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A process for the preparation of hydrotreating catalyst which comprises of a Group VIB metal and Group VIII metal on an active composite carrier for the removal of sulfur from gas oil feed stocks, wherein the said carrier comprises of a phosphated alumina and an ultra stable Y zeolite and the metal

A process for the preparation of hydrotreating catalyst which comprises of a Group VIB metal and Group VIII metal on an active composite carrier for the removal of sulfur from gas oil feed stocks, wherein the said carrier comprises of a phosphated alumina and an ultra stable Y zeolite and the metal components mostly reside on the alumina, said process comprising the steps of impregnation of chelated metal complex preferentially on to the alumina component of the composite support and subjecting the composite catalyst to a high-speed ball milling. The catalyst obtained by the process of the present invention consists of the active metals in the nanoparticle range (less than 50 Å) while also retaining the zeolite properties of the composite carrier and the catalyst produces less than 50 ppm sulfur from gas oil feed stocks containing greater than 1 wt % sulfur under typical commercial operating conditions.

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1. A process for preparing a hydrotreating catalyst composition comprising a composite carrier having an alumina part and a zeolite part wherein active metal belonging to group VIB of the periodic table and active metal belonging to Group VIII of the periodic table, each having a particle size less

1. A process for preparing a hydrotreating catalyst composition comprising a composite carrier having an alumina part and a zeolite part wherein active metal belonging to group VIB of the periodic table and active metal belonging to Group VIII of the periodic table, each having a particle size less than about 50 Å are being preferentially supported on the alumina part of the composite carrier, and useful for desulfurization of gas oils, said process comprising the steps of:(a) impregnating a chelated metal solution containing at least one group VIB and at least one group VIII metal on to an alumina support, optionally in presence of a complexing agent; (b) flash drying the metal impregnated alumina support of step (a); (c) ball milling the flash dried metal-impregnated alumina support of step (b); (d) mixing the ball-milled metal-impregnated alumina support of step (c) with USY zeolite; (e) ball milling the mixture of step (d); (f) adding to the ball milled mixture of step (e) a phosphorous source; (g) aging the mixture of step (f) for a time period ranging between about 1 to 5 hours, and (h) molding, drying and calcining the mixture of step (g) to obtain the hydrotreating catalyst composition. 2. A process as claimed in claim 1, wherein the metal solution is an aqueous solution of corresponding soluble metal salt.3. A process as claimed in claim 1, wherein the group VIB metal is molybdenum.4. A process as claimed in claim 1, wherein the group VIII metal is selected from cobalt or nickel.5. A process as claimed in claim 4, wherein the group VIII metal is cobalt.6. A process as claimed in claim 1, wherein impregnation of the chelated metal solution on to the alumina support is done by incipient wetness method.7. A process as claimed in claim 1, wherein the alumina used in step (a) has the following characteristics:Al2O3??74 wt %Na2O0.002 wt %Surface Area (BET)??250 m2/gPore Volume?0.50 ml/g8. A process as claimed in claim 1 wherein in step (a), the complexing agent is soduim salt of EDTA.9. A process as claimed in claim 1 wherein in step (b), the metal impregnated alumina support is flash dried by heating at a temperature ranging from about 40° to 200° C.10. A process as claimed in claim 9 wherein, the metal impregnated alumina support is flash dried by heating at a temperature ranging from about 80° to 150° C.11. A process as claimed in claim 1 wherein in step (c), the flash dried metal-impregnated alumina support is ball milled for a time period ranging from about 10 minutes to 1 hour.12. A process as claimed in claim 11, wherein the flash dried metal-impregnated alumina support is ball milled for about 30 minutes.13. A process as claimed in claim 1 wherein in step (d), the Unit Cell Size (UCS) of the USY zeolite used is in the range of about 24.25 to 24.45 Å.14. A process as claimed in claim 13, wherein the UCS of the USY zeolite is about 24.35 Å.15. A process as claimed in claim 1 wherein in step (d), the weight percentage of USY zeolite used is in the range of about 1 to 10.16. A process as claimed in claim 15, wherein the weight percentage of USY zeolite used is in the range of about 1 to 5.17. A process as claimed in claim 1 wherein in step (e), the mixture of ball-milled metal-impregnated alumina support and USY zeolite is ball milled for a time period ranging from about 10 minutes to 2 hours.18. A process as claimed in claim 17, wherein the mixture of ball-milled metal-impregnated alumina support and USY zeolite is ball milled for a time period ranging from about 10 minutes to 1 hour.19. A process as claimed in claim 1 wherein in step (f), the phosphorous source is di-ammonium hydrogen phosphate.20. A process as claimed in claim 19, wherein di-ammonium hydrogen phosphate used is in the weight range of about 0.1 to 5% by total weight of P2O5.21. A process as claimed in claim 20, wherein the di-ammonium hydrogen phosphate used is in the weight range of about 0.1 to 2% by total weight of P2O5.22. A process as claimed in claim 1 wherein in step (g), the mixture is aged for a time period ranging from about 1 to 2 hours.23. A process as claimed in claim 1 wherein in step (h), molding is done by extrusion or granulation.24. A process as claimed in claim 23, wherein the mixture is molded in the form of cylinders, granules or tablets.25. A process as claimed in claim 23, wherein the diameter of the extrudate is in the range of about 0.5 mm to 3.0 mm.26. A process as claimed in claim 23, wherein the extrudate is dried at a temperature ranging between ambient temperature and 150° C. for a time period ranging from about 10 to 30 hours.27. A process as claimed in claim 26, wherein the dried extrudate is calcined at a temperature ranging from about 250° to 800° C.28. A process as claimed in claim 27, wherein the dried extrudate is calcined at a temperature ranging from about 250° to 600° C.29. A process as claimed in claim 1 wherein in step (h), the hydrotreating catalyst thus obtained has the following composition:IngredientWeight %CoO13.841MoO320.154Na2O0.002P2O50.094Al2O371.947USY3.96230. A process as claimed in claim 1 wherein in step (h), the hydrotreating catalyst thus obtained has the following characteristics:UCS (Å)24.28Total SA, m2/gGreater than 260Pore Volume, cc/gm0.25 to 0.45Metal cluste size (Å)Less than 5031. A process as claimed in claim 30, wherein the hydrotreating catalyst thus obtained has the following characteristics:UCS (Å)?24.28Total SA, m2/g279Pore Volume, cc/gm?0.29Metal cluster size (Å)Less than 5032. A process as claimed in claim 1, wherein the metal is preferentially loaded on the alumina support and the zeolite is substantially free from the metal.33. A process as claimed in claim 1, wherein the hydrotreating catalyst removes refractory sulfur species from gas oils.34. A process as claimed in claim 1, wherein the hydrotreating catalyst produces gas oil having less than about 50-ppm sulfur from a gas oil feedstock having about 1 wt % sulfur content under commercial operating conditions.