Passivation of sulphur hydroconversion catalyst
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01J-020/34
B01J-020/30
B01J-038/30
B01J-038/00
B01J-038/22
B01J-027/02
출원번호
UP-0526499
(2004-02-06)
등록번호
US-7582587
(2009-09-16)
우선권정보
FR-03 01634(2003-02-11)
국제출원번호
PCT/FR04/000272
(2004-02-06)
§371/§102 date
20051005
(20051005)
국제공개번호
WO04/071655
(2004-08-26)
발명자
/ 주소
Dufresne, Pierre
Labruyere, Franck
출원인 / 주소
Eurecat S.A.
대리인 / 주소
Millen, White, Zelano & Branigan, P.C.
인용정보
피인용 횟수 :
12인용 특허 :
7
초록▼
The present invention concerns a process for ex situ oxidizing passivation of hydrocarbon hydroconversion catalysts, in particular for hydrotreatment in their sulphurized states, in which the sulphurized catalyst undergoes two treatments: contact with an oxidizing gas stream, and contact with an org
The present invention concerns a process for ex situ oxidizing passivation of hydrocarbon hydroconversion catalysts, in particular for hydrotreatment in their sulphurized states, in which the sulphurized catalyst undergoes two treatments: contact with an oxidizing gas stream, and contact with an organic liquid (for example hydrocarbon) which partially fills its pores.
대표청구항▼
The invention claimed is: 1. A process for ex situ oxidizing passivation of a sulfurized hydrocarbon hydroconversion catalyst, comprising a first step of contacting said sulfurized catalyst with at least one oxidizing gaseous stream, and a subsequent step of contacting the catalyst with at least on
The invention claimed is: 1. A process for ex situ oxidizing passivation of a sulfurized hydrocarbon hydroconversion catalyst, comprising a first step of contacting said sulfurized catalyst with at least one oxidizing gaseous stream, and a subsequent step of contacting the catalyst with at least one organic liquid with an initial boiling point of more than 120° C. which at least partially fills the pores of the catalyst. 2. A process according to claim 1, wherein contact with said gas stream is carried out in two stages, the first in a partial pressure of oxygen of less than 8 kPa, the second in a partial pressure of oxygen that is higher than that of the first stage and at most 21.3 kPa. 3. A process according to claim 2, wherein the second stage of the first step is carried out in air. 4. A process according to claim 2, wherein the organic liquid comprises an ester. 5. A process according to claim 1, wherein contact with said gas stream is carried out in one or more stages with one or more gas streams all having a partial pressure of oxygen of more than 8 kPa. 6. A process according to claim 5 wherein the stream or streams is/are air. 7. A process according to claim 5, wherein the organic liquid comprises an ester. 8. A process according to claim 7, wherein the catalyst comprises Co and Mo. 9. A process according to claim 8, wherein said ester comprises animal or vegetable oils or partially unsaturated fatty acid triglycerides. 10. A process according to claim 1, wherein the catalyst is treated while in motion. 11. A process according to claim 10, wherein the catalyst is in a moving bed. 12. A process according to claim 11, carried out in a rotary oven, a fluidized bed oven, a band oven, a gravity bed reactor oven or a rising bed device. 13. A process according to claim 1, wherein said organic liquid used in the second step comprises kerosene, gas oil, a vacuum distillate, a lube oil, a wax or a paraffin with an initial boiling point of more than 1800° C. 14. A process according to claim 1, wherein said organic liquid comprises a compound containing at least one heteroatom selected from the group consisting of oxygen, sulphur and nitrogen. 15. A process according to claim 14, wherein said organic liquid comprises an alcohol, an aldehyde, a ketone, an ester, an amine, an amide, a mercaptan, a sulphide or a sulphone. 16. A process according to claim 15, wherein the organic liquid is an ester. 17. A process according to claim 16, wherein said ester comprises animal or vegetable oils or partially unsaturated fatty acid triglycerides. 18. A process according to claim 1, wherein the catalyst comprises Co and Mo. 19. A process for ex situ oxidizing passivation of a sulfurized hydrocarbon hydroconversion catalyst, comprising a first step of contacting said sulfurized catalyst with at least one oxidizing gaseous stream, and a second step of contacting the catalyst with at least one organic liquid with an initial boiling point of more than 120° C. which at least partially fills the pores of the catalyst, said second step being conducted on the catalyst previously contacted with said at least one oxidizing gaseous stream and without any intervening chemical reaction between the first and second steps. 20. A process for ex situ oxidizing passivation of a sulfurized hydrocarbon hydroconversion catalyst, comprising a first step of contacting said sulfurized catalyst with at least one oxidizing gaseous stream, and an immediately subsequent step of contacting the catalyst with at least one organic liquid with an initial boiling point of more than 120° C. which at least partially fills the pores of the catalyst.
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이 특허에 인용된 특허 (7)
McCarthy,Stephen J.; Beeckman,Jean W.; Borghard,William G.; Hantzer,Sylvain, Ex-situ reduction and dry passivation of noble metal catalysts.
Dufresne Pierre,FRX ; Brahma Nilanjan,FRX ; Darcissac Jean,FRX ; Labruyere Franck,FRX, Process for incorporating sulfur into the pores of a hydrocarbon treatment catalyst.
Dufresne, Pierre; Labruyere, Franck; Meens, Maxime; Romano, Loredana, Process for sulfurization or presulfurization of solid particles of a catalyst or an adsorbent.
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