초록 ▼

An electronic device composed of a semiconductor layer in contact with a number of electrodes, wherein the semiconductor layer includes a small molecular thiophene compound consisting of: at least one divalent linkage; and a plurality of thiophene units, each thiophene unit being represented by stru

An electronic device composed of a semiconductor layer in contact with a number of electrodes, wherein the semiconductor layer includes a small molecular thiophene compound consisting of: at least one divalent linkage; and a plurality of thiophene units, each thiophene unit being represented by structure (A) wherein each thiophene unit is bonded at either or both of the second ring position and the fifth ring position, wherein there is at least one thiophene unit where R1 is present at the third ring position or the fourth ring position, or at both the third ring position and the fourth ring position, wherein for any two adjacent thiophene units there is excluded the simultaneous presence of the same or different R1 at the 3-position of one thiophene unit and at the 3'-position of the other thiophene unit, and wherein the number of the thiophene units is at least 6.

대표청구항 ▼

The invention claimed is: 1. An electronic device comprising a semiconductor layer in contact with a number of electrodes, wherein the semiconductor layer includes a small molecular thiophene compound consisting of: at least one divalent linkage; and a plurality of thiophene units, each thiophene u

The invention claimed is: 1. An electronic device comprising a semiconductor layer in contact with a number of electrodes, wherein the semiconductor layer includes a small molecular thiophene compound consisting of: at least one divalent linkage; and a plurality of thiophene units, each thiophene unit being represented by structure (A) wherein each thiophene unit is bonded at either or both of the second ring position and the fifth ring position, wherein m is 0, 1, or 2, wherein each thiophene unit is the same or different from each other in terms of substituent number, substituent identity, and substituent position, wherein each R1 is independently selected from the group consisting of: (a) a hydrocarbon group, (b) a heteroatom containing group, and (c) a halogen, wherein there is at least one thiophene unit where R1 is present at the third ring position or the fourth ring position, or at both the third ring position and the fourth ring position, wherein for any two adjacent thiophene units as represented by structure (A1): there is excluded the simultaneous presence of the same or different R1 at the 3-position of one thiophene unit and at the 3'-position of the other thiophene unit, and wherein the number of the thiophene units is at least 6 wherein the semiconductor layer is substantially free of a thiophene compound having an average number of thiophene units. 2. The device of claim 1, wherein the semiconductor layer further includes a different small molecular thiophene compound consisting of a plurality of thiophene units and an optional divalent linkage, with each thiophene unit of the different small molecular thiophene compound represented by the structure (A). 3. The device of claim 1, wherein the plurality of thiophene units consists of a first set of thiophenes and a second set of thiophenes that are equal in number, wherein the divalent linkage is positioned between the first set and the second set. 4. The device of claim 1, wherein the divalent linkage is selected from the group consisting of: wherein n is 0, 1, 2, 3, or 4, and when n is at least 2, the substituents of R4 are the same or different from each other wherein R4 is selected from the group consisting of a hydrocarbon group, a heteroatom containing group, and a halogen. 5. The device of claim 1, wherein the hydrocarbon group is substituted. 6. The device of claim 1, wherein the hydrocarbon group forms part of a ring structure attached to the carbon atoms at the third ring position and the fourth ring position of the thiophene unit. 7. The device of claim 1, wherein the heteroatom containing group forms part of a ring structure attached to the carbon atoms at the third ring position and the fourth ring position of the thiophene unit. 8. The device of claim 1, wherein the number of thiophene units ranges from 6 to about 32. 9. The device of claim 1, wherein the compound is symmetrical. 10. The device of claim 1, wherein the compound is selected from the group consisting of: where y is the number of units, wherein R and R' are the same or different from each other, R is selected from the group consisting of: (a) the hydrocarbon group, (b) the heteroatom containing group, and (c) the halogen, R' is selected from the group consisting of: (a) the hydrocarbon group, (b) the heteroatom containing group, (c) the halogen, and (d) a hydrogen. 11. The device of claim 1, wherein the thiophene units are selected from the group consisting of: wherein R2 and R3 are the same or different from each other, and are selected from the group consisting of: (a) the hydrocarbon group, (b) the heteroatom containing group, (c) the halogen, and (d) a hydrogen. 12. The device of claim 1, wherein the device is an organic thin film transistor. 13. The device of claim 1, wherein the compound is selected from the group consisting of: or a mixture thereof.