초록 ▼

Monolithic metallic catalyst substrates offering improved heat conductivity are provided from metal powder extrusion batches of copper, tin, zinc, aluminum, iron, silver, nickel, and mixtures and alloys thereof by extrusion through a honeycomb extrusion die followed by drying and firing in a two sta

Monolithic metallic catalyst substrates offering improved heat conductivity are provided from metal powder extrusion batches of copper, tin, zinc, aluminum, iron, silver, nickel, and mixtures and alloys thereof by extrusion through a honeycomb extrusion die followed by drying and firing in a two stage firing process to oxidize organic extrusion batch components, remove residual oxides from the porous wall structure, and consolidate the metal powders to strong, integral honeycomb support structures.

대표청구항 ▼

1. A method for making a monolithic metallic catalyst substrate comprising the steps of:compounding a metal powder extrusion batch comprising (i) a powder of a metal selected from the group consisting of copper, tin, zinc, aluminum, silver, iron, nickel, and mixtures and alloys thereof, and (ii) at

1. A method for making a monolithic metallic catalyst substrate comprising the steps of:compounding a metal powder extrusion batch comprising (i) a powder of a metal selected from the group consisting of copper, tin, zinc, aluminum, silver, iron, nickel, and mixtures and alloys thereof, and (ii) at least one carbon-containing temporary organic binder; extruding the batch through a honeycomb extrusion die to form a honeycomb substrate preform; heating the honeycomb substrate preform in an oxidizing atmosphere for a time and to a temperature at least sufficient to substantially remove the carbon-containing organic binder or extrusion aide by oxidation, thus to provide a carbon-free preform; and heating the carbon-free preform in a reducing atmosphere for a time and to a temperature at least sufficient to sinter the carbon-free preform to a unitary monolithic metallic catalyst substrate. 2. A method in accordance with claim 1 wherein the powder is copper metal powder.3. A monolithic copper catalyst substrate produced in accordance with the method of claim 2.4. A monolithic copper catalyst substrate in accordance with claim 3 which incorporates a high surface area washcoat and a metal or metal oxide catalyst.5. A monolithic copper catalyst substrate in accordance with claim 4 wherein the washcoat is composed of alumina and the catalyst comprises a precious metal.6. A monolithic catalyst substrate in accordance with claim 3 having a wall flow honeycomb configuration.7. A monolithic copper catalyst substrate in accordance with claim 3 having a z-flow honeycomb configuration.8. A method in accordance with claim 1 wherein the metal powder extrusion batch further includes an organic extrusion aide and a liquid vehicle.9. A method in accordance with claim 1 wherein the carbon-free preform is heated in a reducing atmosphere at a time and for a temperature at least sufficient to achieve a honeycomb wall porosity in the range of 0-50% by volume.