초록 ▼

An active system for regenerating a NOx adsorber and a particulate filter, the system includes a fuel source, a reformer for generating hydrogen and carbon monoxide in fluid communication with the fuel source, a first valve, a second valve, and a third valve in fluid communication with the reformer,

An active system for regenerating a NOx adsorber and a particulate filter, the system includes a fuel source, a reformer for generating hydrogen and carbon monoxide in fluid communication with the fuel source, a first valve, a second valve, and a third valve in fluid communication with the reformer, an oxidation catalyst, a NOx adsorber located downstream from the oxidation catalyst, a particulate filter located downstream from the NOx adsorber; and wherein the first valve, the second valve, and the third valve control fluid flow from the reformer to the oxidation catalyst, the NOx adsorber, and the particulate filter.

대표청구항 ▼

What is claimed is: 1. A process for regenerating and desulfating a NOx adsorber in an engine and exhaust system, comprising the steps of: providing an exhaust conduit in fluid communication with an exhaust outlet of the engine; supplying a hydrogen-and carbon monoxide-containing fluid from a sourc

What is claimed is: 1. A process for regenerating and desulfating a NOx adsorber in an engine and exhaust system, comprising the steps of: providing an exhaust conduit in fluid communication with an exhaust outlet of the engine; supplying a hydrogen-and carbon monoxide-containing fluid from a source of reformate into the exhaust conduit upstream of the NOx adsorber, said source of reformate being in parallel flow with an exhaust conduit; controllably flowing said hydrogen-and carbon monoxide-containing fluid into said exhaust conduit wherein said fluid reacts with NOx contained in the NOx adsorber, thereby chemically reducing the NOx to form gaseous nitrogen; exhausting the gaseous nitrogen from the system; providing a first oxidation catalyst device upstream of said NOx adsorber controllably flowing said hydrogen-and carbon monoxide-containing fluid into said exhaust conduit upstream of said first oxidation device; and generating an exotherm in the first oxidation catalyst device and heating an exhaust fluid passing therethrough to a temperature effective to desulfate the NOx adsorber. 2. The process of claim 1, wherein said source of reformate is a partial oxidation reformer. 3. The process of regenerating a particulate filter, and regenerating and desulfating a NOx adsorber in an engine and exhaust system as in claim 1, further comprising: providing a second oxidation catalyst device downstream of the NOx adsorber and upstream of the particulate filter, the second oxidation catalyst device being separate from the particulate filter; controllably flowing said hydrogen-and carbon monoxide-containing fluid into said exhaust conduit upstream of the second oxidation device; and generating an exotherm in the second oxidation catalyst device and heating an exhaust fluid passing therethrough to a temperature effective to combust trapped particles in the particulate filter. 4. The process of claim 1, wherein said NOx adsorber comprises a support, a catalytic metal component, and a NOx trapping material. 5. The process of claim 4, wherein said catalytic metal is selected from the group consisting of platinum, palladium, rhodium, iridium, osmium, ruthenium, tantalum, zirconium, yttrium, cerium, aluminum, nickel, copper, and mixtures thereof. 6. The process of claim 4, wherein said support is a porous material selected from the group consisting of alumina, gamma-alumina, zirconia, alpha-alumina, magnesium oxide cerium oxide, zirconium oxide, lanthanum oxide, yttrium oxide, neodymium oxide, and mixtures thereof. 7. An exhaust system for controlling NOx emissions from an engine comprising: an exhaust conduit in fluid communication with an exhaust outlet on said engine; a source of reformate adapted to provide a hydrogen-and carbon monoxide-containing fluid; a NOx adsorber having an inlet in fluid communication with said exhaust conduit, and an outlet, said source of reformate having an outlet in fluid communication with said exhaust conduit upstream of said NOx adsorber a first oxidation catalyst device having an inlet in fluid communication with said exhaust conduit, and an outlet in fluid communication with said NOx adsorber inlet, said outlet of said source of reformate in fluid communication with said exhaust conduit upstream of said first oxidation catalyst; a first valve in flow communication with said source of reformate for controlling said hydrogen-and carbon monoxide-containing fluid to said first oxidation catalyst device to generate an exotherm in said first oxidation catalyst to heat an exhaust fluid passing through said first oxidation catalyst to a temperature effective to desulfate said NOx adsorber; and a second valve in flow communication with said source of reformate for controlling said hydrogen-and carbon monoxide-containing fluid to said NOx adsorber, wherein said source of reformate is in parallel flow with said exhaust conduit. 8. The system of claim 7, wherein said source of reformate is a partial oxidation reformer. 9. The system of claim 7, further comprising: a particulate filter having an inlet in fluid communication with said exhaust conduit, and an outlet, a second oxidation catalyst having an inlet in fluid communication with said exhaust conduit and said outlet of said NOx adsorber, and an outlet in fluid communication with said inlet of said particulate filter, said second oxidation catalyst device being separate from said particulate filter and disposed upstream of said particulate filter, said outlet of said source of reformate in fluid communication with said exhaust conduit upstream of said second oxidation filter; and a third valve in flow communication with said source of reformate for controlling said hydrogen-and carbon monoxide-containing fluid to said second oxidation catalyst. 10. The system of claim 7, wherein said NOx adsorber comprises a support, a catalytic metal component, and a NOx trapping material. 11. The system of claim 10, wherein said catalytic metal is selected from the group consisting of platinum, palladium, rhodium, iridium, osmium, ruthenium, tantalum, zirconium, yttrium, cerium, aluminum, nickel, copper, and mixtures thereof. 12. The system of claim 10, wherein said support is a porous material selected from the group consisting of alumina, gamma-alumina, zirconia, alpha-alumina, magnesium oxide cerium oxide, zirconium oxide, lanthanum oxide, yttrium oxide, neodymium oxide, and mixtures thereof.