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An antireflective coating composition, antireflection films and fabrication method thereof. The antireflection film is constructed by stacked crosslink colloid particles, having a plurality of nanopores distributed uniformly therein. Due to the nanopores, the antireflection film has a refractive ind

An antireflective coating composition, antireflection films and fabrication method thereof. The antireflection film is constructed by stacked crosslink colloid particles, having a plurality of nanopores distributed uniformly therein. Due to the nanopores, the antireflection film has a refractive index less than 1.45, reducing the reflectivity of less than 3.0%. Furthermore, since the antireflection film comprises crosslink oxide colloid, the film exhibits superior mechanical strength and is suitable for use in display devices.

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What is claimed is: 1. An antireflective coating composition, comprising, as a uniform solution in an organic solvent: an initiator; a polymerizable oxide-containing colloid, comprising condensation products derived from (i) colloid particles having a formula (I), of ZxOy, and (ii) a compound with

What is claimed is: 1. An antireflective coating composition, comprising, as a uniform solution in an organic solvent: an initiator; a polymerizable oxide-containing colloid, comprising condensation products derived from (i) colloid particles having a formula (I), of ZxOy, and (ii) a compound with polymerizable groups having a formula (II), of (R1)n—M(OR2)m, wherein Z is element of Group IIIB, Group IVB, or Group VB, W, Be, Ti, Zr, or Zn; x and y are integers equal to or more than 1; R1 is acryloyl group, epoxy group, or isocyanato group; R2 is alkyl group or haloalkyl group; M is Si, Al, Ti, Zr, Sn, or Sb; and n and m are integers equal to or more than 1, wherein the weight ratio between (i) the colloid particles and (ii) the compound with polymerizable groups is 10:1˜1:10; and a template, wherein the weight ratio between the template and the polymerizable oxide-containing colloid is 45:55˜5:95, and the template comprises a polymer non-reactive with polymerizable oxide-containing colloid. 2. The antireflective coating composition as claimed in claim 1, wherein the colloid particles represented by formula (I) comprise WO3, ZnO, SiO2, Al2O3, TiO2, ZrO2, SnO2, BeO, Sb2O5, or combinations thereof. 3. The antireflective coating composition as claimed in claim 1, wherein the compound with polymerizable groups comprises glycidoxy triethoxysilane, glycidyloxypropyl triethoxy silane, or combinations thereof. 4. The antireflective coating composition as claimed in claim 1, further comprising a polymerizable monomer, wherein the weight ratio between the polymerizable monomer and the polymerizable oxide-containing colloid is 10:1 to 1:10. 5. The antireflective coating composition as claimed in claim 1, wherein the diameter of the colloid particle is 5˜150 nm. 6. The antireflective coating composition as claimed in claim 1, further comprising an additive, wherein the weight ratio between the additive and the polymerizable oxide-containing colloid is 1:99˜1:1, and the additive comprises planarization reagent, leveling agent, tackifier, filler, defoamer, or combinations thereof. 7. The antireflective coating composition as claimed in claim 1, wherein the polymerizable oxide-containing colloid comprises a mixture or product of a fluorine-containing polymerizable monomer and condensation products derived from (i) colloid particles with a formula (I), and (ii) a compound with polymerizable groups having a formula (II). 8. The antireflective coating composition as claimed in claim 7, wherein the fluorine-containing polymerizable monomer comprises 2,2,2-trifluoroethyl acrylate, 2,2,2 trifluoroethyl methacrylate, hexafluoroisopropyl acrylate, hexafluoroisopropyl methacrylate, 2,2,3,3,3-pentafluoropropyl acrylate, 2,2,3,3,3-pentafluoropropyl methacrylate, 2,2,3,3,4,4,4-heptafluorobutyl acrylate, 2,2,3,3,4,4,4-heptafluorobutyl methacrylate, 2,2,3,3-tetrafluoropropyl acrylate, 2,2,3,3-tetrafluoropropyl methacrylate, 2,2,3,4,4,4-hexafluorobutyl acrylate, 2,2,3,3,3-pentafluoropropyl methacrylate, 2,2,3,3,4,4,4-heptafluorobutyl methacrylate, 2,2,3,3-tetrafluoropropyl methacrylate, 2,2,3,4,4,4-hexafluorobutyl methacrylate, or combinations thereof. 9. A method for fabricating antireflection film, comprising: providing a substrate with a surface; forming a coating of an antireflective coating composition on the surface; and curing the coating to polymerize the antireflective coating composition, thereby forming an antireflection film, wherein the antireflective coating composition comprises, as a uniform solution in an organic solvent: an initiator; and a polymerizable oxide-containing colloid, comprising condensation products derived from (i) colloid particles having a formula (I), of ZxOy, and (ii) a compound with polymerizable groups having a formula (II), of (R1)n—M(OR2)m, wherein Z is element of Group IIIB, Group IVB, or Group VB, W, Be, Ti, Zr, or Zn; x and y are integers equal to or more than 1; R1 is acryloyl group, epoxy group, or isocyanato group; R2 is alkyl group or haloalkyl group; M is Si, Al, Ti, Zr, Sn, or SB; and n and m are integers equal to or more than 1, wherein the weight ratio between (i) the colloid particles and (ii) the compound with polymerizable groups is 10:1˜1:10; and a template, wherein the weight ratio between the template and the polymerizable oxide-containing colloid is 45:55˜5:95, and the template comprises a polymer non-reactive with polymerizable oxide-containing colloid. 10. The method as claimed in claim 9, wherein the colloid particles represented by formula (I) comprise WO3, ZnO, SiO2, Al2O3, TiO2, ZrO2, SnO2, BeO, Sb2O5, or combinations thereof. 11. The method as claimed in claim 9, wherein the compound with polymerizable groups comprises glycidoxy triethoxysilane, glycidyloxypropyl triethoxy silane, or combinations thereof. 12. The method as claimed in claim 9, further comprising a polymerizable monomer, wherein the weight ratio between the polymerizable monomer and the polymerizable oxide-containing colloid is 10:1 to 1:10. 13. The method as claimed in claim 9, wherein the diameter of the colloid particle is 5˜150 nm. 14. The method as claimed in claim 9, further comprising an additive, wherein the weight ratio between the additive and the polymerizable oxide-containing colloid is 1:99˜1:1, and the additive comprises planarization reagent, leveling agent, tackifier, filler, defoamer, or combinations thereof. 15. The method as claimed in claim 9, wherein the polymerizable oxide-containing colloid comprises a mixture or product of a fluorine-containing polymerizable monomer and condensation products derived from (i) colloid particles with a formula (I), and (ii) a compound with polymerizable groups having a formula (II). 16. The method as claimed in claim 9, wherein the coating is formed by spin coating, dip coating, roll coating, printing, embossing, stamping, or spray coating. 17. A method for fabricating antireflection film, comprising: providing a substrate with a surface; forming a coating of an antireflective coating composition on the surface, wherein the composition comprises, as a uniform solution in a first organic solvent: an initiator in an amount of 1 to 10 parts by weight; a template in an amount of 5 to 55 parts by weight; and a polymerizable oxide-containing colloid in an amount of 45 to 95 parts by weight, based on 100 parts by weight of the polymerizable oxide-containing colloid and the template, wherein the polymerizable oxide-containing colloid comprises condensation products derived from (i) colloid particles having a formula (I), of ZxOy, and (ii) a compound with polymerizable groups having a formula (II), of (R1)n—M(OR2)m, wherein Z is element of Group IIIB, Group IVB, or Group VB, W, Be, Ti, Zr, or Zn; x and y are integers equal to or more than 1; R1 is acryloyl group, epoxy group, or isocyanato group; R2 is alkyl group or haloalkyl group; M is Si, Al, Ti, Zr, Sn, or SB; and n and m are integers equal to or more than 1, and the weight ratio between (i) the colloid particles and (ii) the compound with polymerizable groups is 10:1˜1:10, and the template comprises a polymer non-reactive with polymerizable oxide-containing colloid; curing the coating to polymerize the antireflective coating composition to form a dry film; and dissolving the template from the dry film by a second organic solvent to remain anantireflection film with nanopores. 18. The method as claimed in claim 17, wherein the colloid particles represented by formula (I) comprises WO3, ZnO, SiO2, Al2O3, TiO2, ZrO2, SnO2, BeO, Sb2O5, or combinations thereof. 19. The method as claimed in claim 17, wherein the compound with polymerizable groups comprises glycidoxy triethoxysilane, glycidyloxypropyl triethoxy silane, or combinations thereof. 20. The method as claimed in claim 17, further comprising a polymerizable monomer, wherein the weight ratio between the polymerizable monomer and the polymerizable oxide-containing colloid is 10:1 to 1:10. 21. The method as claimed in claim 17, wherein the diameter of the colloid particle is 5˜150 nm. 22. The method as claimed in claim 17, further comprising an additive, wherein the weight ratio between the additive and the polymerizable oxide-containing colloid is 1:99˜1:1, and the additive comprises planarization reagent, leveling agent, tackifier, filler, defoamer, or combinations thereof. 23. The method as claimed in claim 17, wherein the polymerizable oxide-containing colloid comprises a mixture or product of a fluorine-containing polymerizable monomer and condensation products derived from (i) colloid particles with a formula (I), and (ii) a compound with polymerizable groups having a formula (II). 24. The method as claimed in claim 17, wherein the coating is formed by spin coating, dip coating, roll coating, printing, embossing, stamping, or spray coating. 25. The method as claimed in claim 17, wherein the template comprises non-reactive organic compound, non-reactive oligomer, non-reactive polymer, or combinations thereof. 26. An antireflection film produced by the method of claim 9. 27. An antireflection film produced by the method of claim 17.