초록

High green strength reactive hot melt adhesives are prepared using relatively low levels of reactive acrylic, and may be prepared with liquid crystalline or crystalline diols.

대표청구항 ▼

The invention claimed: 1. A polyurethane hot melt adhesive composition comprising an isocyanate, a non-polymeric aromatic difunctional, and a thermoplastic polymer, wherein the non-polymeric aromatic difunctional comprises at least one liquid crystailine diol and wherein the thermoplastic polymer i

The invention claimed: 1. A polyurethane hot melt adhesive composition comprising an isocyanate, a non-polymeric aromatic difunctional, and a thermoplastic polymer, wherein the non-polymeric aromatic difunctional comprises at least one liquid crystailine diol and wherein the thermoplastic polymer is selected from the group consisting of acrylic polymers, functional acrylic polymers, non-functional acrylic polymers, hydroxy functional acrylic polymers, functional EVA and mixtures thereof, wherein the non-polymeric aromatic difunctional is selected from the group consisting of non-polymeric aromatic diols, non-polymeric aromatic dithiols, non-polymeric aromatic diamines, non-polymeric aromatic diacids and mixtures thereof. 2. The adhesive of claim 1, further comprising a thermoplastic polymer selected from the group consisting of polyvinyl acetate, polyvinyl chloride, methylene polyvinyl ether, cellulose acetate, styrene acrylonitrile, amorphous polyolefin, thermoplastic urethane, polyacrylonitrile, block copolymers, ethylenelacrylate copolymers, ethyl methacrylate, ethyl hexyl acrylate, ethylene-n-butyl acrylate, polybutadiene diol, ethylene butadiene, isobutylene dial, and mixtures thereof. 3. The adhesive of claim 1, further comprising a polyol. 4. The adhesive of claim 3, wherein the polyol is a polyether polyol. 5. The adhesive of claim 3, wherein the polyol is a polyester polyol. 6. The adhesive of claim 3, wherein the polyol is a mixture of a polyester polyol and a polyether polyol. 7. The adhesive of claim 1, wherein the liquid crystalline dial is selected from the group comprising Brilliant Yellow, Dispersed Red, and mixtures thereof. 8. The adhesive of claim 1, wherein the aromatic dial comprises a non-polymeric compound having a molecular weight lower than 2000. 9. The adhesive of claim 1, wherein the liould crystalline dial is selected from the group consisting of aminobenzyl alcohol; aminobenzylamine; amlnophenol, Bis(2-hydroxyethyl) terephthalate; 1,5-Diaminonaphthalene, 4-hydroxyphenethyl alocohol; 2-hydroxy-4-methoxybenzyl alcohol; hydroxybenzyl alcohol, 2-(2-Hydroxyethoxy)phenol, 3-(1-hydroxyethyl)aniline, 4-hydroxy-3-methoxybenzyl alcohol, Homovanillyl alcohol, 4-hydroxyphenethyl alcohol, 1,5-Dihydroxynaphthalene; 2',4'-Dihydroxybenzophenone; 4,4'-(Hexanfturoisopropylidene)diphenyl; 2,6-Dihydroxyanthraquinone; 1,5-Dihydroxynaphthalene (DHN); Diethylstilbestrol; 9H-Fluorene-9,9-dimethanol; Eosin B, spirit soluble; 5-tertbutyl-1,3-benzenedicarboxilic acid; 5-tert-Butyl-4-hydroxy-2-methylphenyl sulfide; 3-(4-Carboxylphenyl) 2,3-dihydro-1,1,3-trimethyl indene-5-carboxylic acid; 4,4'-di(aminophenyl)-9-fluorenylidene; 2',4-Dlhydroxyacetophenone; 6'-Butoxy-2,6-diamino-3,-3'-azodipyridine and 4,4'-(Hexanfiuroisopropylidene)diphenol and mixtures thereof. 10. The adhesive of claim 1, wherein the adhesive comprises from about 0.01 to about 80 wt % of the non-polymeric aromatic difunctional. 11. The adhesive of claim 10, wherein the adhesive comprises from about 0.5 wt % to about 20 wt % of the non-polymeric aromatic difunctional. 12. The adhesive of claim 1 further comprising one or more additives from the group comprising plasticizers, compatible tackifiers, curing catalysts, dIssocIation catalysts, fillers, anti-oxidants, pigments, adhesion promoters, stabilizers, aliphatic C5-C10 terpene oligomers, rosin, rosin derivatIves, rosin ester, aliphatic hydrocarbons, aromatic hydrocarbons aromatically modified aliphatic hydrocarbons, terpenes, terpene phenol, modified terpone, high molecular weight hindered phenols and multifunctional phenols such as sulfur and phosphorous-containing phenol, terpene oligomers, DMDEE, paraffin waxes, microcrystalline waxes, hydrogenated castor oil, and mixtures thereof. 13. An article of manufacture comprising the adhesive of claim 1. 14. A method of improving the green strength of a polyurethane adhesIve containing isocyanate. comprisIng adding an effective amount of a non-polymeric aromatic difunctional to an adhesive formulation, wherein the adhesive comprises a thermoplastic polymer selected from the group consisting of acrylic polymers, functional acrylic polymers, non-functional acrylic polymers, hydroxy functional acrylio polymers, functional EVA and mixtures thereof, wherein the non-polymeric aromatic difunctional comprises at least one liquid crystalline diol. 15. The method of claim 14, further comprising a thermoplastic polymer is selected from the group consisting of polyvinyl acetate, polyvinyl chloride, methylene polyvinyl ether, cellulose acetate, styrene acrylonitrile. amorphous polyolefin. thermoplastic urethane, polyacryloriltrile, block copolymers, ethylene/ecrylate copolymers, ethyl methacrylate. ethyl hexyl acrylate. ethylene-n-butyl acrylate, polybutadiene did, ethylene butadiene, isobutylene dial, and mixtures thereof. 16. The method of claim 14 wherein the non-polymeric aromatic difunctional is selected from the group consisting of non-polymeric aromatic dials, non-polymeric aromatic dithiols, non-polymeric aromatic diamines, non-polymeric aromatic diacids, and mixtures thereof. 17. The method of claim 14, further comprising a polyol. 18. The method of claim 17, wherein the polyol is a polyether polyol. 19. The method of claim 17, wherein the polyol is a polyester polyol. 20. The method of claim 17, wherein the polyol is a mixture of a polyester polyol and a polyether polyol. 21. The method of claim 14 wherein the liquid crystalline dial is selected from the group consisting of Brilliant Yellow, Dispersed Red, and mixtures thereof. 22. The method of claim 14, wherein the aromatic dial comprises a non-polymeric compound having a molecular weight lower than 2000. 23. The method of claim 14, wherein the liquid crystalline dial is selected from the group consisting of aminobenzyl alcohol; aminobenzylamine; aminophenol, Bis(2-hydroxyathyl)terephthalate; 1, 5-Diaminonaphthalene, 4-hydroxyphenethyl alocohol; 2,hydroxy-4-methoxybenzyl alcohol; hydroxybenzyl alcohol, 2-(2-Hydroxyethoxy)phenol, 3-(1-hydroxyethyl)anilirte, 4-hydroxy-3-methoxybenzyl alcohol, Homovanillyl alcohol, 4-hydroxyphenethyl alcohol, I 1,5-Dihydroxynaphthalene; 2',4'-Dihydroxybenzophenone; 4,4'-(Hexanfluroisopropylidene)diphenyl; 2,6-Dihydroxyanthraquinone; 1,5-Dihydroxynaphthalene (DHN): Diethyistilbestrol; 9H-Fluorene-9,9-dimethanol; Eosin B, spirit soluble; 5-tertbutyl-1,3-benzenedlcarboxilic acid; 5-tert-Butyl-4-hydroxy-2-methylphenyl sulfide; 3-(4-Carboxylphenyl) 2,3-dlhydro-1,1,3-trimethyl indene-5-carboxylic acid: 4,4'-di(amlnophenyl)-9-fluorenylidene; 2,4-Dihydroxyacetophenone; 6'-Butoxy-2,6-diamino-3,-3'-azodipyridine and 4,4-(Hexanfluroisopropylidene)diphenol and mixtures thereof. 24. The method of claim 14, wherein the adhesive comprises from about 0.01 to about 80 wt % of the non-polymeric aromatic difunctional. 25. The method of claim 24, wherein the adhesive comprises from about 0.5 to about 20 wt % of the non-polymeric aromatic difunctional. 26. The method of claim 14, wherein the adhesive further comprises one or more additives from the group comprising plasticizers, compatible tackifiers, curing catalysts, dissociation catalysts, fillers, anti-oxidants, pigments, adhesion promoters, stabilizers, aliphatic C 5-C10 terpene oligomers, rosin, rosin derivatives, rosin ester, aliphatic hydrocarbons, aromatic hydrocarbons aromatically modified aliphatlc hydrocarbons, terpenes, terpene phenol, modified terpene, high molecular weight hindered phenols and multifunctional phenols such as sulfur and phosphorous-containing phenol, terpene oligomers, DMDEE. paraffin waxes, microcrystalline waxes, hydrogenated castor oil, and mixtures thereof. 27. A method of bonding materials together which comprises applying a polyurethane hot melt adhesive composition comprising an isocyanate, a non-polymeric aromatic diol, and a thermoplastic polymer selected from the group consisting of acrylic polymers, functional acrylic polymers, non-functional acrylic polymers, hydroxy functional acrylic polymers, functional EVA and mixtures thereof, wherein the non . polymeric aromatic dial comprises at least one liquid crystalline dial, in a liquid form to a first substrate, bringing a second substrate In contact with the composition applied to the first substrate, and subjecting the composItions to conditions which will allow the compositions to cool and cure to an irreversible solid form, the conditions comprising moisture. 28. The method of claim 27, wherein the liquid crystalline dial is selected from the group consisting of Brilliant Yellow, Dispersed Red and mixtures thereof. 29. The method of claim 27, wherein the aromatic diol comprises a non-polymeric compound having a molecular weight lower than 2000. 30. The method of claim 27, wherein the liouid crystalline diol is selected from the group consisting of.aminobenzyl alcohol; aminobenzylamine; aminophenol, Bis(2-hydroxyethyl) terephthalate; 1,5-Diaminonaphthalene, 4-hydroxyphenethyl alcohol; 2-hydroxy-4-methoxybenzyl alcohol; hydroxybertzyl alcohol, 2-(2-Hydroxyethoxy)phenol, 3-(1-hydroxyethyi)anhline, 4-hydroxy-3-methoxybenzyl alcohol, Homovanillyl alcohol, 4-hydroxyphenethyl alcohol, 1,5-Dihydroxynaphthalene; 2,4'-Oihydroxybenzophenone; 4,4'-(Hexanfluroisopropylidene)diphenyl; 2,6-Dihydroxyanthraquinone; 1,5-Dihydroxynaphthalene (DHN); Diethyistilbestrol; 9H-Fluorene-9,9-dimethanol; Eosin B, spirit soluble; 5-tertbutyl-1,3-benzenedicarboxilic acid; 5-tert-Butyi-4-hydroxy-2-methylphenyl sulfide; 3-(4-Carboxylphenyl) 2,3-dihydro-1,1,3-trimethyl indene-5-carboxylic acid; 4,4'-di(aminophenyl)-9-fiuorenyugdene; 2',4'-Dihydroxyacetophenone; 6'-Butoxy-2,6-diamino-3,-3'-azodipyridine and 4,4-(Hexanfluroisopropylidene)diphenol and mixtures thereof. 31. The method of claim 27, wherein the adhesive comprises from about 0.01 to about 80 wt % of the non-polymeric aromatic diol. 32. The method of claim 31, wherein the adhesive comprises from about 0.5 to about 20 wt % of the non-polymeric aromatic dial. 33. The method of claim 28 wherein the adhesive comprises a non-functional acrylic polymer. 34. The method of claim 28 wherein the adhesive comprises a functional acrylic polymer. 35. The method of claim 34 wherein the functional acrylic polymer is a hydroxy functional polymer.