Multilayered articles having biocompatibility and biostability characteristics
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B32B-001/08
B32B-001/00
B32B-027/40
출원번호
US-0694681
(2003-10-28)
등록번호
US-7264858
(2007-09-04)
발명자
/ 주소
Belliveau,Brian Peter
Downie,Robert Bruce
출원인 / 주소
Lubrizol Advanced Materials, Inc.
인용정보
피인용 횟수 :
8인용 특허 :
18
초록▼
Multilayer articles, such as tubing and films, are disclosed which have a soft layer of aliphatic polyurethane and at least one layer of hard aliphatic polyurethane. The articles formed avoid the problem of tackiness when using only a soft aliphatic polyurethane, while maintaining flexibility. The
Multilayer articles, such as tubing and films, are disclosed which have a soft layer of aliphatic polyurethane and at least one layer of hard aliphatic polyurethane. The articles formed avoid the problem of tackiness when using only a soft aliphatic polyurethane, while maintaining flexibility. The articles are also biocompatible and biostable and are suitable for use in medical applications.
대표청구항▼
What we claim is: 1. A multilayered tube consisting essentially of: a first layer of soft aliphatic polyether polyurethane having an inner and outer surface, wherein said soft aliphatic polyether polyurethane has a Shore hardness from about 40 A to about 95 A as measured according to ASTM D2240; an
What we claim is: 1. A multilayered tube consisting essentially of: a first layer of soft aliphatic polyether polyurethane having an inner and outer surface, wherein said soft aliphatic polyether polyurethane has a Shore hardness from about 40 A to about 95 A as measured according to ASTM D2240; and at least one second layer of hard aliphatic polyurethane selected from the group consisting of polyether polyurethane and polycarbonate polyurethane on at least one of said inner and outer surface of said first layer, wherein said hard aliphatic polyurethane has a Shore hardness from about 95 A to about 85 D as measured according to ASTM D2240, with the proviso that if said hard aliphatic polyurethane is a polycarbonate polyurethane, said Shore hardness of said hard aliphatic polyurethane is from about 70 A to about 80 D; and wherein both of said soft aliphatic polyurethane and said hard aliphatic polyurethane are biocompatible and biostable. 2. The multilayered tube of claim 1, wherein said soft aliphade polyurethane has a Shore hardness of from about 65 A to about 85 A. 3. The multilayered tube of claim 1, wherein said hard aliphatic polyurethane has a Shore hardness of from about 40 D to about 75 D). 4. The multilayered tube of claim 1, wherein said tube has said second layer of hard aliphatic polyurethane on said outer surface of said first layer of soft aliphatic polyurethane. 5. The multilayer tube of claim 4, wherein said rube is a profile tube. 6. The multilayer tube of claim 1, wherein said tube has said second layer of hard aliphatic polyurethane on said inner surface of said first layer of soft aliphatic polyurethane. 7. The niultilayer tube of claim 1, wherein said tube has said second layer of hard aliphatic polyurethane on both said inner and outer surface of said first layer of soft aliphatic polyurethane. 8. The muhilayer tube of claim 1, wherein bath of said soft and said hard aliphatic polyurethane is a polyether polyurethane. 9. The niultilayer tube of claim 1, wherein said polyether polyurethane is the reaction product of at least one polyether polyol with at least one alipharic diisocyanate and at least one glycol chain extender. 10. The multilayer tube of claim 9, wherein said aliphatic diisocyanate is selected from the group consisting of hexamethylene diisocyanate, isophorone diisocyanate, trimethyl hexamethylene diisocyanate, dicyclohexyl methane diisocyanate, and dimer acid diisocyanate. 11. The multilayer tube of claim 10, wherein said aliphatic diisocyanate is dicyclohexyl methane diisocyanate. 12. The multilayer tube of claim 9, wherein said glycol chain extender has from about 2 to about 10 carbon atoms. 13. The multilayer tube of claim 12, wherein said glycol chain extender is 1,4-butanediol. 14. The multilayer tube of claim 9, wherein said polyciher polyol is polytetramethylene ether glycol. 15. The niultilayer tube of claim 14, wherein said polytetrarnethylene ether glycol has a number avenge molecular weight of from about 500 to about 10,000. 16. The inultilayer tube of claim 15, wherein said potytetramethylene ether glycol has a number average molecular weight of from about 700 to about 3,000. 17. The multilayer tube of claim 1, wherein said bard aliphatie polyurethane is a polycarbonate polyurethane. 18. The multilayer tube of claim 17, wherein said polycarbonate polyurethane is the reaction product of at least one polycarbonate polyol with at least one aliphaxic diisocyanate and at least one glycol chain extender. 19. The multilayer tube of claim 18, wherein said polycarbonate polyol has a number average molecular weight of from about 500 to about 10,000. 20. The inultilayer tube of claim 19, wherein said polycarbonate polyol has a number average molecular weight of from about 500 to about 2,500. 21. The multilayer tube of claim 1, wherein the thickness of said at least one second layer of hard aliphatic polyurethane is from about 0.0001 to about 0.010 inch. 22. The multilayer tube of claim 21, wherein the thickness of said at least one second layer of hard aliphatic poiyurethane is from about 0.0005 to about 0.001 inch.
Szycher Michael (Lynnfield MA), Extrudable polyurethane for prosthetic devices prepared from a diisocyanate, a polytetramethylene ether polyol and 1,4 b.
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