[미국특허]
Production of stable olefinic fischer tropsch fuels with minimum hydrogen consumption
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C07C-027/00
C07C-007/20
C10G-045/00
C10G-029/22
출원번호
US-0354956
(2003-01-31)
발명자
/ 주소
O'Rear, Dennis J.
Lei, Guan Dao
출원인 / 주소
Chevron U.S.A. Inc.
대리인 / 주소
Burns, Doane, Swecker &
인용정보
피인용 횟수 :
10인용 특허 :
16
초록▼
The present invention relates to a stable, low sulfur, olefinic distillate fuel blend component derived from a Fischer-Tropsch process and a process for producing this stable, low sulfur, olefinic distillate fuel blend component. The stable, low sulfur, olefinic distillate fuel comprises olefins in
The present invention relates to a stable, low sulfur, olefinic distillate fuel blend component derived from a Fischer-Tropsch process and a process for producing this stable, low sulfur, olefinic distillate fuel blend component. The stable, low sulfur, olefinic distillate fuel comprises olefins in an amount of 2 to 80 weight percent, non-olefins in an amount of 20 to 98 weight percent wherein the non-olefins are predominantly paraffins, oxygenates in an amount of less than 1 weight percent, and sulfur in an amount of less than 10 ppm by weight. A distillate fuel comprising the above blend component forms less than 5 ppm peroxides after storage at 60° C. for four weeks.
대표청구항▼
1. A process for producing a distillate fuel blend component comprising:a) converting at least a portion of a hydrocarbon asset to synthesis gas; b) converting at least a portion of the synthesis gas to a hydrocarbon stream in a Fischer Tropsch process unit; c) isolating a distillate fuel fraction f
1. A process for producing a distillate fuel blend component comprising:a) converting at least a portion of a hydrocarbon asset to synthesis gas; b) converting at least a portion of the synthesis gas to a hydrocarbon stream in a Fischer Tropsch process unit; c) isolating a distillate fuel fraction from the hydrocarbon stream, wherein the distillate fuel fraction comprises 2 to 80 weight % olefins and 20 to 98 weight % non-olefins, wherein the non-olefins comprise greater than 50 weight % paraffins; d) purifying the distillate fuel fraction by contacting the distillate fuel fraction with a metal oxide at elevated temperatures; and e) isolating a distillate fuel blend component comprising oxygenates in an amount of less than 1 weight % and has a total acid number of less than 1.5. 2. A process according to claim 1, wherein the metal oxide is selected from the group consisting of alumina, silica, silica-alumina, zeolites, clays, and mixtures thereof.3. A process according to claim 1, wherein the distillate fuel blend component isolated has a total acid number of less than 0.5.4. A process according to claim 1, wherein the purifying is performed by passing the distillate fuel fraction through a purification unit containing a metal oxide at 450 to 800° F., less than 1000 psig, and 0.25 to 10 LHSV without added gaseous components.5. A process according to claim 1, wherein the purification step comprises conditions of an oxygenate conversion greater than 75%.6. A process according to claim 1, wherein the purification step comprises conditions of an oxygenate conversion greater than 90%.7. A process for producing a blended distillate fuel comprising:a) converting at least a portion of a hydrocarbon asset to synthesis gas; b) converting at least a portion of the synthesis gas to a hydrocarbon stream in a Fischer Tropsch process reactor; c) isolating an olefinic distillate fuel fraction from the hydrocarbon stream, wherein the olefinic distillate fuel fraction comprises 2 to 80 weight % olefins and 20 to 98 weight % non-olefins, wherein the non-olefins comprise greater than 50 weight % paraffins; d) purifying the olefinic distillate fuel fraction by contacting the olefinic distillate fuel fraction with a metal oxide at elevated temperatures to provide a purified olefinic distillate fuel comprising oxygenates in an amount of less than 1 weight %; and e) mixing the purified olefinic distillate fuel fraction with a distillate fuel selected from the group consisting of a hydrocracked Fischer Tropsch derived distillate fuel, a hydrotreated Fischer Tropsch derived distillate fuel, a hydrocracked petroleum derived distillate fuel, a hydrotreated petroleum derived distillate fuel, and mixtures thereof, wherein the blended distillate fuel comprises sulfur in an amount of less than 10 ppm by weight, has a total acid number of less 1.5, and forms less than 5 ppm peroxides after storage at 60° C. for 4 weeks.8. A process according to claim 7, wherein the blended distillate fuel comprises sulfur in an amount of less than 1 ppm by weight.9. A process according to claim 7, wherein the purifying is performed using a metal oxide selected from the group consisting of alumina, silica, silica-alumina, zeolite , clays, and mixtures thereof.10. A process according to claim 7, wherein the blended distillate fuel has a total acid number of less than 0.5.11. A process according to claim 7, wherein the blended distillate fuel meets specifications for a diesel fuel as defined in ASTM D-975-98.12. A process according to claim 7, wherein the blended distillate fuel forms less than 4 ppm peroxides after storage at 60° C. for 4 weeks.13. A process according to claim 7, wherein the blended distillate fuel forms less than 1 ppm peroxides after storage at 60° C. for 4 weeks.14. A process according to claim 7, wherein the purifying is performed by passing the distillate fuel fraction through a purification unit containing a metal oxide at 450 to 800° F., less than 1000 psig, and 0.25 to 10 LHSV without added gaseous components.15. A process according to claim 7, wherein the purifying comprises conditions of an oxygenate conversion greater than 75%.16. A process according to claim 7, wherein the purifying comprises conditions of an oxygenate conversion greater than 90%.17. A process for producing a blended distillate fuel comprising:a) providing an olefinic distillate fuel fraction comprising oxygenates in an amount of less than 1 weight %, 2 to 80 weight % olefins, and 20 to 98 weight % non-olefins, wherein the non-olefins comprise greater than 50 weight % paraffins; and b) mixing the olefinic distillate fuel fraction with a distillate fuel fraction selected from the group consisting of a hydrocracked Fischer Tropsch derived distillate fuel, a hydrotreated Fischer Tropsch derived distillate fuel, a hydrocracked petroleum derived distillate fuel, a hydrotreated petroleum derived distillate fuel, and mixtures thereof, wherein the blended distillate fuel comprises sulfur in an amount of less than 10 ppm by weight has a total acid number of less 1.5, and forms less than 5 ppm peroxides after storage at 60° C. for 4 weeks.18. A process according to claim 17, wherein the blended distillate fuel comprises sulfur in an amount of less than 1 ppm by weight.19. A process according to claim 17, wherein the blended distillate fuel comprises a total acid number of less than 0.5.20. A process according to claim 17, wherein the blended distillate fuel forms less than 1 ppm peroxides after storage at 60° C. for 4 weeks.
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