IPC분류정보
국가/구분 |
United States(US) Patent
등록
|
국제특허분류(IPC7판) |
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출원번호 |
US-0216823
(2005-08-31)
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등록번호 |
US-7344585
(2008-03-18)
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발명자
/ 주소 |
- Kulprathipanja,Santi
- Soontraratpong,Jidapa
- Chiou,Jeffrey J.
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출원인 / 주소 |
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대리인 / 주소 |
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인용정보 |
피인용 횟수 :
6 인용 특허 :
8 |
초록
▼
An improved mixed matrix membrane for the separation of gases comprises a nitrogen containing compound such as an amine, silicone rubber and activated carbon on a porous support. The membrane may also comprise a carbonate such as potassium carbonate and a plasticizer such as polyethylene glycol. Mem
An improved mixed matrix membrane for the separation of gases comprises a nitrogen containing compound such as an amine, silicone rubber and activated carbon on a porous support. The membrane may also comprise a carbonate such as potassium carbonate and a plasticizer such as polyethylene glycol. Membranes of this design may be used in processing natural gas or other gases. The gases which may be separated by the membrane include mixtures of methane and carbon dioxide, mixtures of oxygen and nitrogen, and mixtures of carbon dioxide and nitrogen.
대표청구항
▼
What is claimed is: 1. A multi-component membrane for the separation of gases, the membrane comprising a mixture of silicone rubber, zeolite particles and a nitrogen containing compound on a cellulose acetate porous support media wherein said nitrogen containing compound is of a general formula:
What is claimed is: 1. A multi-component membrane for the separation of gases, the membrane comprising a mixture of silicone rubber, zeolite particles and a nitrogen containing compound on a cellulose acetate porous support media wherein said nitrogen containing compound is of a general formula: description="In-line Formulae" end="lead"NR1R2R3 description="In-line Formulae" end="tail" wherein R1, R2 and R3 may independently one or more of the following groups: C1-C50-alkyl, C3-C50-cycloalkyl, aromatic, alkyl substituted aromatic, such as C1-C50-alkyl substituted aromatic, aromatic substituted aliphatic moieties such as C1-C50-alkylene moieties substituted with one or more aromatic groups, C1-C50-hydroxyalkyl, amino-and/or hydroxyl-substituted C1-C50-alkyl, alkoxyalkyl such as C2-C50-alkoxyalkyl, dialkylaminoalkyl such as C3-C50-dialkylaminoalkyl, alkylaminoalkyl such as C2-C50-alkylaminoalkyl, heterocyclic, aromatic heterocyclic, alkyl substituted heterocyclic and alkyl substituted aromatic heterocyclic, such as C1-C50-alkyl substituted heterocyclic and aromatic heterocyclic compounds, and heterocyclic substituted aliphatic moieties such as C1-C50-alkylene moieties substituted with one or more aromatic groups and R1 and R2 may independently be hydrogen and R1 and R2 may form, with the nitrogen atom, a nitrogen-containing heterocycle, aromatic heterocycle, alkyl substituted heterocycle or alkyl substituted aromatic heterocycle, with the proviso that when R3 is alkyl and R1 and R2 are independently hydrogen then R3 is C4-C50-alkyl. 2. The multi-component membrane of claim 1 wherein the zeolite particles comprise one or more zeolites selected from the group consisting of sodium X, sodium Y, potassium X, potassium Y, calcium X, calcium Y, lithium X and lithium Y zeolite. 3. The multi-component membrane of claim 1 wherein the zeolite particles comprise lithium X or sodium X zeolite. 4. The multi-component membrane of claim 1 further comprising a plasticizer. 5. The multi-component membrane of claim 1 wherein said plasticizer is selected from the group consisting of polyethylene glycol, tetraethylene glycol, triethylene glycol, diethylene glycol, propylene glycol, dipropylene glycol, ethylene glycol and polypropylene glycol. 6. The multi-component membrane of claim 4 wherein said plasticizer is polyethylene glycol. 7. The multi-component membrane of claim 1 comprising 10-30 wt % of said zeolite particles. 8. The multi-component membrane of claim 1 wherein said nitrogen containing compound comprises an amine selected from the group consisting of monoethanolamine, diethanolamine, ethylene diamine and triethylene tetramine. 9. A process for separating a gas mixture comprising contacting a pressurized gas mixture with a multi-component membrane comprising a mixture of silicone rubber, zeolite particles and a nitrogen containing compound on a cellulose acetate porous support media wherein said nitrogen containing compound is of a general formula: description="In-line Formulae" end="lead"NR1R2R3 description="In-line Formulae" end="tail" wherein R1, R2 and R3 may independently one or more of the following groups: C1-C50-alkyl, C3-C50-cycloalkyl, aromatic, alkyl substituted aromatic, such as C1-C50-alkyl substituted aromatic, aromatic substituted aliphatic moieties such as C1-C50-alkylene moieties substituted with one or more aromatic groups, C1-C50-hydroxyalkyl, amino-and/or hydroxyl-substituted C1-C50-alkyl, alkoxyalkyl such as C2-C50-alkoxyalkyl, dialkylaminoalkyl such as C3-C50-dialkylaminoalkyl, alkylaminoalkyl such as C2-C50-alkylaminoalkyl, heterocyclic, aromatic heterocyclic, alkyl substituted heterocyclic and alkyl substituted aromatic heterocyclic, such as C1-C50-alkyl substituted heterocyclic and aromatic heterocyclic compounds, and heterocyclic substituted aliphatic moieties such as C1-C50-alkylene moieties substituted with one or more aromatic groups and R1 and R2 may independently be hydrogen and R1 and R2 may form, with the nitrogen atom, a nitrogen-containing heterocycle, aromatic heterocycle, alkyl substituted heterocycle or alkyl substituted aromatic heterocycle, with the proviso that when R3 is alkyl and R1 and R2 are independently hydrogen then R3 is C4-C50-alkyl. 10. The process of claim 9 wherein said multi-component membrane further comprises a plasticizer selected from the group consisting of polyethylene glycol, tetraethylene glycol, triethylene glycol, diethylene glycol, propylene glycol, dipropylene glycol, ethylene glycol and polypropylene glycol. 11. The process of claim 9 wherein the zeolite particles comprise one or more zeolites selected from the group consisting of sodium X, sodium Y, potassium X, potassium Y, calcium X, calcium Y, lithium X and lithium Y zeolite. 12. The process of claim 9 wherein the zeolite particles comprise lithium X or sodium X zeolite. 13. The process of claim 9 wherein said multi-component membrane comprises 10-30 wt % of said zeolite particles. 14. The process of claim 9 wherein said nitrogen containing compound comprises an amine selected from the group consisting of monoethanolamine, diethanolamine, ethylene diamine and triethylene tetramine. 15. The process of claim 9 wherein said gas mixture comprises at least two gases from the group consisting of methane, nitrogen, carbon dioxide, sulfur dioxide, ammonia, hydrogen sulfide, hydrogen and oxygen. 16. The process of claim 9 wherein said gas mixture comprises methane and carbon dioxide. 17. The process of claim 9 wherein said gas mixture comprises nitrogen and carbon dioxide.
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