Method and apparatus for monitoring polyolefin production
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
G01J-003/44
C08F-002/00
C08F-002/38
출원번호
US-0950249
(2004-09-24)
등록번호
US-7433761
(2008-10-07)
발명자
/ 주소
Battiste,David R.
출원인 / 주소
Chevron Philips Chemical Company, LP
대리인 / 주소
Fletcher Yoder
인용정보
피인용 횟수 :
5인용 특허 :
8
초록▼
The present technique provides for the use of spectroscopic probes, such as Raman probes, within the conduits of a polyolefin production system. The Raman probe or other spectroscopic probes may be used to obtain spectroscopic measurements of the contents of the conduits. The spectroscopic measurem
The present technique provides for the use of spectroscopic probes, such as Raman probes, within the conduits of a polyolefin production system. The Raman probe or other spectroscopic probes may be used to obtain spectroscopic measurements of the contents of the conduits. The spectroscopic measurements may be processed and analyzed to determine the composition of the conduit contents. In addition, the spectroscopic measurements may be used in conjunction with correlations or other statistical models to determine one or more properties of interest of a constituent of the conduit contents. One or more processes upstream and/or downstream of the conduit may be adjusted in response to the determined composition or composition properties.
대표청구항▼
What is claimed is: 1. A method of operating a feed system for a polyolefin polymerization reactor, comprising the acts of: exposing contents in a pumping mechanism within a feed system of a polyolefin polymerization reactor to a radiation emission from a spectroscopic probe; acquiring a spectrosco
What is claimed is: 1. A method of operating a feed system for a polyolefin polymerization reactor, comprising the acts of: exposing contents in a pumping mechanism within a feed system of a polyolefin polymerization reactor to a radiation emission from a spectroscopic probe; acquiring a spectroscopic signal from the contents on-line in substantially real-time in response to the radiation emission via the spectroscopic probe; and analyzing the spectroscopic signal to determine a property of the contents. 2. The method as recited in claim 1, comprising the act of controlling the addition rate of the feed stream to the polymerization reactor in response to the property. 3. The method as recited in claim 1, comprising the act of mixing a plurality of feedstocks in the feed system. 4. The method as recited in claim 1, wherein the polymerization reactor comprises a loop slurry reactor adapted to polymerize an olefin to form a polyolefin. 5. The method as recited in claim 1, wherein the polyolefin comprises polyethylene, polyethylene copolymer, polypropylene, or polypropylene copolymer, or any combination thereof. 6. The method as recited in claim 1, wherein the property comprises a concentration in the contents of a monomer, a comonomer, a diluent, a catalyst, a co-catalyst, a donor agent, hydrogen, an inert component, a contaminant, or a catalyst poison, or any combination thereof. 7. The method as recited in claim 1, wherein the spectroscopic probe comprises a Raman probe. 8. A method of monitoring and controlling a polyolefin production process, comprising the acts of: receiving a feedstock into a feed system of a polymerization reactor; exposing contents in a pumping mechanism in the feed system to a radiation emission from a spectroscopic probe; acquiring a spectroscopic signal from the contents in substantially real-time in response to the radiation emission via the spectroscopic probe; analyzing the spectroscopic signal to determine a property of the contents; and adjusting an operation of the polyolefin production process based on the property. 9. The method as recited in claim 8, wherein the act of adjusting the operation of the polyolefin production process comprises the act of adjusting an addition rate of a feed stream to the polymerization reactor. 10. The method as recited in claim 9, wherein the act of adjusting the addition rate of the feed stream comprises the act of manipulating the operation of a flow controller, a valve, a compressor, or a pump, or any combination thereof. 11. The method as recited in claim 8, wherein the act of adjusting the operation of the polyolefin production process comprises the act of adjusting a concentration of a component in a feed stream to the polymerization reactor. 12. The method as recited in claim 11, wherein the act of adjusting the concentration of the component in the feed stream comprises the act of manipulating the operation of a flow controller, a valve, a compressor, or any pump, or any combination thereof. 13. The method as recited in claim 8, wherein the act of adjusting the operation of the polyolefin production process comprises the act of adjusting a concentration of a component in the polymerization reactor. 14. The method as recited in claim 13, wherein the component comprises a catalyst. 15. The method as recited in claim 14, wherein the concentration of the catalyst is adjusted to control a polyolefin polymer property in the polymerization reactor, a polyolefin solids concentration in the polymerization reactor, a production rate of a polyolefin in the polymerization reactor, or a polyolefin slurry density in the polymerization reactor, or any combination thereof. 16. The method as recited in claim 13, wherein the component comprises a comonomer. 17. The method as recited in claim 16, wherein the concentration of the comonomer is adjusted to control a polyolefin product density in the polymerization reactor. 18. The method as recited in claim 13, wherein the component comprises hydrogen. 19. The method as recited in claim 18, wherein the concentration of hydrogen is adjusted to control a polyolefin melt flow rate in the polymerization reactor, or a polyolefin melt index in the polymerization reactor, or any combination thereof. 20. The method as recited in claim 8, wherein the act of adjusting the operation of the polyolefin production process comprises the act of adjusting an operation of the feed system or the polymerization reactor, or a combination thereof, to facilitate a polyolefin grade transition in the polymerization reactor. 21. The method as recited in claim 8, wherein the spectroscopic probe comprises a Raman probe. 22. A method of using a Raman spectroscopic device in a polyolefin production process, comprising the acts of: exposing a feed for a polymerization reactor to a radiation emission from a Raman spectroscopic probe; acquiring a Raman spectroscopic signal from the feed in response to the radiation emission; analyzing the Raman spectroscopic signal to determine a property of the feed; and terminating an upstream supply of feedstock in response to the property. 23. The method as recited in claim 22, wherein the Raman spectroscopic signal is acquired via the Raman spectroscopic probe. 24. The method as recited in claim 22, wherein the feed comprises an olefin monomer, a comonomer, a diluent, a catalyst, a co-catalyst, a donor, or a chain transfer agent, or any combination thereof. 25. The method as recited in claim 24, wherein: the olefin monomer and the comonomer comprise ethylene, propylene, butene, hexene, octene, or decene, or a combination thereof; the diluent comprises isobutane, propane, n-pentane, i-pentane, neopentane, or n-hexane, or a combination thereof; and the chain transfer agent comprises hydrogen. 26. The method as recited in claim 22, wherein the feed comprises an on-line mixture in a feed system, the feed system configured to manage feed components and to deliver a feed stream to the polymerization reactor. 27. The method as recited in claim 22, wherein the Raman spectroscopic signal is acquired in substantially real-time. 28. The method as recited in claim 22, wherein the feed comprises an off-line sample collected from a feed system. 29. The method as recited in claim 22, wherein the property comprises a concentration of an olefin monomer, a comonomer, a diluent, a catalyst, a co-catalyst, a chain transfer agent, a donor, an inert component, a contaminant, and a catalyst poison, or any combination thereof. 30. A method of using a Raman spectroscopic device in a polyolefin production process, comprising the acts of: exposing a feed for a polymerization reactor to a radiation emission from a Raman spectroscopic probe; acquiring a Raman spectroscopic signal from the feed in response to the radiation emission; analyzing the Raman spectroscopic signal to determine a property of the feed; and notifying a supplier of a feedstock to adjust a supplier operation in response to the property. 31. The method as recited in claim 22, comprising the act of adjusting a flow rate of a feed stream to the polymerization reactor in response to the property. 32. The method as recited in claim 22, comprising the act of adjusting a component concentration in a feed stream to the polymerization reactor in response to the property. 33. The method as recited in claim 22, comprising the act of adjusting a ratio of a first component to a second component in a feed stream to the polymerization reactor in response to the property. 34. A method of monitoring a polyolefin production process, comprising: receiving a feedstock into a feed system of a polyolefin reactor, wherein the feed system is configured to deliver a feed stream comprising the feedstock to the polyolefin reactor, and the polyolefin reactor is configured to polymerize at least one olefin in the presence of a catalyst into a polyolefin; placing a Raman spectroscopic probe tip into a process volume in the feed system; exposing contents in the process volume to a radiation emission from a Raman spectroscopic probe; acquiring a Raman spectroscopic signal from the contents in substantially real-time in response to the radiation emission via the spectroscopic probe; analyzing the Raman spectroscopic signal to determine a property of the contents; and notifying a supplier of the feedstock to adjust a supplier operation in response to the property. 35. The method as recited in claim 34, wherein the process volume comprises a conduit, a vessel, or a pumping mechanism, or a combination thereof. 36. The method as recited in claim 34, wherein the feed stream passes through the process volume. 37. The method as recited in claim 34, comprising the act of adjusting a feed rate to a polymerization reactor, a feed concentration to the polymerization reactor, or a concentration in the polymerization reactor, or any combination thereof, in response to the property. 38. A process for manufacturing a product comprising a polyolefin, the process comprising the act of: manufacturing a product at least a portion of which comprises a polyolefin, wherein the polyolefin is produced by a method comprising the acts of: receiving a feedstock into a feed system of a polymerization reactor, wherein the feed system is configured to deliver a feed stream comprising the feedstock to the polymerization reactor, and the polymerization reactor is configured to polymerize at least one olefin in the presence of a catalyst into the polyolefin; exposing contents on-line in the feed system to a radiation emission from a spectroscopic probe; acquiring a spectroscopic signal from the contents in substantially real-time in response to the radiation emission via the spectroscopic probe; analyzing the spectroscopic signal to determine a property of the contents; and terminating an upstream supply of feedstock in response to the property. 39. The process as recited in claim 38, wherein the spectroscopic probe comprises a Raman probe. 40. The process as recited in claim 38, comprising the act of obtaining the polyolefin. 41. The process as recited in claim 38, wherein the act of manufacturing comprises the act of processing the polyolefin to form the product or to form a polyolefin component of the product, or any combination thereof. 42. The process as recited in claim 41, wherein the act of processing comprises the act of blending, heating, melting, extruding, injection-molding, blow-molding, forming a film, incorporating an additive, or any combination thereof. 43. The process as recited in claim 38, wherein the act of manufacturing comprises the act of assembling a component formed from the polyolefin into the product. 44. The process as recited in claim 38, comprising the act of shipping the product or shipping a polyolefin component of the product, or a combination thereof. 45. The process as recited in claim 38, wherein the polyolefin comprises high density polyethylene (HDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), isotactic polypropylene (iPP), or syndiotactic polypropylene (sPP), or a combination thereof. 46. The process as recited in claim 38, wherein the product comprises film, piping, food packaging, beverage packaging, retail packaging, pharmaceutical packaging, furniture, carpeting, a consumer electronic, a household container, a household appliance, a toy, an automobile component, or an agricultural product, or a combination thereof.
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이 특허에 인용된 특허 (8)
Topliss Robert J. (Naperville IL) Brockmeier Norman F. (Wheaton IL) Lindahl Harold A. (Riverside IL), Advanced control strategies for melt flow rate and reactor concentration in the polypropylene slurry process.
Alsmeyer Daniel Charles (Kingsport TN) Pearce Michael Joseph (Blountville TN) Nicely Vincent Alvin (Kingsport TN), On-line quantitative analysis of chemical compositions by Raman spectrometry.
Kreischer Bruce E. ; Verser Donald W. ; Hein James E., Process and apparatus for recovering diluent, monomer, and comonomer from a polymerization reactor effluent.
Lange Sandra V. (Lake Jackson TX) Denton David P. (Richwood TX) Weller Joseph P. (Lake Jackson TX) Chauvel ; Jr. Jean P. (Lake Jackson TX) Farquharson Stuart (Freeport TX) Ruhl ; Jr. Harry D. (Midlan, Process control method for manufacturing polyolefin.
Buchanan Norma Lindsey (Kingsport TN) Alsmeyer Daniel Charles (Kingsport TN) Nelson Gregory Wayne (Kingsport TN) Edwards Roger Dale (Blackwater VA) Nicely Vincent Alvin (Kingsport TN), Robust spectroscoptic optical probe.
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