초록 ▼

Carbon-silicon carbide brake preforms are manufactured by carbonizing a blend of carbon (e.g., polyacrylonitrile) fibers and thermosetting pitch resin, optionally along with a lubricant such as graphite,.to provide an intermediate product having open porosity and subsequently filling the pores of th

Carbon-silicon carbide brake preforms are manufactured by carbonizing a blend of carbon (e.g., polyacrylonitrile) fibers and thermosetting pitch resin, optionally along with a lubricant such as graphite,.to provide an intermediate product having open porosity and subsequently filling the pores of the intermediate product with silicon by a melt infiltration process. Molded articles that consist principally of carbon, that have relatively high strength and resistance to decomposition by frictional heat, and that are suitable for melt infiltration with silicon, are produced by, e.g.: coating randomly oriented polyacrylonitrile-derived carbon fibers, optionally mixed with finely divided carbon powder, with a thermosetting blend of (a) pitch and (b) an organic medium, at an elevated temperature to form a viscous molding compound; molding the compound at a low pressure and elevated temperature so that a solid compact is obtained; stripping a molded article made of said compound from the mold; optionally heating the molded article at gradually increasing temperatures to insure complete condensation within the article; and carbonizing the condensed molded article in an inert atmosphere at gradually increasing temperatures to produce a molded C/C intermediate article suitable for melt-infiltration with silicon. The preforms may be configured in the form of a disc brake rotor or a disc brake pad.

대표청구항 ▼

What is claimed is: 1. A process for manufacturing a brake lining made of a fiber-reinforced ceramic C/SiC material, comprising: producing a mixture of organic carbon fibers and pitch resin mixture; pressing the mixture to form a green compact; pyrolyzing the green compact to form a porous C/C body

What is claimed is: 1. A process for manufacturing a brake lining made of a fiber-reinforced ceramic C/SiC material, comprising: producing a mixture of organic carbon fibers and pitch resin mixture; pressing the mixture to form a green compact; pyrolyzing the green compact to form a porous C/C body in which the organic carbon fibers are at least partially sheathed by pitch; and infiltrating the C/C body with liquid silicon so that a portion of the carbon randomly distributed throughout the C/C body becomes silicon carbide, thereby forming a friction material suitable for use as a brake lining, said material comprising a compressed and charred mixture of 30-70 parts by weight of a C/SiC friction material and 30-70 parts by weight of carbonized organic carbon fibers protected by pitch-based resin char. 2. The process of claim 1, wherein the pitch resin mixture comprises a blend of coal tar pitch and furfuryl alcohol. 3. A process for manufacturing a fiber-reinforced ceramic C/SiC brake lining material, said process comprising sequentially: (a) forming a pitch resin mixture; (b) treating said pitch resin mixture with an acidic catalyst to form an acidified pitch resin binder mixture; (c) adding organic carbon fibers and a friction-modifying constituent to said acidified pitch resin binder mixture to form a mixture of organic carbon fibers and pitch resin mixture; (d) pressing the fiber-containing pitch resin mixture to form a green compact; (e) pyrolyzing the green compact to form a porous C/C body having organic carbon fibers that are at least partially sheathed by pitch; and (f) infiltrating the C/C body with liquid silicon so that a portion of the carbon that is randomly distributed throughout the C/C body becomes silicon carbide; thereby forming a friction material suitable for use as a brake lining, said material comprising a compressed and charred mixture of 30-70 parts by weight of a C/SiC friction material, up to 30 parts by weight of a friction-modifying constituent, and 20-45 parts by weight of carbonized organic carbon fibers protected by pitch-based resin char. 4. The process of claim 3, wherein said friction-modifying constituent is a graphite powder. 5. The process of claim 3, wherein, after pyrolyzing, the organic carbon fibers are carbonized organic carbon fibers selected from the group consisting of carbonized cellulose, rayon, and polyacrylontrile fibers. 6. The process of claim 3, wherein the pitch resin mixture comprises a blend of coal tar pitch and furfuryl alcohol. 7. The process of claim 3, wherein the acidic catalyst comprises toluene sulfonic acid.