[특허]Fischer-tropsch catalyst, preparation, and use thereof

[미국특허] Fischer-tropsch catalyst, preparation, and use thereof 원문보기

IPC분류정보
국가/구분	United States(US) Patent 등록
국제특허분류(IPC7판)	B01J-023/40 B01J-023/42 B01J-021/00 B01J-020/00 B01J-023/02
출원번호	US-0433846 (2001-12-11)
등록번호	US-7351679 (2008-04-01)
우선권정보	GB-0030170.5(2000-12-11)
국제출원번호	PCT/GB01/005461 (2001-12-11)
§371/§102 date	20031110 (20031110)
국제공개번호	WO02/047816 (2002-06-20)
발명자 / 주소	Eri,Sigrid Kinnari,Keijo J. Schanke,Dag Hilmen,Anne Mette
출원인 / 주소	Statoil ASA
대리인 / 주소	Patterson, Thuente, Skaar & Christensen, P.A.
인용정보	피인용 횟수 : 13 인용 특허 : 26

초록

Embodiments include a catalyst for use in a Fischer-Tropsch synthesis reaction which comprises cobalt supported on alumina. In some embodiments, the alumina support may have specific surface area of less than 50 m2/g and/or may be least 10% α-alumina.

대표청구항 ▼

The invention claimed is: 1. A catalyst for use in a Fischer-Tropsch synthesis reaction, the catalyst comprising catalyst particles comprising cobalt supported on an alumina support, wherein the alumina support has a specific surface area of less than 50 m2/g, and wherein the catalyst particles have an average particle size of between 0.01 mm and 0.2 mm. 2. The catalyst of claim 1 wherein the specific surface area of the alumina support is less than 30 m2/g. 3. The catalyst of claim 1, wherein the alumina support comprises at least 50% alpha-alumina. 4. The catalyst of claim 3, wherein the alumina support is substantially pure alpha-alumina. 5. The catalyst of claim 1, wherein cobalt represents from 3 to 35% by weight of the catalyst. 6. The catalyst of claim 5, wherein the cobalt represents from 5 to 20% by weight of the catalyst. 7. The catalyst of claim 5, further comprising a promoter that comprises rhenium and is present as 0.5 to 50% of the cobalt content. 8. The catalyst of claim 5, further comprising a promoter that is a member selected from the group consisting of platinum, rhodium, iridium, and combinations thereof, wherein the promoter is present as 0.1 to 50% of the cobalt content. 9. The catalyst of claim 1, further comprising a promoter. 10. The catalyst of claim 9, wherein the promoter comprises a member selected from the group consisting of rhenium, platinum, rhodium, iridium, and combinations thereof. 11. The catalyst of claim 1, comprising up to 2% rhenium by weight of the catalyst in total. 12. A catalyst for use in a Fischer-Tropsch synthesis reaction, the catalyst comprising cobalt supported on an alumina support, wherein the alumina support has a specific surface area of less than 50 m2/g, and wherein the alumina support comprises at least 10% alpha-alumina. 13. The catalyst of claim 12 wherein the catalyst comprises 3 to 35% by weight cobalt. 14. The catalyst of claim 12 wherein the catalyst further comprises a promoter chosen from the group consisting of rhenium, platinum, rhodium, iridium, and combinations thereof. 15. The catalyst of claim 14 wherein the promoter is present as 0.1 to 50% by weight of the cobalt content. 16. The catalyst of claim 12 further comprising rhenium present at less than 2% by weight of the catalyst. 17. A catalyst for use in a Fischer-Tropsch synthesis reaction, the catalyst comprising catalyst particles comprising cobalt supported on an alumina support, wherein the alumina support has a specific surface area of less than 50 m2/g, and wherein the catalyst particles have an average particle size of between 0.1 mm and 10 mm. 18. The catalyst of claim 17, wherein the catalyst particles have an average particle size of between 0.5 and 5 mm.

이 특허에 인용된 특허 (26) 인용/피인용 타임라인 분석

Kharas Karl C. C. ; Robota Heinz J. ; Nunan John G. ; Henk Michael G., Alloyed metal catalysts for the reduction of NO.sub.x in the exhaust gases from internal combustion engines containing e.
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Gerdes William H. (Hudson OH) Doddato Carmine M. (Cuyahoga Falls OH) Malone Patrick F. (Phoenix AZ), Catalyst carrier.
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Noguchi Masaaki (Nagoya JPX) Bunda Tsuchio (Okazaki JPX) Yamamoto Noboru (Nagoya JPX) Soejima Shigeo (Nagoya JPX), Catalyst carrier, catalyst and their manufacturing process.
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Fujitani Yoshiyasu (Aichi JPX) Muraki Hideaki (Aichi JPX) Kondoh Shiroh (Aichi JPX), Catalyst for hydrocarbon synthesis.
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Eri Sigrid (Trondheim PA NOX) Goodwin ; Jr. James G. (Pittsburgh PA) Marcelin George (Pittsburgh PA) Riis Trygve (Oslo NOX), Catalyst for production of hydrocarbons.
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Eri Sigrid (Trondheim PA NOX) Goodwin ; Jr. James G. (Pittsburgh PA) Marcelin George (Pittsburgh PA) Riis Trygve (Oslo NOX), Catalyst for production of hydrocarbons.
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Matsumoto Shinichi (Aichi JPX) Tanaka Toru (Aichi JPX) Ishikawa Yutaka (Shizuoka JPX) Matsuura Shinji (Shizuoka JPX) Shinjoh Hirofumi (Aichi JPX) Ozawa Masakuni (Aichi JPX), Catalyst for purification of exhaust gases.
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Noguchi Masaaki (Nagoya JPX) Bunda Tsuchio (Okazaki JPX) Yamamoto Noboru (Nagoya JPX) Soejima Shigeo (Nagoya JPX), Catalyst for purifying exhaust gas from an internal combustion engine.
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Baker Bruce G. (Torrens Park AUX) Clark Neville J. (Bellevue Heights AUX) McArthur Hamish (Bellevue Heights AUX) Summerville Edward (Everard Park AUX), Catalysts and methods of their manufacture.
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Bhasin Madan Mohan ; Jarrell Michael Scott, Catalysts comprising substantially pure alpha-alumina carrier for treating exhaust gases.
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Lok, Martinus C; Kelly, Gordon J; Gray, Gavin, Catalysts with high cobalt surface area.
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Van Berge, Peter Jacobus; Van De Loosdrecht, Jan; Visagie, Jacobus Lucas, Cobalt catalysts.
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Bonne Raimond Laurentius,GBX ; Lok Cornelis Martinus,GBX, Cobalt on alumina catalysts.
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Matusz Marek (Houston TX) Mesters Carolus M. A. M. (Amsterdam TX NLX) Buffum John E. (Houston TX), Ethylene oxide catalyst and process.
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Singleton, Alan H.; Oukaci, Rachid, Highly active fischer-tropsch catalyst having increased thermal stability.
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Eri Sigrid (Trondheim PA NOX) Goodwin ; Jr. James G. (Pittsburgh PA), Process for production of hydrocarbons.
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Eri Sigrid (Trondheim PA NOX) Goodwin ; Jr. James G. (Pittsburgh PA) Marcelin George (Pittsburgh PA) Riis Trygve (Oslo NOX), Process using a supported catalyst for hydrocarbon synthesis.
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Kinnari Keijo J.,NOX ; Schanke Dag,NOX, Regeneration of Fischer-Tropsch catalysts by using synthesis gas at a low flow rate.
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Murib Jawad H. (Cincinnati OH), Selective catalytic oxidation of carbon monoxide in hydrocarbon stream to carbon dioxide.
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Couvillion Mark C. (Freeport TX), Selective hydrogenation of acetylenes in the presence of butadiene and catalyst used in the hydrogenation.
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Gardner Lloyd E. (1340 SE. Hampden Sq. Bartlesville OK 74006) Kukes Simon G. (569 Braemer Ave. Naperville IL 60540), Support material containing catalyst for fixed hydrofining beds.
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Chuang Karl T.,CAX ; Zhang Mingqian,CAX ; Zhou Bing,CAX, Supported catalyst and process for catalytic oxidation of volatile organic compounds.
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Eri Sigrid (Trondheim PA NOX) Goodwin ; Jr. James G. (Pittsburgh PA) Marcelin George (Pittsburgh PA) Riis Trygve (Oslo NOX), Supported catalyst for hydrocarbon synthesis.
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Bellussi, Giuseppe; Zennaro, Roberto; Piccolo, Vincenzo; Radaelli, Enrico; Roy-Auberger, Magalie, Supported cobalt-based catalyst.
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Bellussi, Giuseppe; Zennaro, Roberto; Piccolo, Vincenzo; Radaelli, Enrico; Roy-Auberger, Magalie, Supported cobalt-based catalyst.
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Kukes Simon G. (Naperville IL) Harris Jesse R. (Bartlesville OK), Treated alumina material for fixed hydrofining beds.
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이 특허를 인용한 특허 (13) 인용/피인용 타임라인 분석

Koranne, Manoj M.; Rytter, Erling; Eri, Sigrid; Borg, Oyvind, Attrition resistant supports for fischer-tropsch catalyst and process for making same.
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Nakamura, Masanori; Suga, Katsuo; Sekiba, Toru; Wakamatsu, Hironori; Shiratori, Kazuyuki; Yasuda, Hirofumi, Catalyst powder, exhaust gas purifying catalyst, and method of producing the catalyst powder.
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Yasuda, Hirofumi; Suga, Katsuo; Nakamura, Masanori; Wakamatsu, Hironori; Shiratori, Kazuyuki; Sekiba, Toru, Catalyst powder, exhaust gas purifying catalyst, and method of producing the catalyst powder.
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Shiratori, Kazuyuki; Sekiba, Toru; Suga, Katsuo; Nakamura, Masanori; Wakamatsu, Hironori; Yasuda, Hirofumi, Catalyst powder, method of producing the catalyst powder, and exhaust gas purifying catalyst.
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Bezemer, Gerrit Leendert; Geerinck, Peter, Fischer-Tropsch catalysts.
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Rytter, Erling; Eri, Sigrid; Myrstad, Rune; Lindvåg, Odd Asbjørn, Fischer-Tropsch catalysts.
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Rytter, Erling; Skagseth, Torild Hulsund; Wigum, Hanne; Sincadu, Nonyameko, Fischer-Tropsch catalysts.
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Rytter, Erling; Borg, Øyvind; Eri, Sigrid; Sperle, Thomas, Fischer-Tropsch synthesis.
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Koranne, Manoj M.; Rytter, Erling; Eri, Sigrid; Borg, Oyvind, Fischer-tropsch catalysts.
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Espinoza, Rafael L.; Agee, Kenneth L., Optimized fischer-tropsch catalyst.
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Espinoza, Rafael L.; Agee, Kenneth L., Optimized fischer-tropsch catalyst.
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Nakamura, Masanori; Wakamatsu, Hironori; Suga, Katsuo; Sekiba, Toru, Powdery catalyst, exhaust-gas purifying catalyzer, and powdery catalyst production method.
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Lok, Cornelis Martinus; Bale, Sharon, Shaped eggshell catalyst containing cobalt, use and preparation thereof.
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[미국특허] Fischer-tropsch catalyst, preparation, and use thereof 원문보기

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