초록 ▼

Disclosed is a process and apparatus for removing nitrogen compounds from an alkylation substrate such as benzene. A conventional adsorbent bed can be used to adsorb basic organic nitrogen compounds and a hot adsorbent bed of acidic molecular sieve can adsorb the weakly basic nitrogen compounds such

Disclosed is a process and apparatus for removing nitrogen compounds from an alkylation substrate such as benzene. A conventional adsorbent bed can be used to adsorb basic organic nitrogen compounds and a hot adsorbent bed of acidic molecular sieve can adsorb the weakly basic nitrogen compounds such as nitrites. Water facilitates the adsorption of the weakly basic nitrogen compounds. Running an alkylation substrate stream from a fractionation column of elevated temperature and suitable water concentration to the hot adsorbent bed may be advantageous.

대표청구항 ▼

1. A process for alkylating an alkylation substrate with an alkylation agent, said process comprising:passing an alkylation substrate feed stream comprising an alkylation substrate and a nitrogen-containing compound to a separation zone; recovering from the separation zone a contaminated substrate s

1. A process for alkylating an alkylation substrate with an alkylation agent, said process comprising:passing an alkylation substrate feed stream comprising an alkylation substrate and a nitrogen-containing compound to a separation zone; recovering from the separation zone a contaminated substrate stream comprising the alkylation substrate and the nitrogen-containing compound; passing at least a portion of a stream containing the alkylation substrate to an impurity adsorption zone containing an adsorbent selective for the adsorption of impurities comprising basic organic nitrogen compounds; passing at least a portion of the contaminated substrate stream to a nitrogen adsorption zone containing an adsorbent selective for the adsorption of the nitrogen compound, and recovering from the adsorption zone a denitrogenated substrate stream comprising the alkylation substrate and having a concentration of the nitrogen-containing compound that is less than the concentration of the nitrogen-containing compound in the contaminated substrate stream; and passing an alkylation agent and at least a portion of the denitrogenated substrate stream comprising the alkylation substrate to an alkylation reaction zone separate from the nitrogen adsorption zone, alkylating the alkylation substrate with the alkylation agent over an alkylation catalyst to produce alkylate, and recovering from the alkylation reaction zone the reaction effluent stream comprising the alkylate. 2. The process of claim 1 wherein said alkylation substrate feed stream includes water.3. The process of claim 1 wherein said contaminated substrate stream includes water.4. The process of claim 1 further including passing at least a portion of a reaction effluent stream to the separation zone.5. The process of claim 1 wherein said alkylation catalyst and said adsorbent in said nitrogen adsorption zone are different.6. The process of claim 2 wherein the contaminated substrate stream includes between 50 and 150 wppm water.7. The process of claim 1 wherein said contaminated substrate stream is heated or cooled before entering the nitrogen adsorption zone.8. The process of claim 1 wherein the nitrogen adsorption zone includes no more than 1.0 wt-% alkylation agent.9. The process of claim 1 wherein the adsorbent selective for the adsorption of impurities is a clay or a resin.10. The process of claim 1 wherein the adsorbent selective for the adsorption of the nitrogen compound is an acidic molecular sieve.11. The process of claim 9 wherein the adsorbent comprises a material selected from the group of zeolite beta and zeolite Y.12. The process of claim 1 wherein the nitrogen-containing compound comprises a nitrile.13. The process of claim 1 wherein the alkylation substrate comprises benzene and the alkylation agent is either propylene or ethylene.14. The process of claim 1 wherein the contaminated substrate stream is an intermediate stream from the separation zone.15. A process for alkylating an alkylation substrate with an alkylation agent, said process comprising:passing a first alkylation substrate feed stream comprising an alkylation substrate and impurities to an impurity adsorption zone containing a purifying adsorbent comprising clay or resin selective for the adsorption of impurities and recovering from the impurity adsorption zone a purified alkylation substrate feed stream comprising the alkylation substrate and having a concentration of impurities that is less than the concentration of impurities in the first alkylation substrate feed stream; passing a second alkylation substrate feed stream comprising an alkylation substrate, at least 20 wppm water and a nitrile compound to a nitrogen adsorption zone containing a denitrogenating adsorbent selective for the adsorption of nitriles, and recovering from the adsorption zone a denitrogenated alkylation substrate stream comprising the alkylation substrate and having a concentration of the nitrile compound that is less than the concentration of the ntrile compound in the second alkylation substrate feed stream, the denitrogenating adsorbent being different from the purifying adsorbent; and passing an alkylation agent and at least a portion of the purified substrate stream and at least a portion of the denitrogenated alkylation substrate stream comprising the alkylation substrate to an alkylation reaction zone containing an alkylation catalyst, said impurity adsorption zone and said nitrogen adsorption zone being spaced from said alkylation reaction zone, alkylating the alkylation substrate with the alkylation agent to produce alkylate, and recovering from the alkylation reaction zone the reaction effluent stream comprising the alkylate. 16. The process of claim 15 wherein the alkylation catalyst is different from the denitrogenating adsorbent.17. The process of claim 15 wherein the alkylation reaction zone and the nitrogen adsorption zone are in two separate vessels.18. The process of claim 15 wherein no more than 1 wt-% alkylation agent is present in the nitrogen adsorption zone.19. The process of claim 15 wherein the denitrogenating adsorbent is a molecular sieve and the purifying adsorbent is a resin.20. The process of claim 15 wherein that the denitrogenating adsorption zone operates at adsorption conditions comprising a temperature of greater than 125° C.21. The process of claim 15 wherein the denitrogenating adsorbent is a molecular sieve.22. The process of claim 15 wherein the denitrogenating adsorbent is a molecular sieve and the purifying adsorbent is a clay.23. The process of claim 15 wherein the denitrogenated alkylation substrate feed stream contains at least a portion of the purified alkylation substrate feed stream.24. A process for alkylating an alkylation substrate with an alkylation agent, said process comprising:passing an alkylation substrate feed stream comprising an alkylation substrate and impurities to an impurity adsorption zone containing a purifying adsorbent comprising clay or resin selective for the adsorption of impurities and recovering from the impurity adsorption zone a purified alkylation substrate feed stream comprising the alkylation substrate and having a concentration of impurities that is less than the concentration of impurities in the alkylation substrate feed stream; passing at least a portion of the purified alkylation substrate feed stream comprising at least 20 wppm water and a nitrile compound to a nitrogen adsorption zone containing a denitrogenating adsorbent selective for the adsorption of nitriles, and recovering from the adsorption zone a denitrogenated alkylation substrate stream comprising the alkylation substrate and having a concentration of the nitrile compound that is less than the concentration of the nitrile compound in the purified alkylation substrate feed stream, the denitrogenating adsorbent being different from the purifying adsorbent; and passing an alkylation agent and at least a portion of the denitrogenated alkylation substrate stream comprising the alkylation substrate to an alkylation reaction zone containing an alkylation catalyst, said nitrogen adsorption zone being spaced from said alkylation reaction zone, alkylating the alkylation substrate with the alkylation agent to produce alkylate, and recovering from the alkylation reaction zone the reaction effluent stream comprising the alkylate.