Method for producing acrolein and/or acrylic acid
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C07C-051/16
C07C-051/42
출원번호
US-0297579
(2001-06-13)
등록번호
US-7321058
(2008-01-22)
우선권정보
DE-10028582(2000-06-14)
국제출원번호
PCT/EP01/006708
(2001-06-13)
§371/§102 date
20021212
(20021212)
국제공개번호
WO01/096271
(2001-12-20)
발명자
/ 주소
Machhammer,Otto
Adami,Christoph
Hechler,Claus
Zehner,Peter
출원인 / 주소
BASF Aktiengesellschaft
대리인 / 주소
Oblon, Spivak, McClelland, Maier & Neustadt, P.C.
인용정보
피인용 횟수 :
9인용 특허 :
22
초록▼
Acrolein and/or acrylic acid are prepared from propane and/or propene by a process comprising the following steps: (a) separation of propane and/or propene from a propane-and/or propene-containing gas mixture by absorption in an absorbent, (b) separation of the propane and/or propene from the absorb
Acrolein and/or acrylic acid are prepared from propane and/or propene by a process comprising the following steps: (a) separation of propane and/or propene from a propane-and/or propene-containing gas mixture by absorption in an absorbent, (b) separation of the propane and/or propene from the absorbent to give a gas B and (c) use of the gas B obtained in stage (b) for an oxidation of propane and/or propene to acrolein and/or acrylic acid, no heterogeneously catalyzed dehydrogenation of propane without supply of oxygen being carried out between steps (b) and (c).
대표청구항▼
We claim: 1. A process for the preparation of at least one of acrolein and acrylic acid from at least one of propane and propene, the process comprising the following steps: (a) separating at least one of propane and propene from a gas mixture A containing at least one of propane and propene by abs
We claim: 1. A process for the preparation of at least one of acrolein and acrylic acid from at least one of propane and propene, the process comprising the following steps: (a) separating at least one of propane and propene from a gas mixture A containing at least one of propane and propene by absorption in an absorbent, (b) separating at least one of propane and propene from the absorbent to give a gas B containing at least one of propane and propene and (c) oxidizing the gas B obtained in stage (b) to form at least one of acrolein and acrylic acid, wherein no heterogeneously catalyzed dehydrogenation of propane without a supply of oxygen is carried out between steps (b) and (c), and wherein the separating in step (b) is carried out by stripping with at least one of a pressure change and a temperature change, using at least one of steam, air and an oxygen/nitrogen mixture, and wherein during the separating (a) the gas mixture A is brought into contact with the absorbent at a pressure of from 1 to 50 bar, and wherein the stripping (b) is carried out at a pressure of from 0.1 to 10 bar. 2. The process as claimed in claim 1, wherein the gas mixture A further comprises at least one component selected from the group consisting of hydrogen, nitrogen and oxides of carbon. 3. The process as claimed in claim 1, wherein at least one C8-C20-alkane or C8-C20-alkene is used as the absorbent in step (a). 4. The process as claimed in claim 1, wherein, in step (c), propene is oxidized to at least one of acrolein and acrylic acid. 5. The process as claimed in claim 1, wherein, in step (c), propane is oxidized to at least one of acrolein and acrylic acid. 6. The process as claimed in claim 5, wherein a multimetal oxide material of the formula (I) description="In-line Formulae" end="lead"MoVbM1cM2dOn (I)description="In-line Formulae" end="tail" where M1 is at least one of Te or Sb, M2 is at least one element selected from the group consisting of Nb, Ta, W, Ti, Al, Zr, Cr, Mn, Ga, Fe, Ru, Co, Rh, Ni, Pd, Pt, La, Bi, B, Ce, Sn, Zn, Si and In, b is from .0.01 to 1, c is from >0 to 1, d is from >0 to 1, and n is a number which is determined by the valency and frequency of the elements other than oxygen in (I), is used as the catalyst for oxidizing propane in step (c). 7. The process as claimed in claim 1, wherein the gas mixture A used in step (a) has the composition of a gas mixture which is obtained by at least one of homogeneous or heterogeneously catalyzed dehydrogenation of propane to propane. 8. The process as claimed in claim 7, wherein the propane dehydrogenation is carried out with a supply of oxygen. 9. The process as claimed in claim 1, wherein, after step (c) has been carried out, unconverted propane and optionally propene is subjected to a propane dehydrogenation and the product mixture obtained is subjected to step (a) again. 10. The process as claimed in claim 1, wherein step (c) is carried out directly after step (b). 11. The process as claimed in claim 1, wherein after step (b) and before step (c) a water quench is carried out for separating absorbent. 12. A process for the preparation of at least one of acrolein and acrylic acid from at least one of propane and propene, the process comprising the following steps: (a) separating at least one of propane and propene from a gas mixture A containing at least one of propane and propene by absorption in an absorbent, (b) separating at least one of propane and propene from the absorbent to give a gas B containing at least one of propane and propene and (c) oxidizing the gas B obtained in stage (b) to form at least one of acrolein and acrylic acid, wherein no heterogeneously catalyzed dehydrogenation of propane without a supply of oxygen is carried out between steps (b) and (c), wherein, after step (c) has been carried out, at least one of unconverted propane and unconverted propene is separated off according to steps (a) and (b) and is recycled to step (c), and wherein the separating in step (b) is carried out by stripping with at least one of a pressure change and a temperature change, using at least one of steam, air and an oxygen/nitrogen mixture, and wherein during the separating (a) the gas mixture Ais brought into contact with the absorbent at a pressure of from 1 to 50 bar, and wherein the stripping (b) is carried out at a pressure of from 0.1 to 10 bar. 13. The process as claimed in claim 12, wherein, in step (c), propene is oxidized to at least one of acrolein and acrylic acid. 14. The process as claimed in claim 12, wherein, in step (c), propane is oxidized to at least one of acrolein and acrylic acid. 15. The process as claimed in claim 12, wherein the gas mixture A used in step (a) has the composition of a gas mixture which is obtained by at least one of homogeneous or heterogeneously catalyzed dehydrogenation of propane to propene. 16. The process as claimed in claim 12, wherein, after step (c) has been carried out, unconverted propane and optionally propene is subjected to a propane dehydrogenation and the product mixture obtained is subjected to step (a) again. 17. The process as claimed in claim 12, wherein step (c) is carried out directly after step (b). 18. The process as claimed in claim 12, wherein after step (b) and before step (c) a water quench is carried out for separating absorbent. 19. The process as claimed in claim 1, further comprising: dehydrogenating propane by heterogeneous catalysis in the presence of oxygen. 20. The process as claimed in claim 12, further comprising: dehydrogenating propane by heterogeneous catalysis in the presence of oxygen. 21. The process as claimed in claim 1, wherein the oxidizing is carried out in the presence of an oxidation catalyst with substantially no decrease in the activity of the oxidation catalyst. 22. The process as claimed in claim 1, wherein the absorbent is an organic solvent having a boiling point of from 200 to 350�� C. 23. The process as claimed in claim 1, wherein the absorbent is tetradecane. 24. The process as claimed in claim 1, further comprising: quenching gas B after the separating (b). 25. The process as claimed in claim 24, wherein quenching includes spraying water into the gas B to form a two phase mixture and separating an aqueous phase of the two phase mixture from an organic phase of the two phase mixture. 26. The process as claimed in claim 25, wherein the organic phase of the two phase liquid comprises the absorbent. 27. The process as claimed in claim 12, wherein the oxidizing is carried out in the presence of an oxidation catalyst with substantially no decrease in the activity of the oxidation catalyst. 28. The process as claimed in claim 12, wherein the absorbent is an organic solvent having a boiling point of from 200 to 350�� C. 29. The process as claimed in claim 12, wherein the absorbent is tetradecane. 30. The process as claimed in claim 12, further comprising: quenching gas B after the separating (b). 31. The process as claimed in claim 30, wherein the quenching includes spraying water into the gas B to form a two phase mixture and separating an aqueous phase of the two phase mixture from an organic phase of the two phase mixture. 32. The process as claimed in claim 31, wherein the organic phase of the two phase liquid comprises the absorbent. 33. The processes claimed in claim 1, wherein any hydrogen present in the gas mixture A is not present after the separating (b). 34. The processes claimed in claim 12, wherein any hydrogen present in the gas mixture A is not present after the separating (b). 35. The process as claimed in claim 1, wherein the stripping is carried out using air. 36. The process as claimed in claim 12, wherein the stripping is carried out using air. 37. The process as claimed in claim 1, wherein the stripping (b) is carried out at a pressure of from 1 to 5 bar, and the gas mixture A is contacted with the absorbent at a temperature of from 30 to 50�� C. 38. The process as claimed in claim 12, wherein the stripping (b) is carried out at a pressure of from 1 to 5 bar, and the gas mixture A is contacted with the absorbent at a temperature of from 30 to 50�� C.
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이 특허에 인용된 특허 (22)
Etzkorn William G. (Cross Lanes WV) Harkreader Gordon G. (Charleston WV), Anhydrous diluent process for the propylene oxidation reaction to acrolein and acrolein oxidation to acrylic acid.
Etzkorn William G. (Cross Lanes WV) Harkreader Gordon G. (Charleston WV), Anhydrous diluents for the propylene oxidation reaction to acrolein and acrolein oxidation to acrylic acid.
Savage Kelly B. (Coffeyville KS) Brinkmeyer Francis M. (Bartlesville OK) Bridges Steven D. (Bartlesville OK), Apparatus for dehydrogenation process control.
Otto Machhammer DE; Andreas Tenten DE; Harald Jachow DE; Susanne Haupt DE; Heiko Arnold DE; Signe Unverricht DE, Method for producing acrolein and/or acrylic acid from propane.
Khare Gyanesh P. (Bartlesville OK) Porter Randall A. (Bartlesville OK), Platinum and tin-containing catalyst and use thereof in alkane dehydrogenation.
Agaskar Pradyot A. (41 Navesink Dr. Hopewell NJ 08638) Grasselli Robert K. (12 Black Rock Rd. Chadds Ford PA 19317-9270) Michaels James N. (804 Devon La. Neshanic Station NJ 08853) Reischman P. Thoma, Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen.
Agaskar Pradyot A. (Lawrenceville NJ) Grasselli Robert K (Chadds Ford PA) Michaels James N. (Neshanic Station NJ) Reischman P. Thomas (Lambertville NJ) Stern David L. (Lawrenceville NJ) Tsikoyiannis , Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen.
Agaskar Pradyot A. (Lawrenceville NJ) Grasselli Robert K. (Chadds Ford PA) Michaels James N. (Neshanic Station NJ) Reischman P. Thomas (Lambertville NJ) Stern David L. (Lawrenceville NJ) Tsikoyiannis, Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen.
Agaskar Pradyot A. (Lawrenceville NJ) Grasselli Robert K. (Chadds Ford PA) Michaels James N. (Neshanic Station NJ) Reischman P. Thomas (Lambertville NJ) Stern David L. (Princeton NJ) Tsikoyiannis Joh, Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen.
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Dieterle, Martin; Schindler, Götz-Peter; Horstmann, Catharina; Müller-Engel, Klaus Joachim, Process for regenerating a catalyst bed deactivated in the course of a heterogeneously catalyzed partial dehydrogenation of a hydrocarbon.
Heilek, Joerg; Mueller Engel, Klaus Joachim; Adami, Christoph; Dieterle, Martin, Process for removing methacrolein from liquid phase comprising acrylic acid as a main constituent and target product, and methacrolein as a secondary component.
Cremer, Ulrich; Dieterle, Martin; Mueller-Engel, Klaus Joachim, Process for the long-term operation of a heterogeneously catalyzed partial gas phase oxidation of an organic starting compound.
Cremer, Ulrich; Dieterle, Martin; Mueller-Engel, Klaus Joachim, Process for the long-term operation of a heterogeneously catalyzed partial gas phase oxidation of an organic starting compound.
Hechler, Claus; Ruppel, Wilhelm; Schindler, Goetz-Peter; Klanner, Catharina; Bassler, Hans-Juergen; Dieterle, Martin; Klappert, Karl-Heinrich; Mueller-Engel, Klaus Joachim, Reactor for continuous heterogeneously catalyzed partial dehydrogenation of at least one hydrocarbon to be dehydrogenated.
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