Systems and methods of producing a crude product
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C10G-047/02
C10G-047/00
출원번호
US-0014028
(2004-12-16)
등록번호
US-7413646
(2008-08-19)
발명자
/ 주소
Wellington,Scott Lee
Brownscombe,Thomas Fairchild
출원인 / 주소
Shell Oil Company
인용정보
피인용 횟수 :
22인용 특허 :
109
초록▼
Contact of a crude feed with a hydrogen source in the presence of an inorganic salt catalyst produces a total product that includes a crude product. The crude feed has a residue content of at least 0.2 grams of residue per gram of crude feed. The inorganic salt catalyst may include one or more alkal
Contact of a crude feed with a hydrogen source in the presence of an inorganic salt catalyst produces a total product that includes a crude product. The crude feed has a residue content of at least 0.2 grams of residue per gram of crude feed. The inorganic salt catalyst may include one or more alkali metals. The crude product is a liquid mixture at 25�� C. and 0.101 MPa. One or more properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed.
대표청구항▼
What is claimed is: 1. A method of producing a crude product, comprising: contacting a crude feed with a hydrogen source in the presence of an inorganic salt catalyst to produce a total product that includes the crude product, wherein the crude product is a liquid mixture at 25�� C. and 0.101 MPa,
What is claimed is: 1. A method of producing a crude product, comprising: contacting a crude feed with a hydrogen source in the presence of an inorganic salt catalyst to produce a total product that includes the crude product, wherein the crude product is a liquid mixture at 25�� C. and 0.101 MPa, the crude feed has a residue content of at least 0.2 grams of residue per gram of crude feed, the inorganic salt catalyst comprises alkali metal salts, wherein at least one of the alkali metal salts is an alkali metal carbonate, and the alkali metals have an atomic number of at least 11, and at least one atomic ratio of an alkali metal having an atomic number of at least 11 to an alkali metal having an atomic number greater than 11 is in a range from about 0.1 to about 10; and controlling contacting conditions such that the crude product has a residue content of at most 30% of the residue content of the crude feed, wherein residue content is as determined by ASTM Method D5307. 2. The method of claim 1, wherein the atomic ratio is in a range from about 0.2 to about 4. 3. The method of claim 1, wherein at least two of the alkali metals are sodium and potassium and an atomic ratio of sodium to potassium is in a range from about 0.2 to about 4. 4. The method of claim 1, wherein the alkali metals are sodium, potassium, cesium, rubidium, or mixtures thereof. 5. The method of claim 1, wherein at least three of the alkali metals are sodium, potassium, and rubidium, and each of the atomic ratios of sodium to potassium, sodium to rubidium, and potassium to rubidium is in a range from about 0.1 to about 5. 6. The method of claim 1, wherein at least three of the alkali metals are sodium, potassium, and cesium, and each of the atomic ratios of sodium to potassium, sodium to cesium, and potassium to cesium is in a range from about 0.1 to about 5. 7. The method of claim 1, wherein at least three of the alkali metals are potassium, cesium, rubidium, and each of the atomic ratios of potassium to cesium, potassium to rubidium, and cesium to rubidium is in a range from about 0.1 to about 5. 8. The method of claim 1, wherein the inorganic salt catalyst comprises in addition one or more alkali metal hydroxides. 9. The method of claim 1, wherein the inorganic salt catalyst comprises in addition one or more alkali metal hydrides. 10. The method of claim 1, wherein the inorganic salt catalyst comprises in addition one or more alkali metal hydroxides, alkali metal hydrides, or mixtures thereof. 11. The method of claim 1, wherein the inorganic salt catalyst comprises in addition one or more alkaline-earth metal salts. 12. The method of claim 1, wherein the hydrogen source is hydrogen, light hydrocarbons, water, or mixtures thereof. 13. The method of claim 1, wherein the inorganic salt catalyst comprises in addition one or more sulfides of one or more alkali metals, one or more sulfides of one or more alkaline-earth metals, one or more amides of one or more alkali metals, one or more amides of one or more alkaline-earth metals, or mixtures thereof. 14. The method of claim 1, wherein the crude feed has from about 0.2 to about 0.99 grams of residue. 15. The method of claim 1, wherein the contacting conditions are also controlled such that the crude product also has at most 0.05 grams of coke per gram of crude product. 16. The method of claim 1, wherein the contacting conditions are also controlled such that the crude product also has at most 0.03 grams of coke per gram of crude product. 17. The method of claim 1, wherein at least a portion of the total product is produced as a vapor, and the method further comprises condensing at least a portion of the vapor to form the crude product. 18. The method of claim 1, wherein the residue content of the crude product is at most 10% of the residue content of the crude feed. 19. The method of claim 1, wherein the crude product has from about 0.000001 to about 0.1 grams of residue per gram of crude product. 20. The method of claim 1, wherein the crude feed also has a total Ni/V/Fe content, expressed in total grams of Ni/V/Fe per gram of crude feed, and the vapor production is also controlled such that the crude product also has a total Ni/V/Fe content of at most 90% of the Ni/V/Fe content of the crude feed, wherein Ni/V/Fe content is as determined by ASTM Method D5863. 21. The method of claim 1, wherein the crude feed also has a sulfur content, expressed in grams of sulfur per gram of crude feed, and the vapor production is also controlled such that the crude product also has a sulfur content of at most 90% of the sulfur content of the crude feed, wherein sulfur content is as determined by ASTM Method D4294. 22. The method of claim 1, wherein the crude product also has at least 0.1 grams of vacuum gas oil per gram of crude product. 23. The method of claim 1, wherein the crude product also has from about 0.1 to about 0.5 grams of distillate per gram of crude product. 24. The method of claim 1, wherein the method further comprises providing steam to the crude feed prior to or during contacting. 25. The method of claim 1, wherein the method further comprises combining the crude product with a crude that is the same as or different from the crude feed to form a blend suitable for transportation and/or treatment facilities. 26. The method of claim 1, wherein the method further comprises processing the crude product to produce transportation fuel. 27. The method of claim 26, wherein the processing comprises distilling the crude product into one or more distillate fractions. 28. The method of claim 26, wherein the processing comprises hydrotreating.
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Jacobson Allan J. (Princeton NJ) Ho Teh C. (Bridgewater NJ) Chianelli Russel R. (Somerville NJ) Pecoraro Theresa A. (Danville CA), Amorphous, iron promoted Mo and W sulfide hydroprocessing catalysts and uses thereof.
Raybaud Pascal,FRX ; Toulhoat Herve,FRX ; Kasztelan Slavik,FRX, Catalyst compromising a mixed sulphide and its use for hydrorefining and hydroconverting hydrocarbons.
Boorman Philip M. (Calgary CAX) Chivers Tristram (Calgary CAX) Tavares Donald F. (Calgary CAX) Mahadev Kalabeerappa N. (Calgary CAX), Catalyst for sulphur removal from hydrocarbons.
Kretschmar Klaus (Dorsten DEX) Merz Ludwig (Recklinghausen DEX) Niemann Klaus (Oberhausen DEX) Guitian Jos (Dorsten DEX) Krasuk Julio (Duesseldorf DEX) Marruffo Franzo (Duesseldorf DEX) Kurzeja Klaus, Catalyst for the hydrogenation of hydrocarbon material.
Baird ; Jr. William C. (Baton Rouge LA) Bearden ; Jr. Roby (Baton Rouge LA), Combined desulfurization and hydroconversion with alkali metal hydroxides.
Baird ; Jr. William C. (Baton Rouge LA) Beardon ; Jr. Roby (Baton Rouge LA), Desulfurization and hydroconversion of residua with sodium hydride and hydrogen.
Aldridge Clyde L. (Baton Rouge LA) Bearden ; Jr. Roby (Baton Rouge LA) Lewis William E. (Baton Rouge LA), Hydroconversion of heavy feeds by use of both supported and unsupported catalysts.
Tamalis George R. (Houston TX) Chess David D. (Houston TX) Patel Mahendra S. (Hopewell Junction NY) Bhattacharya Ajit K. (Beacon NY) Gipson Robert M. (Port Arthur TX), Hydroconversion process containing a molybdenum complex recovered from epoxidation of olefinic hydrocarbons.
Varghese Philip (Voorhees NJ) Whitehurst Darrell D. (Titusville NJ), Hydrocracking of heavy feeds plus light fractions with dispersed dual function catalyst.
Sears Paul L. (Dunrobin CAX) de Bruijn Theo J. W. (Constance Bay CAX) Dawson William H. (Edmonton CAX) Pruden Barry B. (Calgary CAX) Jain Anil K. (Calgary CAX), Hydrocracking of heavy hydrocarbon oils with heavy hydrocarbon recycle.
Belinko Keith (Nepean CAX) Khulbe Chandra P. (Oakville CAX) Jain Anil K. (Oakville CAX), Hydrocracking of heavy oil in presence of ultrafine iron sulphate.
Ranganathan Ramaswami (Ottawa CAX) Denis Jean-Marie D. (Munster CAX) Pruden Barry B. (Ottawa CAX), Hydrocracking of heavy oils using iron coal catalyst.
Sudhakar Chakka (Wappingers Falls NY) Dolfinger ; Jr. Frank (Poughkeepsie NY) Cesar Max R. (Newburgh NY) Patel Mahendra S. (Hopewell Junction NY) Fritz Paul O. (Newburgh NY), Hydrodearomatization of hydrocarbon oils using novel “phophorus treated carbon”supported metal sulfide catalysts.
Eberly ; Jr. Paul E. (Baton Rouge LA), Hydrodesulfurization process with conversion of heavy hydrocarbons utilizing a catalyst containing a group IIA metal com.
Dohler Werner (Marl-Polsum DEX) Holighaus Rolf (Haltern DEX) Niemann Klaus (Oberhausen DEX), Hydrogenation of mineral oils contaminated with chlorinated hydrocarbons.
Dahlberg Arthur J. (Rodeo CA) Shinn John H. (Richmond CA) Rosenthal Joel W. (El Cerrito CA) Chu Tim T. (Oakland CA), Hydroprocessing of heavy hydrocarbonaceous oils.
Ebner Jerry R. (St. Louis MO) Gleaves John T. (St. Louis MO), Method and apparatus for carrying out catalyzed chemical reactions and for studying catalysis.
Ebner Jerry R. (St. Charles MO) Gleaves John T. (St. Charles MO), Method and apparatus for carrying out catalyzed chemical reactions and for studying catalysts.
Seamans James Dallas (Woodlands TX) Adams Charles Terrell (Houston TX) Dominguez Wendy Beth (Rosenberg TX) Chen Andrew An-Ju (Houston TX), Method of presulfurizing a hydrotreating, hydrocracking or tail gas treating catalyst.
Erekson Erek J. (LaGrange IL) Lee Anthony L. (Glen Ellyn IL) Barone S. Peter (Hoffman Estates IL) Solomon Irvine J. (Highland Park IL), Mixed basic metal oxide/sulfide catalyst.
Erekson Erek J. (LaGrange IL) Lee Anthony L. (Glen Ellyn IL) Barone S. Peter (Hoffman Estates IL) Solomon Irvine J. (Highland Park IL), Mixed basic metal sulfide catalyst.
Eijsbouts, Sonja; Oogjen, Bob Gerardus; Homan Free, Hermannus Willem; Cerfontain, Marinus Bruce; Riley, Kenneth Lloyd; Soled, Stuart Leon; Miseo, Sabato, Mixed metal catalyst, its preparation by co-precipitation, and its use.
Erekson Erek J. (LaGrange IL) Lee Anthony L. (Glen Ellyn IL), Mixed-solid solution tri-metallic oxide/sulfide catalyst and process for its preparation.
Carrazza Jose (San Antonio de Los Altos VEX) Pereira Pedro (San Antonio de Los Altos VEX) Martinez Nelson (San Antonio de Los Altos VEX), Process and catalyst for upgrading heavy hydrocarbon.
Deschamps Andr (Noisy le Roi FRX) Dezael Claude (Maisons Laffitte FRX) Franckowiak Sigismond (Rueil-Malmaison FRX), Process for converting heavy petroleum residues to hydrogen and gaseous distillable hydrocarbons.
Oleck Stephen M. (Moorestown NJ) Sherry Howard S. (Cherry Hill NJ) Fischer Ronald H. (Oakton VA) Milstein Donald (Cherry Hill NJ), Process for demetalation and desulfurization of petroleum oils.
Brons Glen ; Myers Ronald Damian,CAX ; Bearden ; Jr. Roby ; MacLeod John Brenton,CAX, Process for desulfurization of petroleum feeds utilizing sodium metal.
Krasuk Julio H. (Caracas VEX) Silva Fernando J. (Miranda VEX) Galiasso Roberto E. (Miranda VEX) Souto Alfredo (Miranda VEX), Process for hydroconversion and upgrading of heavy crudes of high metal and asphaltene content.
Boon Andries Qirin Maria,NLX ; Den Ouden Constantinus Johannes Jacobus,NLX ; Bhan Opinder Kishen, Process for hydrotreating metal-contaminated hydrocarbonaceous feedstock.
Eijsbouts, Sonja; Oogjen, Bob Gerardus; Homan Free, Harmannus Willem; Cerfontain, Marinus Bruce; Riley, Kenneth Lloyd; Soled, Stuart Leon; Miseo, Sabato, Process for preparing a mixed metal catalyst composition.
Kretschmar Klaus (Dorsten DEX) Merz Ludwig (Recklinghausen DEX) Niemann Klaus (Oberhausen DEX), Process for the hydrogenative conversion of heavy oils and residual oils, used oils and waste oils, mixed with sewage sl.
Seamans James D. (Woodlands TX) Adams Charles T. (Houston TX) Dominguez Wendy B. (Rosenberg TX) Chen Andrew A.-J. (Houston TX), Process of hydrotreating and/or hydrocracking hydrocarbon streams or tail gas treating sulfur-containing gas streams.
Colombet Pierre (Nantes FRX) Molinie Philippe (Saint Herblain FRX) Spiesser Michel (Nantes FRX), Production of binary rare earth/sulfur or transition metal/sulfur compounds.
Nongbri Govanon (Newtown PA) Brandt Susan M. (Oakford PA) Chervenak Michael C. (Pennington NJ), Selective operating conditions for high conversion of special petroleum feedstocks.
Dahlberg Arthur J. (Rodeo CA) Shinn John H. (Richmond CA) Rosenthal Joel W. (El Cerrito CA) Chu Tim T. (Oakland CA), Two-step hydroprocessing of heavy hydrocarbonaceous oils.
King Laurence F. (Mooretown CA) Gaspar Noel J. (Sarnia CA) Pasternak Israel S. (Sarnia CA), Visbreaking a heavy hydrocarbon feedstock in a regenerable molten medium in the presence of hydrogen.
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