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A binderless glass fiber mat suitable for use as a separator for valve regulated (“recombinant”) lead acid (“VRLA”) batteries is disclosed. The separator is produced by a dry process by collecting the fibers from fiberizing apparatus, without subjecting them to a wet pape

A binderless glass fiber mat suitable for use as a separator for valve regulated (“recombinant”) lead acid (“VRLA”) batteries is disclosed. The separator is produced by a dry process by collecting the fibers from fiberizing apparatus, without subjecting them to a wet paper making or other post forming process, and selecting portions of the collected fibers which are sufficiently uniform in thickness and grammage for use as battery separators. The fibers can be entwined to produce a superior separator material. Additives can be introduced during the collection process to enhance the properties of the separator. A battery comprises at least one stack of alternating positive and negative plates, with the separator between adjacent plates. Separators according to the invention are significantly more resilient and have longer fibers than otherwise identical separators made from different samples of the same glass fibers, but by a conventional wet paper making process.

대표청구항 ▼

1. In a storage battery comprising a plurality of lead plates in a closed case, a fibrous sheet plate separator between adjacent ones of said plates, and a body of a sulfuric acid electrolyte absorbed by each of said separators and maintained in contact with each of the adjacent ones of said plates,

1. In a storage battery comprising a plurality of lead plates in a closed case, a fibrous sheet plate separator between adjacent ones of said plates, and a body of a sulfuric acid electrolyte absorbed by each of said separators and maintained in contact with each of the adjacent ones of said plates, the improvement wherein said separator sheets consist essentially of intermeshed glass fibers, intermeshed organic fibers, or intermeshed glass and organic fibers produced by opening bundles of the fibers, suspending the carded fibers in a gaseous medium, carding the suspended fibers and collecting the carded fibers on a foraminous material, with the proviso that the mass of fibers has a BET surface area of from 0.2 to 5 m 2 per gram. 2. In a storage battery as claimed in claim 1, the improvement wherein at least two different kinds of bundled organic fibers are carded, and the fibers of one kind have a melting temperature at least 20° C. lower than the melting temperature of the fibers of the other kind. 3. In a storage battery as claimed in claim 1, the improvement wherein the suspended fibers comprise organic fibers. 4. In a storage battery as claimed in claim 3, the improvement wherein the organic fibers are polyolefin. 5. In a storage battery as claimed in claim 4, the improvement wherein the polyolefin fibers are treated to make them hydrophilic. 6. In a storage battery as claimed in claim 5, the improvement wherein the polyolefin fibers are treated to make them hydrophilic by acrylic acid grafting. 7. In a storage battery as claimed in claim 5, the improvement wherein the polyolefin fibers are treated by sulfonation to make them hydrophilic. 8. In a storage battery as claimed in claim 5, the improvement wherein the polyolyfin fibers which are carded contain an internal wetting agent which has migrated to the fiber surfaces to make the surfaces hydrophylic. 9. In a storage battery as claimed in claim 3, the improvement wherein the organic fibers are polyester. 10. In a storage battery as claimed in claim 9, the improvement wherein the outer surfaces of the polyester fibers are rough, and the roughness improves the ability of the fiber to wick. 11. In a storage battery as claimed in claim 3, the improvement wherein the organic fibers are acrylic. 12. In a storage battery as claimed in claim 11, the improvement wherein the organic acrylic fibers are fibrillated. 13. In a storage battery as claimed in claim 1, the improvement wherein some of the intermeshed fibers are glass microfibers having a BET surface area of from 0.2 to 5 m 2 per gram. 14. In a storage battery as claimed in claim 1, the improvement wherein the separator is composed of organic fibers and a particulate inorganic material which was suspended in the gaseous medium with the organic fibers. 15. In a storage battery as claimed in claim 14, the improvement wherein the particulate material constitutes from 5 percent w/w to 90 percent w/w of the total of organic fibers and particulate material. 16. In a storage battery as claimed in claim 3, the improvement wherein at least some of the organic fibers are bi-component fibers. 17. In a storage battery as claimed in claim 16, the improvement wherein at least some of the bi-component fibers are thermally bonded to adjacent fibers at points of contact. 18. In a storage battery as claimed in claim 1, the improvement wherein at least some of the fibers are bi-component fibers. 19. In a storage battery as claimed in claim 1, the improvement wherein at least two different kinds of bundled organic fibers are carded, suspended and collected, and the fibers of one kind have a melting temperature at least 20° C. lower than the melting temperature of the fibers of the other kind. 20. In a storage battery as claimed in claim 3, the improvement wherein the suspended organic fibers are Sulfar. 21. In a storage battery as claimed in claim 1, the improvement wherein the separator contains a particulate inorganic material which was suspended in the gaseous medium with glass fibers, and the glass fibers and particulate inorganic material are collected on a foraminous material.