[미국특허]
Polyester process using a pipe reactor
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C08G-063/02
C08G-063/00
C08G-085/00
B22D-011/01
출원번호
US-0456448
(2003-06-06)
발명자
/ 주소
DeBruin,Bruce Roger
Martin,Daniel Lee
출원인 / 주소
Eastman Chemical Company
인용정보
피인용 횟수 :
23인용 특허 :
112
초록▼
There are disclosed polyester processes using a pipe reactor and corresponding apparatuses. In particular, there are disclosed processes and corresponding apparatuses including an esterification pipe reactor with a recirculating reaction zone (RR zone) and a plug reaction profile reaction zone (PRPR
There are disclosed polyester processes using a pipe reactor and corresponding apparatuses. In particular, there are disclosed processes and corresponding apparatuses including an esterification pipe reactor with a recirculating reaction zone (RR zone) and a plug reaction profile reaction zone (PRPR zone), especially when operated with a significant part of the overall conversion taking place in the plug reaction profile reaction zone (PRPR zone).
대표청구항▼
What is claimed is: 1. A process for making a pre-polyester comprising: providing an esterification pipe reactor comprising a pipe, the pipe having an inlet and an outlet; adding a solubilizing agent into the pipe; and reacting one or more reactants flowing in the pipe towards the outlet under este
What is claimed is: 1. A process for making a pre-polyester comprising: providing an esterification pipe reactor comprising a pipe, the pipe having an inlet and an outlet; adding a solubilizing agent into the pipe; and reacting one or more reactants flowing in the pipe towards the outlet under esterification reaction conditions to form the pre-polyester, with the pipe also having a recirculation reaction zone (RR zone) and a plug reaction profile reaction zone (PRPR zone) with the RR zone being closer to the inlet than the PRPR zone is. 2. The process of claim 1 wherein the pipe is substantially empty. 3. A process comprising: performing the process according to claim 1 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 4. The process of claim 3 wherein the step of reacting under polycondensation reaction conditions is carried out in a polycondensation pipe reactor. 5. A process comprising: performing the process according to claim 2 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 6. The process of claim 5 wherein the step of reacting under polycondensation reaction conditions is carried out in a polycondensation pipe reactor. 7. The process of claim 1 wherein the solubilizing agent comprises a polyester oligomer. 8. The process of claim 2 wherein the solubilizing agent comprises a polyester oligomer. 9. A process comprising: performing the process according to claim 7 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 10. The process of claim 9 wherein the step of reacting under polycondensation reaction conditions is carried out in a polycondensation pipe reactor. 11. A process comprising: performing the process according to claim 8 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 12. The process of claim 11 wherein the step of reacting under polycondensation reaction conditions is carried out in a polycondensation pipe reactor. 13. The process of claim 7 wherein the ratio of the mass flow rate of the solubilizing agent added to the pipe to the mass flow of the material leaving the pipe and not being recycled back to the pipe is from 2:1 to 25:1. 14. The process of claim 8 wherein the ratio of the mass flow rate of the solubilizing agent added to the pipe to the mass flow of the material leaving the pipe and not being recycled back to the pipe is from 2:1 to 25:1. 15. A process comprising: performing the process according to claim 13 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 16. A process comprising: performing the process according to claim 14 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 17. The process of claim 7 wherein the ratio of the mass flow rate of the solubilizing agent added to the RR zone to the mass flow of the material leaving the RR zone and not being recycled back to the RR zone is from 2:1 to 25:1. 18. The process of claim 8 wherein the ratio of the mass flow rate of the solubilizing agent added to the RR zone to the mass flow of the material leaving the RR zone and not being recycled back to the RR zone is from 2:1 to 25:1. 19. A process comprising: performing the process according to claim 17 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 20. A process comprising: performing the process according to claim 18 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 21. The process of claim 1 wherein the reactants forming the pre-polyester comprise a diacid, a diol, a diester, a hydroxy ester, an acid ester, a hydroxy acid or combinations thereof. 22. The process of claim 2 wherein the reactants forming the pre-polyester comprise a diacid, a diol, a diester, a hydroxy ester, an acid ester, a hydroxy acid or combinations thereof. 23. A process comprising: performing the process according to claim 21 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 24. The process of claim 23 wherein the step of reacting under polycondensation reaction conditions is carried out in a polycondensation pipe reactor. 25. A process comprising: performing the process according to claim 22 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 26. The process of claim 25 wherein the step of reacting under polycondensation reaction conditions is carried out in a polycondensation pipe reactor. 27. The process of claim 1 wherein the reactants forming the pre-polyester comprise terephthalic acid, dimethyl terephthalate, cyclohexane dimethanol, isophthalic acid, ethylene glycol or combinations thereof. 28. The process of claim 2 wherein the reactants forming the pre-polyester comprise terephthalic acid, dimethyl terephthalate, cyclohexane dimethanol, isophthalic acid, ethylene glycol or combinations thereof. 29. A process comprising: performing the process according to claim 27 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 30. The process of claim 29 wherein the step of reacting under polycondensation reaction conditions is carried out in a polycondensation pipe reactor. 31. A process comprising: performing the process according to claim 28 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 32. The process of claim 31 wherein the step of reacting under polycondensation reaction conditions is carried out in a polycondensation pipe reactor. 33. The process of claim 3 wherein the polyester is polyethylene terephthalate or polyethylene terephthalate modified with cyclohexane dimethanaol. 34. The process of claim 5 wherein the polyester is polyethylene terephthalate or polyethylene terephthalate modified with cyclohexane dimethanaol. 35. The process of claim 1 wherein the average solids content of the material flowing through the outlet of the RR zone of the pipe is less than 2.5 weight percent. 36. The process of claim 2 wherein the average solids content of the material flowing through the outlet of the RR zone of the pipe is less than 2.5 weight percent. 37. A process comprising: performing the process according to claim 35 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 38. The process of claim 37 wherein the step of reacting under polycondensation reaction conditions is carried out in a polycondensation pipe reactor. 39. A process comprising: performing the process according to claim 36 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 40. The process of claim 39 wherein the step of reacting under polycondensation reaction conditions is carried out in a polycondensation pipe reactor. 41. The process of claim 1 wherein the conversion in the product of the RR zone of the pipe is 75 to 95 percent. 42. The process of claim 2 wherein the conversion in the product of the RR zone of the pipe is 75 to 95 percent. 43. A process comprising: performing the process according to claim 41 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 44. The process of claim 43 wherein the step of reacting under polycondensation reaction conditions is carried out in a polycondensation pipe reactor. 45. A process comprising: performing the process according to claim 42 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 46. The process of claim 45 wherein the step of reacting under polycondensation reaction conditions is carried out in a polycondensation pipe reactor. 47. The process of claim 27 wherein the conversion in the product of the RR zone of the pipe is 75 to 95 percent. 48. The process of claim 28 wherein the conversion in the product of the RR zone of the pipe is 75 to 95 percent. 49. A process comprising: performing the process according to claim 47 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 50. A process comprising: performing the process according to claim 48 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 51. The process of claim 35 wherein operating conditions in the pipe are such that conversion at the outlet of the PRPR zone is greater than or equal to 1.08 times the conversion at the outlet of the RR zone. 52. The process of claim 36 wherein operating conditions in the pipe are such that conversion at the outlet of the PRPR zone is greater than or equal to 1.08 times the conversion at the outlet of the RR zone. 53. A process comprising: performing the process according to claim 51 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 54. The process of claim 53 wherein the step of reacting under polycondensation reaction conditions is carried out in a polycondensation pipe reactor. 55. A process comprising: performing the process according to claim 52 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 56. The process of claim 55 wherein the step of reacting under polycondensation reaction conditions is carried out in a polycondensation pipe reactor. 57. The process of claim 17 wherein the reactants forming the pre-polyester comprise terephthalic acid, dimethyl terephthalate, cyclohexane dimethanol, isophthalic acid, ethylene glycol or combinations thereof. 58. The process of claim 18 wherein the reactants forming the pre-polyester comprise terephthalic acid, dimethyl terephthalate, cyclohexane dimethanol, isophthalic acid, ethylene glycol or combinations thereof. 59. A process comprising: performing the process according to claim 57 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 60. A process comprising: performing the process according to claim 58 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 61. The process of claim 57 wherein the average solids content of the material flowing through the outlet of the RR zone of the pipe is less than 2.5 weight percent. 62. The process of claim 58 wherein the average solids content of the material flowing through the outlet of the RR zone of the pipe is less than 2.5 weight percent. 63. A process comprising: performing the process according to claim 61 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 64. A process comprising: performing the process according to claim 62 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 65. The process of claim 57 wherein the conversion in the product of the RR zone of the pipe is 75 to 95 percent. 66. The process of claim 58 wherein the conversion in the product of the RR zone of the pipe is 75 to 95 percent. 67. A process comprising: performing the process according to claim 65 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 68. A process comprising: performing the process according to claim 66 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 69. The process of claim 61 wherein operating conditions in the pipe are such that conversion at the outlet of the PRPR zone is greater than or equal to 1.08 times the conversion at the outlet of the RR zone. 70. The process of claim 62 wherein operating conditions in the pipe are such that conversion at the outlet of the PRPR zone is greater than or equal to 1.08 times the conversion at the outlet of the RR zone. 71. A process comprising: performing the process according to claim 69 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 72. A process comprising: performing the process according to claim 70 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 73. The process of claim 70 wherein the conversion in the product of the RR zone of the pipe is 75 to 95 percent. 74. A process comprising: performing the process according to claim 73 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 75. The process of claim 74 wherein the step of reacting under polycondensation reaction conditions is carried out in a polycondensation pipe reactor. 76. The process of claim 1 further comprising removing vapor from inside the pipe. 77. The process of claim 2 further comprising removing vapor from inside the pipe. 78. The process of claim 1 further comprising removing vapor from inside the RR zone. 79. The process of claim 2 further comprising removing vapor from inside the RR zone. 80. The process of claim 1 wherein at least one of the RR and PRPR zones has froth or stratified flow appearing. 81. The process of claim 2 wherein at least one of the RR and PRPR zones has froth or stratified flow appearing. 82. The process of claim 1 wherein the solubilizing agent is added at least in part from a tank. 83. The process of claim 2 wherein the solubilizing agent is added at least in part from a tank. 84. The process of claim 1 wherein the solubilizing agent is at least in part from the outlet of the RR zone. 85. The process of claim 2 wherein the solubilizing agent is at least in part from the outlet of the RR zone. 86. The process of claim 1 wherein the solubilizing agent is at least in part a product of a polyester polycondensation reactor. 87. The process of claim 2 wherein the solubilizing agent is at least in part a product of a polyester polycondensation reactor. 88. An apparatus for making a pre-polyester comprising: an esterification pipe reactor comprising a pipe, the pipe having an inlet, an outlet and means for addition of a solubilizing agent, and wherein pre-polyester forming reactants are passed towards the outlet, with the pipe also having a recirculation reaction zone (RR zone) and a plug reaction profile reaction zone (PRPR zone) with the RR zone being closer to the inlet than the PRPR zone is. 89. The apparatus of claim 88 wherein the pipe is substantially empty. 90. An apparatus comprising: the apparatus of claim 88; and a polycondensation reactor connected to the outlet of the pipe. 91. The apparatus of claim 90 wherein the polycondensation reactor is a polycondensation pipe reactor. 92. An apparatus comprising: the apparatus of claim 89; and a polycondensation reactor connected to the outlet of the pipe. 93. The apparatus of claim 92 wherein the polycondensation reactor is a polycondensation pipe reactor. 94. The apparatus of claim 88 further comprising means for vapor removal along the pipe. 95. The apparatus of claim 89 further comprising means for vapor removal along the pipe. 96. An apparatus comprising: the apparatus of claim 94; and a polycondensation reactor connected to the outlet of the pipe. 97. An apparatus comprising: the apparatus of claim 95; and a polycondensation reactor connected to the outlet of the pipe. 98. The apparatus of claim 88 wherein the means for addition of a solubilizing agent is into the RR zone. 99. The apparatus of claim 89 wherein the means for addition of a solubilizing agent is into the RR zone. 100. An apparatus comprising: the apparatus of claim 98; and a polycondensation reactor connected to the outlet of the pipe. 101. An apparatus comprising: the apparatus of claim 99; and a polycondensation reactor connected to the outlet of the pipe. 102. The apparatus of claim 88 further comprising a solids detector connected to the outlet of the RR zone. 103. The apparatus of claim 89 further comprising a solids detector connected to the outlet of the RR zone. 104. An apparatus comprising: the apparatus of claim 102; and a polycondensation reactor connected to the outlet of the pipe. 105. An apparatus comprising: the apparatus of claim 103; and a polycondensation reactor connected to the outlet of the pipe. 106. The apparatus of claim 89 further comprising a solids detector connected to the outlet of the RR zone and means for vapor removal along the pipe and wherein the means for addition of a solubilizing is into the RR zone. 107. An apparatus comprising: the apparatus of claim 106; and a polycondensation reactor connected to the outlet of the pipe. 108. The apparatus of claim 107 wherein the polycondensation reactor is a polycondensation pipe reactor. 109. A process comprising: (a) esterifying a reaction mixture flowing through a first pipe reactor zone to thereby form an esterification reaction product; (b) separating said esterification reaction product into a recycle portion and a non-recycle portion at a separating location; and (c) introducing at least a portion of said recycle portion into at least a portion of said reaction mixture at a location upstream of said separating location. 110. The process of claim 109, wherein said process further comprises transporting said recycle portion introduced into said reaction mixture through at least a portion of said first pipe reactor zone, 111. The process of claim 109, wherein said process further comprises subjecting said non-recycle portion of said esterification reaction product to further reaction. 112. The process of claim 111, wherein said further reaction comprises esterification and/or polycondensation. 113. The process of claim 111, wherein said further reaction comprises esterification in a second pipe reactor zone. 114. The process of claim 113, wherein the esterification in said second pipe reactor zone provides a greater conversion than the esterification said first pipe reactor zone. 115. The process of claim 114, wherein the conversion in said second pipe reactor zone is at least 1.08 times the conversion in the first pipe reactor zone. 116. The process of claim 113, wherein said first and second pipe reactor zones are defined by a single pipe reactor. 117. The process of claim 113, wherein said first pipe reactor zone is a recirculation reaction zone (RR zone) and said second pipe reactor zone is a plug reaction profile reaction zone (PRPR zone). 118. The process of claim 113, wherein said reaction mixture flows through at least a portion of said second pipe reactor zone in plug, stratified, and/or froth flow. 119. The process of claim 109, wherein the ratio of the mass flow rate of recycled portion to the non-recycled portion is in the range of from 2:1 to 25:1. 120. The process of claim 109, wherein said recycle portion contains less than 2.5 weight percent solids. 121. The process of claim 109, wherein said reaction mixture comprises a reactant in the form of solid particles. 122. The process of claim 121, wherein said recycle portion of said reaction product aids in the dissolution of said solid particles. 123. The process of claim 109, wherein said reaction mixture flows through at least a portion of said first pipe reactor zone in stratified and/or froth flow. 124. The process of claim 109, wherein said reaction mixture contains reactants selected from the group consisting of dicarboxylic acids, diols, diesters, hydroxyl esters, carboxylic acid esters, hydroxyl carboxylic acids, tricarboxylic acids, and combinations thereof. 125. The process of claim 109, wherein said reaction mixture contains terephthalic acid and ethylene glycol. 126. The process of claim 13, wherein the ratio of the mass flow rate of the solubilizing agent added to the pipe to the mass flow of the material leaving the pipe and not being recycled back to the pipe is from 3:1 to 20:1. 127. The process of claim 14, wherein the ratio of the mass flow rate of the solubilizing agent added to the pipe to the mass flow of the material leaving the pipe and not being recycled back to the pipe is from 3:1 to 20:1. 128. The process of claim 17, wherein the ratio of the mass flow rate of the solubilizing agent added to the RR zone to the mass flow of the material leaving the RR zone and not being recycled back to the RR zone is from 3:1 to 20:1. 129. The process of claim 18, wherein the ratio of the mass flow rate of the solubilizing agent added to the RR zone to the mass flow of the material leaving the RR zone and not being recycled back to the RR zone is from 3:1 to 20:1. 130. The process of claim 35, wherein the average solids content of the material flowing through the outlet of the RR zone of the pipe is less than 0.5 weight percent. 131. The process of claim 36, wherein the average solids content of the material flowing through the outlet of the RR zone of the pipe is less than 0.5 weight percent. 132. The process of claim 41, wherein the conversion in the product of the RR zone of the pipe is 80 to 95 percent. 133. The process of claim 132, wherein the conversion in the product of the RR zone of the pipe is 80 to 90 percent. 134. The process of claim 42, wherein the conversion in the product of the RR zone of the pipe is 80 to 95 percent. 135. The process of claim 134, wherein the conversion in the product of the RR zone of the pipe is 80 to 90 percent. 136. The process of claim 47, wherein the conversion in the product of the RR zone of the pipe is 80 to 95 percent. 137. The process of claim 136, wherein the conversion in the product of the RR zone of the pipe is 80 to 90 percent. 138. The process of claim 48, wherein the conversion in the product of the RR zone of the pipe is 80 to 95 percent. 139. The process of claim 138, wherein the conversion in the product of the RR zone of the pipe is 80 to 90 percent. 140. The process of claim 51, wherein operating conditions in the pipe are such that conversion at the outlet of the PRPR zone is greater than or equal to 1.10 times the conversion at the outlet of the RR zone. 141. The process of claim 140, wherein operating conditions in the pipe are such that conversion at the outlet of the PRPR zone is greater than or equal to 1.15 times the conversion at the outlet of the RR zone. 142. The process of claim 52, wherein operating conditions in the pipe are such that conversion at the outlet of the PRPR zone is greater than or equal to 1.10 times the conversion at the outlet of the RR zone. 143. The process of claim 142, wherein operating conditions in the pipe are such that conversion at the outlet of the PRPR zone is greater than or equal to 1.15 times the conversion at the outlet of the RR zone. 144. The process of claim 61, wherein the average solids content of the material flowing through the outlet of the RR zone of the pipe is less than 0.5 weight percent. 145. The process of claim 62, wherein the average solids content of the material flowing through the outlet of the RR zone of the pipe is less than 0.5 weight percent. 146. The process of claim 65, wherein the conversion in the product of the RR zone of the pipe is 80 to 95 percent. 147. The process of claim 146, wherein the conversion in the product of the RR zone of the pipe is 80 to 90 percent. 148. The process of claim 66, wherein the conversion in the product of the RR zone of the pipe is 80 to 95 percent. 149. The process of claim 148, wherein the conversion in the product of the RR zone of the pipe is 80 to 90 percent. 150. The process of claim 69, wherein operating conditions in the pipe are such that conversion at the outlet of the PRPR zone is greater than or equal to 1.10 times the conversion at the outlet of the RR zone. 151. The process of claim 150, wherein operating conditions in the pipe are such that conversion at the outlet of the PRPR zone is greater than or equal to 1.15 times the conversion at the outlet of the RR zone. 152. The process of claim 70, wherein operating conditions in the pipe are such that conversion at the outlet of the PRPR zone is greater than or equal to 1.10 times the conversion at the outlet of the RR zone. 153. The process of claim 152, wherein operating conditions in the pipe are such that conversion at the outlet of the PRPR zone is greater than or equal to 1.15 times the conversion at the outlet of the RR zone. 154. The process of claim 69, wherein the conversion in the product of the RR zone of the pipe is 75 to 95 percent. 155. The process of claim 154, wherein the conversion in the product of the RR zone of the pipe is 80 to 95 percent. 156. The process of claim 155, wherein the conversion in the product of the RR zone of the pipe is 80 to 90 percent. 157. The process of claim 73, wherein the conversion in the product of the RR zone of the pipe is 80 to 95 percent. 158. The process of claim 157, wherein the conversion in the product of the RR zone of the pipe is 80 to 90 percent. 159. A process comprising: performing the process according to claim 154 to make a pre-polyester; and reacting the pre-polyester and optionally other reactants, under polycondensation reaction conditions. 160. The process of claim 159, wherein the step of reacting under polycondensation reaction conditions is carried out in a polycondensation pipe reactor. 161. The apparatus of claim 88 further comprising a solids detector connected to the outlet of the RR zone and means for vapor removal along the pipe and wherein the means for addition of a solubilizing is into the RR zone. 162. An apparatus comprising: the apparatus of claim 161; and a polycondensation reactor connected to the outlet of the pipe. 163. The apparatus of claim 162, wherein the polycondensation reactor is a polycondensation pipe reactor. 164. The process of claim 109, wherein the conversion in the second pipe reactor zone at least 1.10 times the conversion in the first pipe reactor zone. 165. The process of claim 164, wherein the conversion in the second pipe reactor zone at least 1.15 times the conversion in the first pipe reactor zone. 166. The process of claim 119, wherein the ratio of the mass flow rate of recycled portion to the non-recylced portion is RR zone and not being recycled back to the RR zone is from 3:1 to 20:1. 167. The process of claim 35, wherein the average solids content of the material flowing through the outlet of the RR zone of the pipe is less than 0.5 weight percent.
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Muschelknautz Edgar (Leverkusen DEX) Vogelsgesang Roland (Leverkusen DEX) Ohse Helmut (Dormagen DEX) Westermann Hans (Marl DEX) Mller Eckhard (Marl DEX) Hachmann Klaus (Marl DEX) Schiemann Wilhelm (M, Process for the production of polyesters.
Chisholm, Robert D.; Beck, Debrah A.; Steward, John B.; Johnston, Jordan M.; Lee, Baosheng, Process for treatment of aqueous environments containing a water soluble polymer.
Massey Freddie Lee ; Tung Deborah Ann Snell ; Martin-Shultz Millicent Louise ; Duh Ben ; Kern ; Jr. Charles Louis, Process to prepare a polyester resin.
Hidekazu Nakamoto JP; Susumu Harada JP; Norifumi Maeda JP; Shuji Yamaguchi JP, Production process and production apparatus for polybutylene terephthalate.
Yount Thomas L. (3208 Nola La. Kingsport TN 37664) Adams J. Wesley (4000 Grey Fox Dr. Kingsport TN 37664) Windes Larry C. (1212 Jerry La. Kingsport TN 37664), Reactor trays for a vertical staged polycondensation reactor.
Broughton ; Jr. Roy M. (Auburn AL) Callander Douglas D. (Akron OH) Pengilly Brian W. (Akron OH) Schirmer Joseph P. (Akron OH) Winters Terence E. (Gates Mills OH), Reduction of glycol ethers in polyesters.
Yount Thomas L. (3208 Nola La. Kingsport TN 37664) Windes Larry C. (1212 Jerry La. Kingsport TN 37664) Adams J. Wesley (4000 Grey Fox Dr. Kingsport TN 37664), Split flow reactor trays for vertical staged polycondensation reactors.
Haseltine Douglas M. (Kingsport TN) Yount Thomas L. (Kingsport TN) Ryans Jimmy L. (Kingsport TN), Vaccum system for controlling pressure in a polyester process.
Yount, Thomas Lloyd; DeBruin, Bruce Roger; Windes, Larry Cates; Flores, Roy Douglas; White, Alan Wayne; Bellner, Steven Paul, Horizontal trayed reactor.
Yount, Thomas Lloyd; DeBruin, Bruce Roger; Ekart, Michael Paul; Windes, Larry Cates; Sliger, David Allen, Multi-level tubular reactor with dual headers.
DeBruin, Bruce Roger; Ekart, Michael Paul; Yount, Thomas Lloyd; Windes, Larry Cates; Sliger, David Allen, Multi-level tubular reactor with internal tray.
Yount, Thomas Lloyd; DeBruin, Bruce Roger; Ekart, Michael Paul; Windes, Larry Cates; Sliger, David Allen, Multi-level tubular reactor with oppositely extending segments.
Yount, Thomas Lloyd; DeBruin, Bruce Roger; Ekart, Michael Paul; Windes, Larry Cates; Sliger, David Allen, Multi-level tubular reactor with vertically spaced segments.
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