Fluorine-free fire fighting agents and methods
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
A62D-001/02
A62D-001/00
A62D-001/04
C09K-021/08
C09K-021/00
C09K-021/14
출원번호
US-0600810
(2003-06-20)
발명자
/ 주소
Clark,Kirtland P.
출원인 / 주소
Chemguard Incorporated
인용정보
피인용 횟수 :
3인용 특허 :
28
초록▼
A foam concentrate provides a fire-fighting composition when mixed with water so that the fire-fighting composition does not form a stable seal on cyclohexane and meets UL 162, Class B performance criteria for at least one of AFFF agents and fluoroprotein (FP) agents without requiring organic fluori
A foam concentrate provides a fire-fighting composition when mixed with water so that the fire-fighting composition does not form a stable seal on cyclohexane and meets UL 162, Class B performance criteria for at least one of AFFF agents and fluoroprotein (FP) agents without requiring organic fluorine. The concentrate is formed from water and a high molecular weight acidic polymer (HMWAP) and a coordinating salt.
대표청구항▼
I claim: 1. A fire fighting composition comprising water, a high molecular weight acidic polymer (HMWAP) having an average molecular weight of from 5000 g/mol or greater, a hydrocarbon surfactant and a coordinating salt, the fire fighting composition meeting UL 162, Class B performance criteria for
I claim: 1. A fire fighting composition comprising water, a high molecular weight acidic polymer (HMWAP) having an average molecular weight of from 5000 g/mol or greater, a hydrocarbon surfactant and a coordinating salt, the fire fighting composition meeting UL 162, Class B performance criteria for at least one of AFFF agents and fluoroprotein (FP) agents without requiring organic fluorine and that does not form a stable seal on cyclohexane. 2. The fire fighting composition of claim 1, further comprising: at least one of a fluorochemical surfactant, an amphoteric hydrocarbon surfactant, an anionic surfactant, a nonionic surfactant, a foaming aid, a freeze protection agent, a sequestering agent, a buffering agent, a corrosion inhibitor, a polymeric film former, an antimicrobial agent, a preservative, a polymeric foam stabilizer and a polymeric foam thickener. 3. The fire fighting composition of claim 1, wherein: the fire fighting composition meets UL 162, Class B performance criteria for both AFFF agents and fluoroprotein (FP) agents without requiring organic fluorine. 4. The fire fighting composition of claim 1, wherein the HMWAP content is from about 0.01 to about 0.3% by weight of the fire fighting composition, and wherein the coordinating salt content is from about 0.1 to about 1.5% by weight of the fire fighting composition. 5. The composition of claim 1, wherein: the coordinating salt is a polyvalent salt. 6. The composition of claim 1, further comprising a fluorochemical surfactant, the fluorochemical surfactant providing the fire fighting composition with less than about 0.006% fluorine by weight of the fire fighting composition. 7. The composition of claim 1, wherein the composition has less than about 0.002% fluorine by weight of the fire fighting composition. 8. The composition of claim 1, wherein the composition has less than about 0.001% fluorine by weight of the fire fighting composition. 9. The composition of claim 1, wherein the fire fighting composition has a spreading coefficient against cyclohexane of zero or less. 10. The composition of claim 1, wherein the fire fighting composition has from about 0.03% to about 0.2% HMWAP by weight of the fire fighting composition, and wherein the fire fighting composition has from about 0.12% to about 1.2% of the coordinating salt by weight of the fire fighting composition. 11. The composition of claim 1, wherein the coordinating salt is selected from salts and electrolytes of aluminum, antimony, barium, boron, calcium, copper, iron, magnesium, calcium, strontium and zinc. 12. The composition of claim 1, wherein the HMWAP includes those polymers having C4 to C22 alkyl branching. 13. A fire fighting composition comprising water, a high molecular weight acidic polymer (HMWAP) having an average molecular weight of from 5000 g/mol or greater, a hydrocarbon surfactant and a polyvalent coordinating salt, the fire fighting composition meeting UL 162, Class B performance criteria for at least one of AFFF agents and fluoroprotein (FP) agents and that does not form a stable seal on cyclohexane. 14. The fire fighting composition of claim 13, wherein the HMWAP content is from about 0.01 to about 0.3% by weight of the fire fighting composition, and wherein the coordinating salt content is from about 0.1 to about 1.5% by weight of the fire fighting composition. 15. The composition of claim 13, further comprising a fluorochemical surfactant, and wherein the fluorochemical surfactant provides the fire fighting composition with less than about 0.006% fluorine by weight of the fire fighting composition. 16. The composition of claim 13, wherein the composition has less than about 0.002% fluorine by weight of the fire fighting composition. 17. The composition of claim 13, wherein the coordinating salt is selected from salts and electrolytes of aluminum, antimony, barium, boron, calcium, copper, iron, magnesium, calcium, strontium and zinc. 18. The composition of claim 13, wherein the HMWAP includes those polymers having C4 to C22 alkyl branching. 19. The fire fighting composition of claim 13, wherein: the fire fighting composition meets UL 162, Class B performance criteria for both AFFF agents and fluoroprotein (FP) agents. 20. A fire fighting composition comprising water, a high molecular weight acidic polymer (HMWAP) having an avenge molecular weight of from 5000 g/mol or greater in an amount of from about 0.01% to about 0. 3% by weight of the fire fighting composition, a hydrocarbon surfactant and a polyvalent coordinating salt in an amount of from about 0.1 to about 1.5% by weight of the fire fighting composition, the fire fighting composition meeting UL 162, Class B performance criteria for at least one of AFFF agents and fluoroprotein (FP) agents and that does not form a stable seal on cyclohexane.
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이 특허에 인용된 특허 (28)
Norman Edward C. (Chester Springs PA) Regina Anne C. (Coatesville PA), Alcohol resistant aqueous film forming firefighting foam.
Clark Kirtland P. (Bethel CT) Jacobson Michael (Greensboro NC) Jho Chang H. (Dobbs Ferry NY), Compositions for polar solvent fire fighting containing perfluoroalkyl terminated co-oligomer concentrates and polysacch.
Streit Werner (Bobenheim DEX) Bergold Wolfram (Heidelberg DEX) Bassing Dieter (Ludwigshafen DEX), Concentrated aqueous solutions of mixtures of organic complexing agents and dispersing agents based on polymeric aliphat.
Schimmel Karl F. ; Das Suryya K. ; Kilic Soner, Hydroxy-functional copolymer by reacting epoxy with .gtoreq.C8 monocarboxylic acid/dicarboxylic ester copolymer.
Sopko Thomas M. (Painesville OH) Lorentz Richard E. (Euclid OH), Method of using polymers of amido-sulfonic acid containing monomers and salts as drilling additive.
Chen Catherine S. H. (Berkeley Heights NJ) Sheppard Edward W. (Lambertville NJ), Oil recovery by waterflooding employing an anionic polymeric surfactant containing recurring succinimide or succinamide.
Chen Catherine S. H. (Berkeley Heights NJ) Sheppard Edward W. (Lambertville NJ), Oil recovery by waterflooding employing anionic polymeric surfactants.
Jennings John ; Deisenroth Ted ; Haniff Marlon, Poly-perfluoroalkyl substituted polyamines as grease proofing agents for paper and foam stabilizers in aqueous fire-fighting foams.
Leemans Luc E. (Diepenbeek BEX) Uytterhoeven Herman J. (Bonheiden BEX) Teyssi Philippe J. (Neuville en Condroz BEX) Fayt Roger M. (Neupre BEX) de Jaeger Nikolaas C. (Hove BEX), Polymeric surfactant.
Schade, Christian; Westenfelder, Horst; Sperling-Vietmeier, Karin; Sanner, Axel; Wekel, Hans-Ulrich, Use of crosslinked copolymers of monoethylenically unsaturated carboxylic acids as stabilizer in oil-in-water emulsions.
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