, the B blocks being amorphous above about −20° C.; andlinking groups derived from at least one diisocyanate for end-capping the A blocks and the B blocks and at least one difunctional oligomer comprising two functional groups which are reactive with isocyanate moieties of the at least one diisocyanate. 14. The thermoplastic elastomer as defined in claim 13, wherein:the at least one diisocyanate contains a first isocyanate moiety which is at least five times more reactive with the terminal groups of the blocks than a second isocyanate moiety thereof, wherein the more reactive first isocyanate moiety is capable of reacting with and end-capping the terminal groups of the blocks, leaving the less reactive second isocyanate moiety free and unreacted; andthe at least one difunctional oligomer has two isocyanate-reactive hydroxyl groups which are sufficiently sterically unhindered to be reactive with the free and unreacted second isocyanate moieties of the end-capped blocks. 15. The thermoplastic elastomer as defined in claim 13, wherein the at least one diisocyanate comprises 2,4-toluene diisocyanate. 16. The thermoplastic elastomer as defined in claim 13, wherein the at least one difunctional oligomer comprises a reaction product of at least one diol and at least one diisocyanate, the at least one diol being selected from the group consisting of ethylene glycol, propylene glycol, butylene glycol, 1,4-cyclohexanedimethanol, and any combination thereof. 17. The thermoplastic elastomer as defined in claim 13, wherein the at least one difunctional oligomer comprises a reaction product of at least one diol and at least one diisocyanate, the at least one diisocyanate being selected from the group consisting of hexane diisocyanate, methylene-bis(4-phenyl isocyanate), phenylene diisocyanate, toluene diisocyanate, xylylene diisocyanate, and any combination thereof. 18. The thermoplastic elastomer as defined in claim 13, wherein a weight ratio of A to B blocks is between about 15:85 to about 40:60. 19. The thermoplastic elastomer as defined in claim 13, wherein the isocyanate-reactive terminal groups of the A and B blocks are hydroxyl groups. 20. The thermoplastic elastomer as defined in claim 13, wherein the at least one difunctional oligomer comprises a urethane glycol.