[미국특허]
Bonding of cement paste to porcelain shaped articles through the use of ceramic glazes
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C04B-014/00
C04B-014/22
C04B-014/02
출원번호
US-0191107
(2005-07-27)
발명자
/ 주소
Carty,William M.
Sheppard,Michael Q.
출원인 / 주소
Carty,William M.
Sheppard,Michael Q.
대리인 / 주소
Bingham McHale LLP
인용정보
피인용 횟수 :
2인용 특허 :
21
초록▼
A method for increasing the strength of concrete, including applying a coating of high-silica glaze to porcelain aggregate pieces, dispersing the glaze-coated porcelain aggregate pieces in a Portland cement matrix, bonding the high-silica glaze to the porcelain aggregate pieces, bonding the high-sil
A method for increasing the strength of concrete, including applying a coating of high-silica glaze to porcelain aggregate pieces, dispersing the glaze-coated porcelain aggregate pieces in a Portland cement matrix, bonding the high-silica glaze to the porcelain aggregate pieces, bonding the high-silica glaze to the Portland cement matrix, and curing the Portland cement matrix to yield high-strength concrete. The high-silica glaze further include silica and flux. The molar ratio of silica to flux is at least about 5 to 1 and the flux further comprises RO and R2O. The molar ratio of RO to R2O is at least about 7 to 3. RO is selected from the group including CaO, SrO, BaO, ZnO, FeO, PbO and their combinations and R2O is selected from the group including Li2O, Na2O, K2O, and their combinations.
대표청구항▼
The invention claimed is: 1. A method for strengthening concrete, comprising: a) applying a coating of reactive glaze to aggregate pieces; b) dispersing the glaze-coated aggregate pieces in a cementitious matrix; c) bonding the glaze to the aggregate pieces; d) bonding the glaze to the cementitiou
The invention claimed is: 1. A method for strengthening concrete, comprising: a) applying a coating of reactive glaze to aggregate pieces; b) dispersing the glaze-coated aggregate pieces in a cementitious matrix; c) bonding the glaze to the aggregate pieces; d) bonding the glaze to the cementitious matrix; and e) curing the cementitious matrix to yield concrete; wherein the glaze both chemically and mechanically bonds to the cementitious matrix; wherein the glaze is substantially silica and flux; and wherein the molar ratio of silica to flux is at least about 5 to 1. 2. The method of claim 1 wherein the aggregate pieces are porcelain; wherein the cementitious matrix is Portland cement; and wherein the glaze is substantially silica and flux and wherein the molar ratio of silica to flux is at least about 9 to 1. 3. The method of claim 2 wherein the flux is substantially calcia. 4. The method of claim 3 wherein the flux is about 90 percent calcia and about 10 percent R2O and wherein R is chosen from the group including lithium, sodium and potassium. 5. The method of claim 1 wherein the glaze coating is about 50 microns thick. 6. The method of claim 1 wherein the glaze coating is less than about 250 microns thick. 7. The method of claim 1 wherein the glaze is bonded to the aggregate pieces by firing the coated aggregate pieces to a temperature of at least about 1150 degrees Celsius. 8. A strengthened concrete comprising: an aggregate phase; a cementitious matrix phase; and a glaze phase bonded between the aggregate phase and the cementitious matrix phase; wherein the aggregate phase defines a plurality of aggregate pieces dispersed in the cementitious matrix phase; wherein the aggregate phase is porcelain; wherein the cementitious matrix phase is Portland cement; wherein the glaze phase is substantially silica and flux; and wherein the molar ratio of silica to flux is at least about 5 to 1. 9. The concrete of claim 8 wherein the flux further includes calcia and R2O; wherein the flux is about 90 mole percent calcia and about 10 mole percent R2O; and wherein R is selected from the group including lithium, sodium and potassium. 10. The concrete of claim 9 wherein the flux further includes calcia and R2O; wherein the flux is about 70 mole percent calcia and about 30 mole percent R2O; and wherein R is selected from the group including lithium, sodium and potassium. 11. The concrete of claim 8 wherein the aggregate phase is porcelain; wherein the cementitious matrix phase is Portland cement; wherein the glaze phase is substantially silica, alumina and flux; wherein the molar ratio of silica to flux is at least about 5 to 1 and wherein the molar ratio of flux to alumina is about 5:1. 12. The concrete of claim 8 wherein the aggregate pieces are all substantially the same size and wherein the aggregate pieces substantially all have the shape of a tetrajack. 13. A method for increasing the strength of concrete, comprising: a) applying a coating of high-silica glaze to porcelain aggregate pieces; b) dispersing the glaze-coated porcelain aggregate pieces in a Portland cement matrix; c) firing the porcelain aggregate pieces to bond the high-silica glaze thereto; d) bonding the high-silica glaze to the Portland cement matrix; and e) curing the Portland cement matrix to yield high-strength concrete; wherein the high-silica glaze further comprises silica and flux; wherein the molar ratio of silica to flux is at least about 5 to 1; wherein the flux further comprises RO and R2O; wherein the molar ratio of RO to R2O is at least about 7 to 3; wherein RO is selected from the group including CaO, SrO, BaO, ZnO, FeO, PbO and their combinations; and wherein R2O is selected from the group including Li2O, Na2O, K2O, and their combinations. 14. The method of claim 13 wherein the glaze is substantially silica, alumina and flux and wherein the molar ratio of flux to alumina is about 5:1. 15. The method of claim 13 wherein the aggregate pieces are all substantially the same size and wherein the aggregate pieces substantially all have the shape of a tetrajack. 16. The method of claim 13 wherein the glaze-coated porcelain pieces are fired to a temperature of at least about 1150 degrees Celsius to bond the high-silica glaze thereto. 17. A high-strength concrete, comprising: a porcelain aggregate phase; a Portland cement matrix phase; and a high-silica glaze phase bonded between the porcelain aggregate phase and the Portland cement matrix phase; wherein the porcelain aggregate phase defines a plurality of porcelain pieces dispersed in the Portland cement matrix phase; wherein the high-silica glaze phase further comprises silica and flux; wherein the molar ratio of silica to flux is at least about 5 to 1; wherein the flux further comprises RO and R2O; wherein the molar ratio of RO to R2O is at least about 7 to 3; wherein RO is selected from the group including CaO, SrO, BaO, ZnO, FeO, PbO and their combinations; wherein R2O is selected from the group including Li2O, Na2O, K2O, and their combinations; wherein the aggregate pieces are all substantially the same size; and wherein the aggregate pieces substantially all have the shape of a tetrajack. 18. A method of producing a high-strength cement-aggregate bond, comprising: a) identifying a first porcelain surface and a cementitious second surface to be bonded together; b) treating the first porcelain surface by glazing a bonding layer thereto; c) preparing the first porcelain surface for bonding by firing the first porcelain surface to a temperature of at least about 1150 degrees Celsius; and d) joining the prepared first porcelain surface and the cementitious second surface chemically in the bonding layer; wherein the bonding layer is a glaze having the general formula of (0.1 R2O, 0.9 RO).6.0 SiO2; wherein R2O is selected from the group consisting of Li2O, Na2O, K2O, and their combinations; and wherein RO is selected from the group consisting of CaO, SrO, BaO, ZnO, FeO, PbO and their combinations.
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