Temporary wet strength resins, more particularly, temporary wet strength resins comprising a polymer backbone, wherein the polymer backbone comprises a co-crosslinking monomeric unit, preferably a reversible co-crosslinking monomeric unit, especially in the presence of water, a homo-crosslinking mon
Temporary wet strength resins, more particularly, temporary wet strength resins comprising a polymer backbone, wherein the polymer backbone comprises a co-crosslinking monomeric unit, preferably a reversible co-crosslinking monomeric unit, especially in the presence of water, a homo-crosslinking monomeric units and a cationic monomeric unit, fibrous structures comprising such temporary wet strength resins, sanitary tissue products comprising such fibrous structures and processes for making such fibrous structures and/or such sanitary tissue product. Such fibrous structures and sanitary tissue products exhibit high initial wet tensile strength and improved flushability properties.
대표청구항▼
What is claimed is: 1. A temporary wet strength resin comprising a polymer backbone comprising a co-crosslinking monomeric unit comprising an electrophilic moiety, a homo-crosslinking monomeric unit comprising a hydroxyl moiety and lacking electrophilic moieties and nucleophilic moieties that form
What is claimed is: 1. A temporary wet strength resin comprising a polymer backbone comprising a co-crosslinking monomeric unit comprising an electrophilic moiety, a homo-crosslinking monomeric unit comprising a hydroxyl moiety and lacking electrophilic moieties and nucleophilic moieties that form stable, covalent bonds with electrophilic moieties, and a cationic monomeric unit wherein the temporary wet strength resin has the following formula: and X is--O--,--NH--, or--NCH3--, and R1 is a substituted or unsubstituted aliphatic group, R2 is an unsubstituted aliphatic group or a substituted aliphatic group lacking electrophilic moieties and nucleophilic moieties that form stable, covalent bonds with electrophilic moieties; Y1, Y2, and Y3 are independently--H,--CH3, or a halogen; W is a non-nucleophilic moiety, water-soluble nitrogen heterocyclic moiety or a tertiary amide, and Q is a cationic monomeric unit, wherein the mole percent of a is from about 1% to about 47%, the mole percent of b is from about 0% to about 70%, the mole percent of c is from about 10% to about 90%, and the mole percent of d is from about 1% to about 40%; and said temporary wet strength resin has a weight average molecular weight of at least about 20,000. 2. The temporary wet strength resin according to claim 1 wherein said weight average molecular weight of from about 20,000 to about 400,000. 3. The temporary wet strength resin according to claim 1 wherein a is from about 5% to about 30%, b is from 0% to about 60%, c is about 30% to about 80%, and d is about 2% to about 20%. 4. The temporary wet strength resin according to claim 1 wherein R1 comprises a C2-C7 aliphatic chain. 5. The temporary wet strength resin according to claim 1 wherein Z is and R2 is a C2-C4 aliphatic chain. 6. The temporary wet strength resin according to claim 1 wherein the monomeric unit comprising Z is selected from the group consisting of 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, 4-hydroxybutyl acrylate, 4-hydroxybutyl methacrylate, glyceryl mono-methacrylate, glyceryl mono-acrylate, 2-hydroxypropyl acrylate 2-hydroxypropyl methacrylate, 3-hydroxypropyl acrylate, 3-hydroxypropyl methacrylate, diethylene glycol mono-methacrylate, N-2-hydroxyethyl methacrylamide, N-(2-hydroxypropyl) methacrylamide, and acrylamidotrishydroxymethylmethane. 7. The temporary wet strength resin according to claim 1 wherein the monomeric unit comprising W is selected from the group consisting of vinyl pyrrolidones, vinyl oxazolidones, vinyl imidazoles, vinyl imidazolines, N,N-dialkyl acrylamides, alkyl acrylates, and alkyl methacrylates. 8. The temporary wet strength resin according to claim 1 wherein the monomeric unit comprising W is a vinyl pyrrolidinone, the monomeric unit comprising Z is 2-hydroxyethyl acrylate, and the monomeric unit comprising A is selected from N-(2,2-dimethoxyethyl)-N-methyl acrylamide, 3,3-dimethyoxypropyl acrylamide, 3,3diethoxypropyl acrylamide, 3,3-dimethoxypropyl methacrylamide, 2,2dimethoxy-1-methylethyl acrylate, 3,3-dimethoxypropyl methacrylate, 2-(acryloylamino)ethanal dimethylacetal, 2-(methacryloylamino)propanal dimethyl acetal, 5-(acryloylamino)pentanal dimethylacetal, 8-(acryloylamino)octanal dimethylacetal, and 3-(N-acryloyl-N-methylamino)propanal dimethyl acetal. 9. A fibrous structure comprising a temporary wet strength resin according to claim 1. 10. The fibrous structure according to claim 9 wherein the fibrous structure comprises from about 0.005% to about 5% by weight of the fibrous structure of the temporary wet strength resin. 11. A single-or multi-ply sanitary tissue product comprising a fibrous structure according to claim 9. 12. A surgical garment comprising a fibrous structure according to claim 9. 13. A process for making a fibrous structure comprising the steps of: a) providing a fiber furnish; b) depositing the fibrous furnish on a foraminous forming surface to form an embryonic fibrous web; c) drying the embryonic fibrous web such that the fibrous structure is formed; and d) applying a temporary wet strength resin according to claim 1. 14. A process for making a sanitary tissue product comprising the steps of: a) providing a fibrous structure in accordance with claim 9; and b) converting the fibrous structure into a sanitary tissue product. 15. A method for making a temporary wet strength resin comprising the steps of: a) providing a co-crosslinking monomeric unit comprising an electrophilic moiety, a homo-crosslinking monomeric unit comprising a hydroxyl moiety and lacking electrophilic moieties and nucleophilic moieties that form stable, covalent bonds with electrophilic moieties, and a cationic monomeric unit; and b) polymerizing the monomeric units from a) to form a temporary wet strength resin according to claim 1. 16. The fibrous structure according to claim 9 wherein the fibrous structure exhibits a % Total Wet Tensile Loss (Decay) after 5 minutes of soaking in neutral pH water of at least about 35% and/or a % Total Wet Tensile Loss (Decay) after 30 minutes of soaking in neutral pH water of at least about 65% and/or an initial wet tensile strength/dry tensile strength ratio (WTi/DT) of at least about 7.
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이 특허에 인용된 특허 (16)
Deets Gary L. (St. Peters MO) Tamalis William G. (Maryland Heights MO), Cationic grafted starch copolymers.
Crisp Mark T.,NLX ; Riehle Richard J., Resins of amphoteric aldehyde polymers and use of said resins as temporary wet-strength or dry-strength resins for paper.
Bjorkquist David W. (Wyoming OH), Temporary wet strength resins with nitrogen heterocyclic nonnucleophilic functionalities and paper products containing s.
Bjorkquist David W. (Wyoming OH), Temporary wet strength resins with nitrogen heterocyclic nonnucleophilic functionalities and paper products containing s.
Castro, David J.; Lowe, Robert M.; Liu, Mei, Method of increasing paper bulk strength by using a diallylamine acrylamide copolymer in a size press formulation containing starch.
Castro, David A.; Karnati, Rangarani; Wilson, Shawnee M.; Cheng, Weiguo; Liu, Mei; Zhang, Zhiyi, Use of nanocrystaline cellulose and polymer grafted nanocrystaline cellulose for increasing retention in papermaking process.
Castro, David A.; Karnati, Rangarani; Wilson, Shawnee M.; Cheng, Weiguo; Liu, Mei; Zhang, Zhiyi, Use of nanocrystaline cellulose and polymer grafted nanocrystaline cellulose for increasing retention in papermaking process.
Castro, David J.; Karnati, Rangarani; Wilson, Shawnee M.; Cheng, Weiguo; Liu, Mei; Zhang, Zhiyi, Use of nanocrystaline cellulose and polymer grafted nanocrystaline cellulose for increasing retention in papermaking process.
Castro, David J.; Karnati, Rangarani; Wilson, Shawnee M.; Cheng, Weiguo; Liu, Mei; Zhang, Zhiyi, Use of nanocrystaline cellulose and polymer grafted nanocrystaline cellulose for increasing retention, wet strength, and dry strength in papermaking process.
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