초록 ▼

Process and reaction unit for isothermal shift conversion of a carbon monoxide containing feed gas, the process comprising the steps of introducing the feed gas in a reaction unit into reactor tubes with a fixed bed of a shift conversion catalyst in a reaction zone; contacting the feed gas with the

Process and reaction unit for isothermal shift conversion of a carbon monoxide containing feed gas, the process comprising the steps of introducing the feed gas in a reaction unit into reactor tubes with a fixed bed of a shift conversion catalyst in a reaction zone; contacting the feed gas with the catalyst at conditions being effective in carbon monoxide shift conversion reaction with steam reactant to hydrogen and cooling the reaction by indirect heat exchange with a cooling agent by passing the cooling agent in a falling film along shell side of the reactor tubes and removing heated cooling agent from the falling film; passing hydrogen when it is formed by the shift conversion reaction through a hydrogen selective membrane to a permeate zone; withdrawing hydrogen from the permeate zone and carbon monoxide depleted feed gas from the reaction zone.

대표청구항 ▼

The invention claimed is: 1. Reaction unit comprising a reactor with a reactor shell; within a reactor shell one or more reactor tubes adapted to hold a fixed bed of a shift conversion catalyst and to exchange heat by indirect heat contact with a cooling agent in a falling film along shell side of

The invention claimed is: 1. Reaction unit comprising a reactor with a reactor shell; within a reactor shell one or more reactor tubes adapted to hold a fixed bed of a shift conversion catalyst and to exchange heat by indirect heat contact with a cooling agent in a falling film along shell side of the reactor tube, the upper end of the reactor tubes on the shell side being provided with a cooling agent distributor in the form of a perforated sleeve being arranged on shell side concentrically and spaced apart from the wall of the tubes, and a dosing means in the form of a sleeve with a conical outlet end concentrically with the tube wall; wherein the cooling agent distributor is fitted into the dosing means a hydrogen permeable membrane tube concentric arranged within the reactor tube with a permeation zone on shell side of the membrane tube being in contact with the catalyst bed and a permeate zone on tube side of the membrane tube; on the reactor shell inlet means for a carbon monoxide containing feed gas connected to inlet of the catalyst bed and outlet means for carbon monoxide depleted feed gas connected to outlet of the catalyst bed; outlet means for hydrogen containing permeate connected to the permeate zone of the membrane tube; inlet and outlet means for the cooling agent, the inlet means being adapted to introduce the cooling agent to shell side of the reactor tubes. 2. Reaction unit according to claim 1, further comprising inlet means for a sweep gas connected to the permeation zone of the membrane tube. 3. Reaction unit according to claim 2, further comprising a first pipe connected to the outlet means for the heated cooling agent and a second pipe connected to the inlet means for the sweep gas. 4. Reaction unit according to claim 1, further comprising a first pipe connected to the outlet means for the heated cooling agent a second pipe connected and to the inlet means for the feed gas.