Electron transport agents for organic electronic devices
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
H01L-051/54
H01L-051/50
C07D-249/08
C07D-249/00
C07D-271/10
C07D-271/00
C07D-285/12
C07D-285/00
출원번호
US-0413653
(2003-04-15)
등록번호
US-7271406
(2007-09-18)
발명자
/ 주소
Bentsen,James G.
Goplen,Nicholas P.
Li,Yingbo
Roberts,Ralph R.
출원인 / 주소
3M Innovative Properties Company
인용정보
피인용 횟수 :
3인용 특허 :
49
초록▼
Compounds and compositions are provided that can be used as electron transport agents in organic electronic devices such as organic electroluminescent devices. The compounds are non-polymeric and have an aromatic core conjugated to end capping groups. The aromatic core contains a phenylene group ary
Compounds and compositions are provided that can be used as electron transport agents in organic electronic devices such as organic electroluminescent devices. The compounds are non-polymeric and have an aromatic core conjugated to end capping groups. The aromatic core contains a phenylene group arylene or naphthalene group arylene having a pendant heteroaryl group that includes a--C═N--unit.
대표청구항▼
What is claimed is: 1. A compound comprising an aromatic core and two end capping groups conjugated to the aromatic core, said compound having Formula IV: wherein each Ar1 is independently a radical of benzene, naphthalene, anthracene, phenanthrene, 9,10-dihydrophenanthrene, 4,5,9,10-tetrahydrop
What is claimed is: 1. A compound comprising an aromatic core and two end capping groups conjugated to the aromatic core, said compound having Formula IV: wherein each Ar1 is independently a radical of benzene, naphthalene, anthracene, phenanthrene, 9,10-dihydrophenanthrene, 4,5,9,10-tetrahydropyrene, fluorene, 9-silafluorene, 6,12-dihydroindeno[1,2-b]fluorene, 5,12-dihydro-6H-indeno[1,2-b]phenanthrene, 5,6,12,13-tetrahydrodibenzo[a,h]anthracene, 2-phenyl-9H-fluorene, or acenaphthene that is unsubstituted or substituted with one or more groups selected from alkyl, alkenyl, alkoxy, fluoro, fluoroalkyl, perfluoroalkyl, heteroalkyl, and combinations thereof, wherein when Ar1 is a radical of benzene, the group is selected from each a is independently 1 or 2; each Ey is independently a structure of Formula II or Formula III: each X is independently O, S, or NR1, where R1 is alkyl, aryl, heteroaryl, heteroalkyl, or combinations thereof; each Ar2 is independently an aryl group that is unsubstituted or substituted with one or more groups selected from alkyl, alkenyl, alkoxy, aryl, aryloxy, fluoro, fluoroalkyl, perfluoroalkyl, heteroalkyl, alkyl oxadiazolyl, aryl oxadiazolyl, alkyl triazolyl, aryl triazolyl, diarylamino, aryldiarylamino, and combinations thereof; each asterisk (-*) indicates the location of a bond to another group in the compound; and each end capping group (EC) is independently an aryl, heteroaryl without a--C═N--unit, or tertiary amino aryl group that is unsubstituted or substituted with one or more groups selected from alkyl, alkenyl, alkoxy, aryl, aryloxy, fluoro, fluoroalkyl, perfluoroalkyl, heteroalkyl, heteroaryl without a--C═N--unit, and combinations thereof, wherein said end capping groups are conjugated to the aromatic core. 2. The compound of claim 1 wherein the moiety in Formula IV is a divalent radical of that is unsubstituted or substituted with one or more groups selected from a C1-20 alkyl, C2-20 alkenyl, C1-20 alkoxy, fluoro, C1-20 fluoroalkyl, C1-20 perfluoroalkyl, C1-20 heteroalkyl, and combinations thereof, wherein each R is independently a C1-30 alkyl, C2-30 alkenyl, C1-30 alkoxy, C1-30 heteroalkyl, or combinations thereof; and each R3 is independently selected from hydrogen, C1-30 alkyl, C2-30 alkenyl, C1-30 alkoxy, C1-30 heteroalkyl, and combinations thereof. 3. The compound of claim 2, wherein at least one R or R3 comprises a heteroalkyl having up to 30 carbon atoms, wherein the heteroalkyl comprises a soft segment comprising a divalent poly(oxyalkylene) segment of Formula VI description="In-line Formulae" end="lead"*--O(CmH2mO)y --*description="In-line Formulae" end="tail" or a divalent poly(dialkylsiloxane) segment of Formula VII description="In-line Formulae" end="lead"* Si(CwH2w+1)2Oy *,description="In-line Formulae" end="tail" where in is an integer of 1 to 6, y is an integer of 2 to 20, and xv is an integer of 1 to 10 with the proviso that m, y, and w are selected so as to provide up to 30 carbon atoms. 4. The compound of claim 2, wherein the compound is substituted with a fluoro, fluoroalkyl, or perfluoroalkyl group. 5. The compound of claim 1, wherein Ar2 is an aryl group selected from phenyl, biphenyl, terphenyl, anthryl, naphthyl, acenaphthyl, phenanthryl, dihydrophenanthrenyl, anthracenyl, fluorenyl, 9-silafluorenyl, tetrahydropyrenyl, perylenyl, spirobisfluorenyl, fluoranthenyl, pyrenyl, dihydropyrenyl, tetrahydropyrenyl, rubrenyl, chrysenyl, 5,6,12,13-tetrahydrodibenzo[a,h]anthracenyl, 6,12-dihydroindeno[1,2-b]fluorenyl, 5,12-dihydro-6H-indeno[1,2-b]phenanthrenyl, and benzo[g,h,l]perylenyl that is unsubstituted or substituted with one or more C1-20 alkyl, C1-20 alkenyl, C1-20 alkoxy, C6-20 aryl, C6-20 aryloxy, fluoro, C1-20 fluoroalkyl, C1-20 perfluoroalkyl, C1-20 heteroalkyl, C3-30 alkyl oxadiazolyl, C3-30 aryl oxadiazolyl, C3-20 alkyl triazolyl, C3-30 aryl triazolyl, C3-30 diarylamino, C3-30 diarylaminoaryl, or combinations thereof. 6. The compounds of claim 1, wherein the radical in Formula IV is selected from 7. The compound of claim 1, wherein at least one of the end capping groups comprises a C6-40 aryl comprising phenyl, biphenyl, terphenyl, anthryl, naphthyl,acenaphthyl, phenanthryl, dihydrophenanthrenyl, anthracenyl, fluorenyl, 9-silafluorenyl, tetrahydropyrenyl, perylenyl, spirobistfluorenyl, fluoranthenyl, pyrenyl, dihydropyrenyl, tetrahydropyrenyl, rubrenyl, chrysenyl, benzo[g,h,i]perylenyl, or a radical thereof, wherein the end capping group is unsubstituted or substituted with one or more groups selected from C1-20 alkyl, C2-20 alkenyl, C1-20 alkoxy, C6-20 aryl, C6-20 aryloxy, fluoro, C1-20 fluoroalkyl, C1-20 perfluoroalkyl, C1-20 heteroalkyl, C3-20 heteroaryl without a--C═N--unit, and combinations thereof. 8. The compound of claim 1, wherein at least one of the end capping groups comprises a C3-40 heteroaryl or heteroarylene comprising a radical of furanyl, thiophenyl, bithiophenyl, N-aryl pyrrolyl, N-alkyl pyrrolyl, benzofuranyl, benzothiophenyl, indolyl, N-alkyl carbazolyl, N-aryl carbazolyl, diaryl silanolyl, or a radical thereof, wherein the end capping group is unsubstituted or substituted with one or more groups selected from C1-20 alkyl, C2-20 alkenyl, C1-20 alkoxy, C6-20 aryl, C6-20 aryloxy, fluoro, C1-20 fluoroalkyl, C1-20 perfluoroalkyl, C1-20 heteroalkyl, C3-20 heteroaryl without a--C═N--unit, and combinations thereof. 9. The compound of claim 1, wherein at least one of the end capping groups comprises a C12-60 tertiary amino aromatic aryl comprising a radical of diarylaniline, alkylcarbazole, arylcarbazole tetraaryldiamine, starburst amine, peraryltriamine, dendritic amine, or spiroamine, wherein the end capping group is unsubstituted or substituted with one or more aroups selected from C1-20 alkyl, C2-20 alkenyl, C1-20 alkoxy, C6-20 aryl, C6-20 aryloxy, fluoro, C1-20 fluoroalkyl, C1-20 perfluoroalkyl, C1-20 heteroalkyl, C3-20 heteroaryl without a--C═N--unit, and combinations thereof. 10. The compound of claim 1, wherein a.t least one of the end capping groups comprises a C12-60 tertiary amino aromatic aryl comprising a radical of N,N,N'N'-tetraarylbenzidine, N,N,N',N'-tetraaryl-1,4-phenylenediamine, N,N,N'N'-tetraaryl-2,7-diaminofluorene, N,N'-bis(3-methylphenyl)-N,N'-bis(phenyl)benzidine, N,N'-bis(1-naphthyl)-N,N'-bis(phenyl)benzidine, 1,4-bis(carbazolyl)biphenyl, 4,4',4"-tris(N,N-diarylamino)triphenylamine, 1,3,5-tris(4-diarylaminophenyl)benzene, 4,4',4"-tris(N,N-diphenylamino)triphenylamine, 4,4',4"-tris(N-3-methylphenyl-N-phenylamino)triphenylamine, or 1,3,5-tris(4-diphenylaminophenyl)benzene, wherein the end capping group is unsubstituted or substituted with one or more groups selected from C1-20 alkyl, C2-20 alkenyl, C1-20 alkoxy, C6-20 aryl, C6-20 aryloxy, fluoro, C1-20 fluoroalkyl, C1-20 perfluoroalkyl, C1-20 heteroalkyl, C3-20 heteroaryl without a--C═N--unit, and combinations thereof. 11. The compound of claim 1, wherein at least one end capping group comprises a monovalent radical of that is unsubstituted or substituted with one or more groups selected from C1-20 alkyl, C2-20 alkenyl, C1-20 alkoxy, C6-20 aryl, C6-20 aryloxy, fluoro, C1-20 fluoroalkyl, C1-20 perfluoroalkyl, C1-20 heteroalkyl, C3-20 heteroaryl without a--C═N--unit, and combinations thereof, wherein each R is independently selected from C1-30 alkyl, C2-30 alkenyl, C1-30 alkoxy, C6-20 aryl, C6-20 aryloxy, C3-20 heteroaryl without a--C═N--unit, C1-30 heteroalkyl, and combinations thereof; and each X is independently O, S, or NR1, where R1 is a C1-30 alkyl, C6-20 aryl, C3-30 heteroaryl without a--C═N--unit, C1-30 heteroalkyl, or combinations thereof. 12. The compound of claim 11, wherein the end capping group further comprises a moiety conjugated to a group of Formula CVI to CXXVII, said moiety selected from a divalent radical of that is unsubstituted or substituted with one or more groups selectcd horn C1-20 alkyl, C2-20 alkenyl, C1-20 alkoxy, C6-20 aryl, C6-20 aryloxy, fluoro, C1-20 fluoroalkyl, C1-20 perfluoroalkyl, C1-20 heteroalkyl, C3-20 heteroaryl without a--C═N--unit, and combinations thereof, wherein each R is independently selected from C1-30 alkyl, C2-30 alkenyl, C1-30 alkoxy, C6-30 aryl, C6-30 aryloxy, C3-30 heteroaryl without a--C═N--unit, C1-30 heteroalkyl, and combinations thereof; and each R3 is independently selected from hydrogen, C1-30 alkyl, C2-30 alkenyl, C1-30 alkoxy, C6-30 aryl, C6-30 aryloxy, C3-30 heteroaryl without a--C═N--unit, C1-30 heteroalkyl, and combinations thereof. 13. The compound of claim 11, wherein the end capping group further comprises a moiety conjugated to a group of Formula CVI to CXXVII, said moiety selected from a divalent radical of that is unsubstituted or substituted with one or more groups selected from C1-20 alkyl, C2-20 alkenyl, C1-20 alkoxy, C6-20 aryl, C6-20 aryloxy, fluoro, C1-20 fluoroalkyl, C1-20 perfluoroalkyl, C1-20 heteroalkyl, C3-20 heteroaryl without a--C═N--unit, and combinations thereof, wherein each R is independently selected from C1-30 alkyl, C2-30 alkenyl, C1-30 alkoxy, C6-30 aryl, C6-30 aryloxy, C3-30 heteroaryl without a--C═N--unit, C1-30 heteroalkyl, and combinations thereof; each X is independently O, S, or NR1, where R1 is a C1-30 alkyl, C6-20 aryl, C3-30 heteroaryl without a--C═N--unit, C1-30 heteroalkyl, or combinations thereof; and each t is an integer equal to 0 to 4. 14. The compound of claim 1, wherein the compound is substituted with at least one soft segment comprising a divalent poly(oxyalkylene) segment of formula description="In-line Formulae" end="lead"*--O(CmH2mO)y --*description="In-line Formulae" end="tail" or a divalent poly(dialkylsiloxane) segment of formula description="In-line Formulae" end="lead"Si(CwH2w+1)2Oy*,description="In-line Formulae" end="tail" where m is an integer of 1 to 6, y is an integer of 2 to 20, and w is an integer of 1 to 10. 15. The compound of claim 1, wherein the compound is substituted with at least one fluoro, fluoroalkyl, or perfluoroalkyl group. 16. The compound of claim 1, wherein the compound is 17. The compound or claim 1, wherein the compound is amorphous. 18. The compound of claim 1, wherein the compound is an electron transporting material. 19. The compound of claim 1, wherein the compound is both an electron and hole transporting material. 20. The compound of claim 1, wherein the compound is a light emitting material and an electron transporting material. 21. A composition comprising: (a) a first compound comprising a first aromatic core and two first end capping groups conjugated to the first aromatic core, said compound having Formula IV: wherein each Ar1 is independently a radical of benzene, naphthalene, anthracene, phenanthrene, 9,10-dihydrophenanthrene, 4,5,9,10-tetrahydropyrene, fluorene, 9-silafluorene, 6,12-dihydroindeno[1,2-b]fluorene, 5,12-dihydro-6H-indeno[1,2-b]phenanthrene, 5,6,12,13-tetrahydrodibenzo[a,h]anthracene, 2-phenyl-9H-fluorene, or acenaphthene that is unsubstituted or substituted with one or more groups selected from alkyl, alkenyl, alkoxy, fluoro, fluoroalkyl, perfluoroalkyl, heteroalkyl, and combinations thereof, wherein when Ar1 is a radical of benzene, the group is selected from each a is independently 1 or 2; each Ey is independently a structure of Formula II or Formula III: each X is independently O, S, or NR1, where R1 is alkyl, aryl, heteroaryl, heteroalkyl, or combinations thereof each Ar2 is independently an aryl group that is unsubstituted or substituted with one or more groups selected from alkyl, alkenyl, alkoxy, aryl, aryloxy, fluoro, fluoroalkyl, perfluoroalkyl, heteroalkyl, alkyl oxadiazolyl, aryl oxadiazolyl, alkyl triazolyl, aryl triazolyl, diarylamino, aryldiarylamino, and combinations thereof; each asterisk (-*) indicates the location of a bond to another group in the compound; and each end capping group (EC) is independently a carbocyclic aryl, heteroaryl without a--C═N--unit, or tertiary amino aryl group that is unsubstituted or substituted with one or more groups selected from alkyl, alkenyl, alkoxy, aryl, aryloxy, fluoro, fluoroalkyl, perfluoroalkyl, heteroalkyl, heteroaryl without a--C═N--unit, and combinations thereof, wherein said end capping groups are conjugated to the aromatic core; and (b) a second compound selected from a charge transporting material, a charge blocking material, a light emitting material, a color conversion material, a polymeric binder, or a combination thereof. 22. The composition of claim 21, wherein the composition comprises a hole transporting material and an electron transporting material. 23. The composition of claim 21, wherein the composition comprises a hole transporting material, an electron transporting material, and a light emitting material. 24. The composition of claim 21, wherein the second compound is selected from a charge transporting material, a charge blocking material, a light emitting material, a color conversion material, or a combination thereof, said second compound having an aromatic radical that comprises the first aromatic core of the first compound, wherein the aromatic radical of the second compound can be unsubstituted, substituted with a substituent of a same type that is present on the first aromatic core of the first compound, or substituted with a substituent that is absent on the first aromatic core of the first compound; or a second end capping group that comprises the first end capping group of the first compound, wherein the second end capping group can be unsubstituted, substituted with a substituent of a same type that is present on the first end capping group, or substituted with a substituent that is absent on the first end capping group; or a divalent radical that comprises a divalent radical of the first end capping group of the first compound, wherein the divalent radical in the second compound can be unsubstituted, substituted with a substituent of a same type that is present on the first end capping group, or substituted with a substituent that is absent on the first end capping group; or a combination thereof. 25. The composition of claim 24, wherein the second compound is non-polymeric, said second compound comprising a second aromatic core and at least one second end capping group. 26. The composition of claim 25, wherein the second end capping group of the second compound comprises the first end capping group of the first compound. 27. The composition of claim 26, wherein the second aromatic core of the second compound is different than the first aromatic core of the first compound and the composition further comprises a monomer mixture comprising a first monomer comprising the first aromatic core and a second monomer comprising the second aromatic core. 28. The composition of claim 26, wherein the second aromatic core of the second compound is different than the first aromatic core of the first compound and the composition further comprises a polymer that is the reaction product of a monomer mixture comprising a first monomer comprising the first aromatic core and a second monomer comprising the second aromatic core. 29. The composition of claim 25, further comprising a light emitting polymer. 30. The composition of claim 25, further comprising an electroactive polymer. 31. The composition of claim 25, further comprising an inactive polymer. 32. The composition of claim 25, wherein the second aromatic core of the second compound comprises the first aromatic core of the first compound. 33. The composition of claim 32, further comprising a light emitting polymer. 34. The composition of claim 32, further comprising an electroactive polymer. 35. The composition of claim 32, further comprising an inactive polymer. 36. The composition of claim 32, wherein the second end capping group of the second compound is different than the first end capping group of the first compound and the composition further comprises a monomer mixture comprising a first monomer comprising the first end capping group or a divalent radical of the first end capping group and a second monomer comprising the second end capping group or a divalent radical of the second end capping group. 37. The composition of claim 32, wherein the second compound has a second end capping group that is different than the first end capping group of the first compound and the composition further comprises a polymer that is the reaction product of a monomer mixture comprising a first monomer comprising the first end capping group or a divalent radical of the first end capping group and a second monomer comprising the second end capping group or a divalent radical of the second end capping group. 38. The composition of claim 21, wherein the second compound is a polymer comprising the reaction product of a monomer mixture comprising a first monomer comprising the first aromatic core of the first compound. 39. The composition of claim 21, wherein the second compound is a polymer that is the reaction product of a monomer mixture comprising a first monomer comprising the first end capping group or a radical of the first end capping group. 40. The composition of claim 21, wherein composition is amorphous. 41. The composition of claim 21, wherein the composition is solution processible. 42. An organic electronic device comprising a compound having an aromatic core and two end capping groups conjugated to the aromatic core, said compound having Formula IV: wherein each Ar1 is independently a radical of benzene, naphthalene, anthracene, phenanthrene, 9,10-dihydrophenanthrene, 4,5,9,10-tetrahydropyrene, fluorene, 9-silafluorene, 6,12-dihydroindeno[1,2-b]fluorene, 5,12-dihydro-6H-indeno[1,2-b]phenanthrene, 5,6,12,13-tetrahydrodibenzo[a,h]anthracene, 2-phenyl-9H-fluorene, or acenaphthene that is unsubstituted or substituted with one or more groups selected from alkyl, alkenyl, alkoxy, fluoro, fluoroalkyl, perfluoroalkyl, heteroalkyl, and combinations thereof, wherein when Ar1 is a radical of benzene, the group is selected from each a is independently 1 or 2; each Ey is independently a structure of Formula II or Formula III: each X is independently O, S, or NR1, where R1 is alkyl, aryl, heteroaryl, heteroalkyl, or combinations thereof; each Ar2 is independently an aryl group that is unsubstituted or substituted with one or more groups selected from alkyl, alkenyl, alkoxy, aryl, aryloxy, fluoro, fluoroalkyl, perfluoroalkyl, heteroalkyl, alkyl oxadiazolyl, aryl oxadiazolyl, alkyl triazolyl, aryl triazolyl, diarylamino, aryldiarylamino, and combinations thereof; each asterisk (-*) indicates the location of a bond to another group in the compound; and each end capping group (EC) is independently a carbocyclic aryl, heteroaryl without a--C═N--unit, or tertiary amino aryl group that is unsubstituted or substituted with one or more groups selected from alkyl, alkenyl, alkoxy, aryl, aryloxy, fluoro, fluoroalkyl, perfluoroalkyl, heteroalkyl, heteroaryl without a--C═N--unit, and combinations thereof, wherein said end capping groups are conjugated to the aromatic core. 43. The organic electronic device of claim 42, wherein the device is an organic electroluminescent device. 44. The organic electronic device of claim 43, wherein the organic electroluminescent device comprises an organic emissive element comprising the compound of Formula IV. 45. The organic electronic device of claim 44, wherein the organic emissive element further comprises a charge transporting material, a charge blocking material, a polymeric material, a light emitting material, a color conversion layer, or a combination thereof. 46. The organic electronic device of claim 44, wherein the organic emissive element has multiple layers and the compound of Formula IV is in a light emitting layer. 47. The organic electronic device of claim 44, wherein the organic emissive element has multiple layers and the compound of Formula IV is in a charge transporting layer.
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