[미국특허]
Polyethylene compositions and pipe made from same
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C08F-010/02
C08F-010/00
C08F-010/16
C08L-023/06
C08L-023/00
F16L-009/12
F16L-009/00
출원번호
UP-0358959
(2006-02-22)
등록번호
US-7589162
(2009-09-24)
발명자
/ 주소
Krishnaswamy, Rajendra K.
Yang, Qing
Rohlfing, David C.
McDaniel, Max P.
Jayaratne, Kumudini C.
French, Jim E.
출원인 / 주소
Chevron Philips Chemical Company LP
대리인 / 주소
Conley Rose, P.C.
인용정보
피인용 횟수 :
13인용 특허 :
17
초록▼
A polymer composition comprising a density equal to or greater than about 0.947 g/cc, a high load melt index from about 1 g/10 min to about 30 g/10 min, and a tensile natural draw ratio less than about 14167 ρ-12958, where ρ is the density (g/cc) of the composition. A polymer composition c
A polymer composition comprising a density equal to or greater than about 0.947 g/cc, a high load melt index from about 1 g/10 min to about 30 g/10 min, and a tensile natural draw ratio less than about 14167 ρ-12958, where ρ is the density (g/cc) of the composition. A polymer composition comprising a tensile natural draw ratio less than about 14167ρ-12958, where ρ is the density (g/cc) of the composition and wherein less than about 1 weight percent of the composition comprises non-polymeric additives.
대표청구항▼
What is claimed is: 1. A polymer composition comprising: a copolymer of ethylene and an alpha-olefin comonomer, wherein the alpha-olefin comonomer comprises propylene, 1-butene, 1-pentene, 1-hexene, 3-methyl-1-butene, 4-methyl-1-pentene, 1-heptene, 1-octene, 1-nonene, 1-decene, or combinations ther
What is claimed is: 1. A polymer composition comprising: a copolymer of ethylene and an alpha-olefin comonomer, wherein the alpha-olefin comonomer comprises propylene, 1-butene, 1-pentene, 1-hexene, 3-methyl-1-butene, 4-methyl-1-pentene, 1-heptene, 1-octene, 1-nonene, 1-decene, or combinations thereof; a density equal to or greater than about 0.947 g/cc; a high load melt index from about 1 g/10 min to about 30 g/10 min; and a tensile natural draw ratio less than about 14157ρ-12958, where ρ is the density (g/cc) of the composition, wherein the tensile natural draw ratio is determined in accordance with ASTM D 638-00 at room temperature using a crosshead speed of 51 mm/min, and wherein the polymer composition comprises a metallocene polyethylene. 2. A polymer composition comprising: a density equal to or greater than about 0.947 g/cc; a high load melt index from about 1 g/10 min to about 30 g/10 min; and a tensile natural draw ratio less than about 14167ρ-12958, where ρ is the density (g/cc) of the composition, wherein the tensile natural draw ratio is determined in accordance with ASTM D 638-00 at room temperature using a crosshead speed of 51 mm/min, wherein the polymer composition comprises a metallocene polyethylene, and wherein the polymer of ethylene comprises a multimodal polymer. 3. The composition of claim 1 further comprising a PENT failure time greater than about 1000 hours. 4. The composition of claim 1 further comprising a tensile natural draw ratio less than about 25σy-130, where σy is the tensile yield stress of the composition. 5. The composition of claim 1 further comprising a tensile stress at break equal to or greater than 1.10 times the tensile yield stress of the composition. 6. The composition of claim 1 further comprising a rapid crack propagation S4 critical temperature equal to or less than about-1° C. for an 8 inch SDR11 pipe. 7. The composition of claim 1 further comprising a Charpy ductile to brittle transition temperature equal to or less than about-25° C. 8. The composition of claim 1 further comprising a razor-notched Charpy impact energy at 23° C. of greater than about 0.8 Joules. 9. The composition of claim 1 comprising less than about 1 weight percent of total non-polymeric additives. 10. A pipe fabricated from a polymer composition comprising: a density equal to or greater than about 0.947 g/cc; a high load melt index from about 1 g/10 min to about 30 g/10 min; and a tensile natural draw ratio less than about 14167ρ-12958, where ρ is the density (g/cc) of the composition, wherein the tensile natural draw ratio is determined in accordance with ASTM D 638-00 at room temperature using a crosshead speed of 51 mm/min, and wherein the polymer composition comprises a metallocene polyethylene. 11. The pipe of claim 10 further comprising a minimum required strength equal to or greater than 10.0 MPa. 12. A polymer composition comprising: two or more molecular weight modes; and a tensile natural draw ratio less than about 14167ρ-12958, where ρ is the density (g/cc) of the composition, wherein the tensile natural draw ratio is determined in accordance with ASTM D 638-00 at room temperature using a crosshead speed of 51 mm/min, wherein less than about 1 weight percent of the composition comprises non-polymeric additives, and wherein the polymer composition comprises a metallocene polyethylene. 13. The composition of claim 12 further comprising a high load melt index from about 1 g/10 min to about 30 g/10 min. 14. The composition of claim 12 further comprising a density equal to or greater than about 0.947 g/cc. 15. The composition of claim 12 further comprising a tensile natural draw ratio less than about 25σy-130, where σy is the tensile yield stress of the composition. 16. A pipe fabricated from a polymer composition comprising: a minimum required strength equal to or greater than 10.0 MPa; and a tensile natural draw ratio less than about 14167ρ-12958, where ρ is the density (g/cc) of the composition, wherein the tensile natural draw ratio is determined in accordance with ASTM D 638-00 at room temperature using a crosshead speed of 51 mm/min, wherein less than about 1 weight percent of the composition comprises non-polymeric additives, and wherein the polymer composition comprises a metallocene polyethylene. 17. A polymer composition comprising: a tensile natural draw ratio less than about 25σy-130, where σy is the tensile yield stress of the composition; a tensile natural draw ratio less than about 14167ρ-12958, where ρ is the density (g/cc) of the composition and wherein the tensile natural draw ratio is determined in accordance with ASTM D 638-00 at room temperature using a crosshead speed of 51 mm/min; and a tensile stress at break equal to or greater than 1.10 times the tensile yield stress of the composition, wherein the polymer composition comprises a metallocene polyethylene. 18. A polymer composition comprising: a density equal to or greater than about 0.947 g/cc; a high load melt index from about 1 g/10 min to about 30 g/10 min; and a tensile natural draw ratio less than about 14167ρ-12958, where ρ is the density (g/cc) of the composition, wherein the tensile natural draw ratio is determined in accordance with ASTM D 638-00 at room temperature using a crosshead speed of 51 mm/min, wherein the polymer composition comprises a metallocene polyethylene, and wherein the metallocene polyethylene is prepared from a dual metallocene catalyst system. 19. The polymer composition of claim 2 further comprising: a PENT failure time greater than about 1000 hours; a tensile natural draw ratio less than about 25σy-130, where σy is the tensile yield stress of the composition; and a tensile stress at break equal to or greater than 1.10 times the tensile yield stress of the composition. 20. The polymer composition of claim 19 further comprising: a rapid crack propagation S4 critical temperature equal to or less than about-1° C. for an 8 inch SDR11 pipe; a Charpy ductile to brittle transition temperature equal to or less than about-25° C.; and a razor-notched Charpy impact energy at 23° C. of greater than about 0.8 Joules. 21. The polymer composition of claim 20 further comprising an alpha-olefin comonomer comprising propylene, 1-butene, 1-pentene, 1-hexene, 3-methyl-1-butene, 4-methyl-1-pentene, 1-heptene, 1-octene, 1-nonene, 1-decene, or combinations thereof. 22. The pipe of claim 11 further comprising: a rapid crack propagation S4 critical temperature equal to or less than about-1° C. for an 8 inch SDR11 pipe; a Charpy ductile to brittle transition temperature equal to or less than about-25° C.; and a razor-notched Charpy impact energy at 23° C. of greater than about 0.8 Joules. 23. The pipe of claim 22 further comprising an alpha-olefin comonomer comprising propylene, 1-butene, 1-pentene, 1-hexene, 3-methyl-1-butene, 4-methyl-1-pentene, 1-heptene, 1-octene, 1-nonene, 1-decene, or combinations thereof. 24. The pipe of claim 23 further comprising: a PENT failure time greater than about 1000 hours; a tensile natural draw ratio less than about 25σy-130, where σy is the tensile yield stress of the composition; and a tensile stress at break equal to or greater than 1.10 times the tensile yield stress of the composition. 25. The pipe of claim 23 further comprising: a tensile natural draw ratio less than about 25σy-130, where σy is the tensile yield stress of the composition; and a tensile stress at break equal to or greater than 1.10 times the tensile yield stress of the composition. 26. The pipe of claim 25 further comprising: a PENT failure time greater than about 1000 hours; a rapid crack propagation S4 critical temperature equal to or less than about-1° C. for an 8 inch SDR11 pipe; a Charpy ductile to brittle transition temperature equal to or less than about-25° C.; and a razor-notched Charpy impact energy at 23° C. of greater than about 0.8 Joules. 27. The pipe of claim 16 further comprising: a PENT failure time greater than about 1000 hours; and a rapid crack propagation S4 critical temperature equal to or less than about-1° C. for an 8 inch SDR11 pipe. 28. The pipe of claim 27 further comprising: a Charpy ductile to brittle transition temperature equal to or less than about-25° C.; a razor-notched Charpy impact energy at 23° C. of greater than about 0.8 Joules; a tensile natural draw ratio less than about 25σy-130, where σy is the tensile yield stress of the composition; and a tensile stress at break equal to or greater than 1.10 times the tensile yield stress of the composition. 29. The pipe of claim 28 further comprising an alpha-olefin comonomer comprising propylene, 1-butene, 1-pentene, 1-hexene, 3-methyl-1-butene, 4-methyl-1-pentene, 1-heptene, 1-octene, 1-nonene, 1-decene, or combinations thereof. 30. The polymer composition of claim 17 further comprising: a Charpy ductile to brittle transition temperature equal to or less than about-25° C.; and a razor-notched Charpy impact energy at 23° C. of greater than about 0.8 Joules. 31. The polymer composition of claim 30 further comprising an alpha-olefin comonomer comprising propylene, 1-butene, 1-pentene, 1-hexene, 3-methyl-1-butene, 4-methyl-1-pentene, 1-heptene, 1-octene, 1-nonene, 1-decene, or combinations thereof. 32. The polymer composition of claim 31 further comprising: a PENT failure time greater than about 1000 hours; and a rapid crack propagation S4 critical temperature equal to or less than about-1° C. for an 8 inch SDR11 pipe. 33. The polymer composition of claim 18 further comprising an alpha-olefin comonomer comprising propylene, 1-butene, 1-pentene, 1-hexene, 3-methyl-1-butene, 4-methyl-1-pentene, 1-heptene, 1-octene, 1-nonene, 1-decene, or combinations thereof. 34. The polymer composition of claim 33 further comprising: a PENT failure time greater than about 1000 hours; a tensile stress at break equal to or greater than 1.10 times the tensile yield stress of the composition; and a rapid crack propagation S4 critical temperature equal to or less than about-1° C. for an 8 inch SDR11 pipe. 35. The polymer composition of claim 34 further comprising: a Charpy ductile to brittle transition temperature equal to or less than about-25° C.; a razor-notched Charpy impact energy at 23° C. of greater than about 0.8 Joules; and a tensile natural draw ratio less than about 25σy-130, where σy is the tensile yield stress of the composition.
Hottovy John D. (Bartlesville OK) Lawrence Frederick C. (Bartlesville OK) Lowe Barry W. (Bartlesville OK) Fangmeier James S. (Bartlesville OK), Apparatus and method for producing ethylene polymer.
Deepak R. Parikh ; Martin Guest ; David R. Speth, Compositions comprising a substantially random interpolymer of at least one .alpha.-olefin and at least one vinylidene aromatic monomer or hindered aliphatic vinylidene monomer.
Hottovy John D. ; Hensley Harvey D. ; Przelomski David J. ; Cymbaluk Teddy H. ; Franklin ; III Robert K. ; Perez Ethelwoldo P., High solids slurry polymerization.
Jenkins ; III John M. (So. Charleston WV) Jones Russell L. (Chapel Hill NC) Jones Thomas M. (So. Charleston WV) Beret Samil (Danville CA), Method for fluidized bed polymerization.
Martin,Joel L.; Thorn,Matthew G.; McDaniel,Max P.; Jensen,Michael D.; Yang,Qing; DesLauriers,Paul J.; Kertok,Mark E., Polymerization catalysts and process for producing bimodal polymers in a single reactor.
Hanson Donald O. (Bartlesville OK), Process and apparatus for separating diluents from solid polymers utilizing a two-stage flash and a cyclone separator.
Hlavinka, Mark L.; Ding, Errun; DesLauriers, Paul; Inn, Yongwoo; Cui, Lili; Yang, Qing; Sukhadia, Ashish M.; St. Jean, Guylaine; Buck, Richard M., Higher density polyolefins with improved stress crack resistance.
Hlavinka, Mark L.; Ding, Errun; DesLauriers, Paul; Inn, Yongwoo; Cui, Lili; Yang, Qing; Sukhadia, Ashish; St. Jean, Guylaine; Buck, Richard M., Higher density polyolefins with improved stress crack resistance.
Hlavinka, Mark L.; Ding, Errun; DesLauriers, Paul; Inn, Yongwoo; Cui, Lili; Yang, Qing; Sukhadia, Ashish; St. Jean, Guylaine; Buck, Richard M., Higher density polyolefins with improved stress crack resistance.
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