IPC분류정보
국가/구분 |
United States(US) Patent
등록
|
국제특허분류(IPC7판) |
|
출원번호 |
US-0568365
(2000-05-10)
|
우선권정보 |
DE-0049607 (1997-11-10) |
발명자
/ 주소 |
- Neufert, Ronald
- Witzel, Frank
- Fischer, Stefan
- Pajonk, G?nther
|
출원인 / 주소 |
- Siemens Aktiengesellschaft
|
인용정보 |
피인용 횟수 :
5 인용 특허 :
18 |
초록
▼
To reduce the number of particles in an exhaust gas (A), in particular in the exhaust gas (A) from an internal-combustion engine, sulfur dioxide SO2 which is contained in the exhaust gas (A) is at least partially catalytically oxidized, in the presence of ammonia NH3 in a catalytic converter system
To reduce the number of particles in an exhaust gas (A), in particular in the exhaust gas (A) from an internal-combustion engine, sulfur dioxide SO2 which is contained in the exhaust gas (A) is at least partially catalytically oxidized, in the presence of ammonia NH3 in a catalytic converter system having a catalytic activity which increases in the direction of flow, to form sulfur trioxide SO3. The simultaneous presence of sulfur trioxide SO3 and ammonia NH3 in the exhaust-gas stream which is brought about in this way results in an agglomeration of the small and very small particles and reduction in the number thereof.
대표청구항
▼
1. A method of reducing a number of particles in an exhaust gas formed during a combustion of a fuel, which comprises the steps of providing an exhaust gas containing sulfur dioxide and particles having a first average particle diameter, admixing ammonia with the exhaust gas, and flowing the mixture
1. A method of reducing a number of particles in an exhaust gas formed during a combustion of a fuel, which comprises the steps of providing an exhaust gas containing sulfur dioxide and particles having a first average particle diameter, admixing ammonia with the exhaust gas, and flowing the mixture of ammonia and exhaust gas through a catalytic converter system having oxidation activity such that the catalytic activity increases, in terms of the oxidation of sulfur dioxide SO2, in the direction of flow, whereby sulfur dioxide is at least in part catalytically oxidized to form sulfur trioxide and ammonia and sulfur trioxide interact on a particle surface, leading to agglomeration of the particles and affording exhaust gas with diminished content of sulfur oxides and particles diminished in number and having a second average particle diameter greater than said first average particle diameter.2. The method according to claim 1, which comprises forming the exhaust gas by combustion in an internal-combustion engine.3. The method according to claim 1, wherein the exhaust gas additionally contains nitrogen oxides and the catalytic converter system comprises an SCR catalytic converter containing an SCR catalyst, and the method further comprises subjecting the exhaust gas to an SCR process.4. The method according to claim 3, wherein the oxidation of the sulfur dioxide SO2 takes place at least in a partial area in the SCR catalytic converter.5. The method according to claim 4, wherein the partial area is located on the outlet side in the SCR catalytic converter.6. The method according to claim 3, wherein the SCR catalytic converter is separate from the oxidation catalytic converter in which the oxidation of the sulfur dioxide SO2 takes place.7. The method according to claim 6, wherein the oxidation catalytic converter is connected downstream of the SCR catalytic converter.8. The method according to claim 7, which comprises adding the oxidation catalytic converter to retrofit an exhaust-gas cleaning installation including a conventional SCR catalytic converter.9. The method according to claim 3, wherein the SCR catalyst has BET surface area between 30 and 150 m2/g.10. The method according to claim 3, wherein the SCR catalyst has a pore volume between 100 and 1000 ml/g.11. The method according to claim 1, wherein the catalytic converter system contains, as the catalytically active component used for oxidizing the sulfur dioxide SO2, at least one element selected from the group consisting of Pt, Pd, Rh, Ir, Au, Ag, Ru.12. The method according to claim 1, wherein the catalytic converter system contains, as the catalytically active component used for the oxidation of the sulfur dioxide SO2, at least one oxide or mixed oxide of an element selected from the group consisting of transition metal, lanthanide and actinide elements.13. The method according to claim 1, wherein the catalytic converter system contains, as the catalytically active component used for oxidizing the sulfur dioxide SO2, vanadium or a compound containing vanadium.14. The method according to claim 1, wherein the catalytic converter system additionally contains at least one promoter for the oxidation of the sulfur dioxide SO2 selected from the group consisting of alkali metals, alkaline-earth metals, and compounds thereof.15. A method for reducing the number of particles in an exhaust gas formed during a combustion of a fuel, which comprises the steps of providing an exhaust gas containing sulfur dioxide and particles having a first average particle diameter, admixing ammonia with the exhaust gas, and flowing the mixture of ammonia and exhaust gas through a catalytic converter system having oxidation activity such that the catalytic activity increases, in terms of the oxidation of sulfur dioxide SO2, in the direction of flow; wherein the exhaust gas additionally contains nitrogen oxides and the catalytic converter system comprises an SCR catalytic converter containing an SCR catalyst, and the method further comprises subjecting the exhaust to an SCR process; and wherein the catalytic converter system comprises an inlet-side partial area in which the catalytically active components consist essentially of 70-95% by weight titanium dioxide TiO2, 2-10% by weight of at least one oxide selected from the group consisting of tungsten oxide WO3 and molybdenum oxide MoO3, 0-2% vanadium pentoxide V2O5, 0.1-6% by weight aluminum oxide Al2O3 and 0.1-6% by weight silicon dioxide SiO2, and an outlet-side partial area in which the vanadium pentoxide concentration is greater than in said inlet-side partial area; whereby sulfur dioxide is at least in part catalytically oxidized to form sulfur trioxide and ammonia and sulfur trioxide interact on the surface of particles, leading to agglomeration of the particles and affording exhaust gas with diminished content of sulfur oxides and particles diminished in number and having a second average particle diameter greater than said first average particle diameter.16. The method according to claim 15, wherein the concentration of vanadium pentoxide in the outlet-side partial area is approximately 4% by weight.17. A method for reducing the number of particles in an exhaust gas formed during the combustion of a fuel, which comprises contacting an exhaust gas on a device for admixing ammonia to the exhaust gas and a device having a catalytic converter system disposed in an exhaust pipe, at least partially catalytically oxidizing sulfur dioxide SO2 to form sulfur trioxide SO3, with a catalytic activity in terms of the oxidation of sulfur dioxide which increases in a direction of flow.18. The method according to claim 17, which comprises generating the exhaust gas by fuel combustion in an internal combustion engine.19. The method according to claim 17, wherein the catalytic converter system comprises an SCR catalytic converter.20. The method according to claim 17, wherein at least a partial area of the SCR catalytic converter is an oxidation catalytic converter for oxidation of sulfur dioxide SO2 to form sulfur trioxide SO3.21. The method according to claim 20, wherein the partial area is located on the outlet side in the SCR catalytic converter.22. The method according to claim 20, wherein the catalytic converter system comprises an oxidation catalytic converter which is separate from the SCR catalytic converter.23. The method according to claim 17, wherein the catalytic converter system contains, as the catalytically active component for the oxidation of the sulfur dioxide SO2, at least one element selected from the group consisting of Pt, Pd, Rh, Ir, Au, Ag, Ru.24. The method according to claim 17, wherein the catalytic converter system contains, as the catalytically active component for the oxidation of the sulfur dioxide SO2, at least one oxide of an element selected from the group consisting of the transition metals, the lanthanides, the actinides, and mixtures thereof.25. The method according to claim 17, wherein the catalytic converter system contains, as the catalytically active component for the oxidation of the sulfur dioxide SO2, vanadium V or a component which contains vanadium V.26. The method according to claim 17, wherein the catalytic converter system contains at least one promoter for the oxidation of the sulfur dioxide SO2 selected from the group consisting of the alkali metals, the alkaline-earth metals, and compounds thereof.27. A method for reducing the number of particles in an exhaust gas formed during the combustion of a fuel, which comprises contacting an exhaust gas on a device for admixing ammonia to the exhaust gas and a device having a catalytic converter system disposed in an exhaust pipe, at least partially catalytically oxidizing sulfur dioxide SO2 to form sulfur trioxide SO3, with a catalytic activity in terms of the oxidation of sulfur dioxide which increases in a direction of flow, wherein the catalytic converter system comprises an inlet-side partial area in which the catalytically active components consist essentially of 70-95% by weight titanium dioxide TiO2, 2-10% by weight of at least one oxide selected from the group consisting of tungsten oxide WO3 and molybdenum oxide MoO3, 0-2% vanadium pentoxide V2O5, 0.1-6% by weight aluminum oxide Al2O3 and 0.1-6% by weight silicon dioxide SiO2, and an outlet-side partial area in which the vanadium pentoxide concentration is greater than in said inlet-side partial area.28. The method according to claim 27, wherein the concentration of vanadium pentoxide in the outlet-side partial area is approximately 4% by weight.
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