IPC분류정보
국가/구분 |
United States(US) Patent
등록
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국제특허분류(IPC7판) |
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출원번호 |
US-0324749
(2002-12-18)
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발명자
/ 주소 |
- Zhong, Luhua
- Muller, Edward M.
- Barber, James J.
- Pugach, Joseph
- Whitehouse, Robert S.
- Daughtry, Sean K.
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출원인 / 주소 |
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대리인 / 주소 |
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인용정보 |
피인용 횟수 :
8 인용 특허 :
53 |
초록
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In some embodiments, this invention relates to a method that includes contacting a PHA with an aprotic catalyst to form an ester. The ester has only one monomer unit from the PHA. In certain embodiments, this invention relates to a method that includes treating a PHA-containing non-lyophilized bioma
In some embodiments, this invention relates to a method that includes contacting a PHA with an aprotic catalyst to form an ester. The ester has only one monomer unit from the PHA. In certain embodiments, this invention relates to a method that includes treating a PHA-containing non-lyophilized biomass to form an ester, and removing at least some of the ester from the biomass.
대표청구항
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1. A method, comprising:contacting a PHA with an aprotic catalyst to form an ester, wherein the ester has only one monomer unit from the PHA. 2. The method of claim 1, wherein the PHA is derived from biomass selected from the group consisting of plant biomass and microbial biomass.3. The method of c
1. A method, comprising:contacting a PHA with an aprotic catalyst to form an ester, wherein the ester has only one monomer unit from the PHA. 2. The method of claim 1, wherein the PHA is derived from biomass selected from the group consisting of plant biomass and microbial biomass.3. The method of claim 2, wherein less than about 50 weight percent of the PHA that is treated to form the ester is removed from the biomass before being treated to form the ester.4. The method of claim 2, further comprising, before treating the PHA to form the ester, removing at least about 60 weight percent of the PHA that is treated to form the ester from the biomass.5. The method of claim 1, wherein the aprotic catalyst comprises a transesterification catalyst.6. The method of claim 1, further comprising contacting the PHA with an alcohol.7. The method of claim 6, wherein the alcohol comprises a monohydric alcohol.8. The method of claim 6, wherein the alcohol is selected from the group consisting of methanol, ethanol, propanol, butanol, 2-ethylhexanol, cyclohexanol, decyl alcohol, dodecyl alcohol, isopropyl alcohol, isobutyl alcohol, dodecyl alcohol, stearyl alcohol, oleyl alcohol, linolyl alcohol, linolenyl alcohol, propylene glycol, glycerol, ethylene glycol, propylene glycol, 1,2-propane diol, 1,3-propane diol, 1,3-butane diol, 1,4-butane diol, 1,6-hexane diol, glycerol, erythritol, pentaerythritol, dipentaerythritol, thrimethylol propane, xylose, sucrose, dextrose and triethanolamine.9. The method of claim 6, wherein the ester has a structure selected from the group consisting of: and wherein n is selected from the group consisting of zero and an integer greater than zero, y is zero, each of R1, R2, R3, R4, R5 and R6 is independently selected from the group consisting of a hydrogen atom, a halogen atom and a hydrocarbon radical, and R7 comprises a hydrocarbon radical.10. The method of claim 9, wherein n is zero, one or two.11. The method of claim 10, wherein R2, R3 and R4 are each hydrogen atoms.12. The method of claim 11, wherein R1 is selected from the group consisting of a hydrogen atom, a methyl radical, an ethyl radical, a propyl radical, a butyl radical and a pentyl radical.13. The method of claim 12, wherein R7 is selected from group consisting of a methyl radical, an ethyl radical, a propyl radical, a butyl radical and a pentyl radical.14. The method of claim 1, wherein the PHA is selected from the group consisting of poly 3-hydroxybutyrate, poly 3-hydroxypropionate, poly 4-hydroxybutyrate, poly 5-hydroxypentanoate and poly 6-hydroxyhexanoate.15. The method of claim 1, further comprising combining the PHA with an alcohol to form a combination,wherein the combination contains less than about one milliliter of solvent other than the alcohol per gram of the PHA. 16. The method of claim 1, wherein treating the PHA occurs at a temperature of at least about 180° C.17. The method of claim 1, wherein treating the PHA occurs at a pressure of at least about 50 psig.18. The method of claim 1, wherein the percent yield of ester is at least about 50%.19. The method of claim 18, further comprising combining the PHA with an alcohol,wherein a ratio of moles of alcohol per mole of PHA monomer unit is less than about 20. 20. The method of claim 1, wherein the PHA is a chiral PHA, and a percent chirality yield of chiral ester is at least about five percent.21. The method of claim 1, wherein the ester is an alkanoic ester, and the percent yield of alkenoic byproducts is less than about 10%.22. A method, comprising:combining a PHA-containing non-lyophilized biomass with an alcohol to form a combination; treating the PHA contained in the combination to form an ester; and removing at least some of the ester from the biomass; wherein the combination contains less than about one milliliter of solvent other than the alcohol per gram of the PHA. 23. The method of claim 22, wherein at least about 10 weight percent of the ester is removed from the biomass.24. The method of claim 22, wherein the alcohol comprises a monohydric alcohol.25. The method of claim 22, wherein the alcohol is selected from the group consisting of methanol, ethanol, propanol, butanol, 2-ethylhexanol, cyclohexanol, decyl alcohol, dodecyl alcohol, isopropyl alcohol, isobutyl alcohol, dodecyl alcohol, stearyl alcohol, oleyl alcohol, linolyl alcohol, linolenyl alcohol, propylene glycol, glycerol, ethylene glycol, propylene glycol, 1,2-propane diol, 1,3-propane diol, 1,3-butane diol, 1,4-butane diol, 1,6-hexane diol, glycerol, erythritol, pentaerythritol, dipentaerythritol, thrimethylol propane, xylose, sucrose, dextrose and triethanolamine.26. The method of claim 22, wherein the ester has a structure selected from the group consisting of: and wherein n is selected from the group consisting of zero and an integer greater than zero, y is selected from the group consisting of zero and an integer greater than or equal to one but less than 499, and each of R1, R2, R3, R4, R5 and R6 is independently selected from the group consisting of a hydrogen atom, a halogen atom and a hydrocarbon radical, and R7 comprises a hydrocarbon radical.27. The method of claim 26, wherein n is zero, one or two.28. The method of claim 27, wherein R2, R3 and R4 are each hydrogen atoms.29. The method of claim 28, wherein R1 is selected from the group consisting of a hydrogen atom, a methyl radical, an ethyl radical, a propyl radical, a butyl radical and a pentyl radical.30. The method of claim 29, wherein R7 is selected from group consisting of a methyl radical and, ethyl radical, a propyl radical, a butyl radical and a pentyl radical.31. The method of claim 22, wherein the PHA is selected from the group consisting of poly 3-hydroxybutyrate, poly 3-hydroxypropionate, poly 4-hydroxybutyrate, poly 5-hydroxypentanoate and poly 6-hydroxyhexanoate.32. The method of claim 22, wherein treating the PHA occurs at a temperature of at least about 180° C.33. The method of claim 22, wherein treating the PHA occurs at a pressure of at least about 50 psig.34. The method of claim 22, wherein the percent yield of ester is at least about 50%.35. The method of claim 34,wherein a ratio of moles of alcohol per mole of PHA monomer unit is less than about 20. 36. The method of claim 22, wherein the PHA is a chiral PHA, and a percent chirality yield of chiral ester is at least about five percent.37. The method of claim 22, wherein the ester is an alkanoic ester, and the percent yield of alkenoic byproducts is less than about 10%.
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