초록

Process for making both ACN and HMD from partial hydrogenation of ADN by using a combination of distillations resulting in the formation of a mixture of HMD and THA that can be hydrogenated to produce a mixture of HMD and HMI that can be separated easily by simple distillation.

대표청구항 ▼

What is claimed is: 1. A process for co-producing HMD and ACN from ADN, wherein the HMD contains less than 200 ppm THA, said process comprising the steps of: (1) contacting ADN and hydrogen in the presence of a hydrogenation catalyst to produce a reaction product that comprises HMD, ACN, THA, and u

What is claimed is: 1. A process for co-producing HMD and ACN from ADN, wherein the HMD contains less than 200 ppm THA, said process comprising the steps of: (1) contacting ADN and hydrogen in the presence of a hydrogenation catalyst to produce a reaction product that comprises HMD, ACN, THA, and unreacted ADN; (2) distilling the reaction product to provide a distillate that comprises HMD and THA; (3) contacting the distillate with hydrogen in the presence of a hydrogenation catalyst, thereby providing a hydrogenation product that comprises HMD and HMI, said hydrogenation product containing less than 200 ppm THA; and (4) distilling the hydrogenation product to provide a final distillate that comprises HMI and a bottoms that comprises HMD that contains less than 200 ppm THA and is substantially free of HMI. 2. The process of claim 1 wherein the hydrogenation catalyst of step (3) is Raney Nickel or Raney Cobalt.