IPC분류정보
국가/구분 |
United States(US) Patent
등록
|
국제특허분류(IPC7판) |
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출원번호 |
UP-0303636
(2005-12-16)
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등록번호 |
US-7678950
(2010-04-21)
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발명자
/ 주소 |
- Yao, Jianhua
- Sughrue, II, Edward L.
- Kimble, James B.
- Cross, Joseph B.
- Johnson, Marvin M.
- Ghonasgi, Dhananjay B.
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출원인 / 주소 |
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인용정보 |
피인용 횟수 :
9 인용 특허 :
24 |
초록
▼
Processes for the conversion of carbohydrates to gasoline boiling range hydrocarbons, and processes for increasing the solubility of carbohydrates used in such processes are disclosed. The solubility of carbohydrates may be increased by contacting the carbohydrate with an ion-exchange resin. The dis
Processes for the conversion of carbohydrates to gasoline boiling range hydrocarbons, and processes for increasing the solubility of carbohydrates used in such processes are disclosed. The solubility of carbohydrates may be increased by contacting the carbohydrate with an ion-exchange resin. The dissolved product may be hydrogenated and reacted in the present of a catalyst to form a reaction product containing non-aromatic and aromatic gasoline boiling range hydrocarbons.
대표청구항
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What is claimed is: 1. A process comprising: contacting a carbohydrate-containing material with an ion-exchange resin in a liquid medium to form a mixture; heating said mixture at a temperature sufficient to substantially dissolve said carbohydrate-containing material in said liquid medium; and con
What is claimed is: 1. A process comprising: contacting a carbohydrate-containing material with an ion-exchange resin in a liquid medium to form a mixture; heating said mixture at a temperature sufficient to substantially dissolve said carbohydrate-containing material in said liquid medium; and contacting said mixture with a hydrogenation catalyst under a condition sufficient to form a hydrogenated product. 2. The process of claim 1, wherein said carbohydrate-containing material has an effective hydrogen to carbon ratio of less than about one. 3. The process of claim 1, wherein said carbohydrate-containing material is a polysaccharide. 4. The process of claim 1, wherein said carbohydrate-containing material is selected from the group consisting of starch, cellulose, glycogen and mixtures thereof. 5. The process of claim 1, wherein said carbohydrate-containing material is starch. 6. The process of claim 1, wherein said ion-exchange resin comprises a strongly acidic cation-exchange resin. 7. The process of claim 1, wherein said ion-exchange resin contains sulfonic groups. 8. The process of claim 1, wherein said ion-exchange resin is present in an amount in the range of from about 0.02 to about 10 weight percent, based on the weight of the mixture. 9. The process of claim 1, wherein said temperature is in the range of from about 100.degree.C. to about 180.degree.C. 10. The process of claim 1, wherein said temperature is in the range of from about 120.degree.C. to about 160.degree.C. 11. The process of claim 1, wherein said temperature is in the range of from about 120.degree.C. to about 140.degree.C. 12. The process of claim 1, wherein said contacting comprises loading the mixture into an autoclave, flushing the autoclave with nitrogen, and sealing the autoclave. 13. The process of claim 1, wherein said heating comprises heating the mixture at a temperature in the range of from about 100.degree.C. to about 180.degree.C. until the mixture is dissolved. 14. The process of claim 1, wherein said liquid medium is water. 15. The process of claim 1, wherein said ion-exchange resin is a polystyrene supported resin containing sulfonic acid groups. 16. The process of claim 1, wherein between 95% and 100% of said carbohydrate-containing material is dissolved in said liquid medium. 17. A process comprising: contacting a carbohydrate-containing material with an ion-exchange resin in a liquid medium under a condition sufficient to substantially dissolve the carbohydrate-containing material in the liquid medium to form a mixture, contacting the mixture with a hydrogenation catalyst under a condition sufficient to form a hydrogenated product, and contacting a mixture comprising the hydrogenated product with a catalyst composition comprising a zeolite under a condition sufficient to form a reaction product containing gasoline boiling range hydrocarbons. 18. The process of claim 17, wherein said carbohydrate-containing material has an effective hydrogen to carbon ratio of less than about 1. 19. The process of claim 17, wherein said carbohydrate-containing material is a polysaccharide. 20. The process of claim 17, wherein said carbohydrate-containing material is selected from the group consisting of starch, cellulose, glycogen and mixtures thereof. 21. The process of claim 17, wherein said carbohydrate-containing material is starch. 22. The process of claim 17, wherein the ion-exchange resin comprises an acidic cation-exchange resin. 23. The process of claim 17, wherein the ion-exchange resin contains sulfonic groups. 24. The process of claim 17, wherein said ion-exchange resin is present in an amount in the range of from about 0.02 to about 10 weight percent, based on the weight of the mixture. 25. The process of claim 17, wherein said condition sufficient to substantially dissolve the carbohydrate-containing material in the liquid medium to form a mixture comprises a temperature in the range of from about 100.degree.C. to about 180.degree.C. and a pressure in the range of from about 10 to about 500 psig. 26. The process of claim 17, wherein said hydrogenation catalyst comprises a supported ruthenium catalyst. 27. The process of claim 17, wherein said condition sufficient to form a hydrogenated product comprises a temperature in the range of from about 80.degree. C. to about 300.degree.C. and a pressure in the range of from about 100 to about 2000 psig. 28. The process of claim 17, wherein said condition sufficient to form a reaction product containing gasoline boiling range hydrocarbons comprises a temperature in the range of about 200.degree.C. to about 800.degree.C. and a pressure in the range of from about 1 to about 500 psig. 29. The process of claim 17, wherein said contacting comprises loading the mixture into an autoclave, flushing the autoclave with nitrogen, and sealing the autoclave. 30. The process of claim 17, wherein said heating comprises heating the mixture at a temperature in the range of from about 100.degree.C. to about 180.degree.C. until the mixture is dissolved. 31. The process of claim 17, wherein said liquid medium is water. 32. The process of claim 17, wherein said ion-exchange resin is a polystyrene supported resin containing sulfonic acid groups. 33. The process of claim 17, wherein between 95% and 100% of said carbohydrate-containing material is dissolved in said liquid medium. 34. The process of claim 17, wherein said hydrogenated product is selected from the group consisting of ketones, epoxides, diols, glycols, furans, and organic acids. 35. The process of claim 17, wherein said hydrogenated product is lactic acid. 36. The process of claim 17, wherein said hydrogenated product is sorbitol. 37. The process of claim 17, wherein said mixture further comprises a hydrocarbon. 38. The process of claim 37, wherein said hydrocarbon is isopentane. 39. A process in accordance with claim 17 wherein said zeolite is selected from the group consisting of ZSM-5, ZSM-8, ZSM-11, ZSM-12, ZSM-35, ZSM-38 and combinations thereof. 40. A process in accordance with claim 17 wherein said zeolite is ZSM-5. 41. The process in accordance with claim 17 further comprising a step of modifying a zeolite by steam treatment prior to a step of contacting a mixture comprising the hydrogenated product with a catalyst composition comprising said zeolite. 42. The process in accordance with claim l7 further comprising a step of modifying a zeolite by acid treatment prior to a step of contacting a mixture comprising the hydrogenated product with a catalyst composition comprising said zeolite. 43. The process in accordance with claim 17 further comprising a step of modifying a zeolite by metal cation prior to a step of contacting a mixture comprising the hydrogenated product with a catalyst composition comprising said zeolite. 44. A process in accordance with claim 43 wherein said metal cation is selected from the group consisting of zinc, gallium, and nickel. 45. A process comprising: contacting an aqueous solution containing at least one carbohydrate with a hydrogenation catalyst under a condition sufficient to form a hydrogenated product, and contacting the hydrogenated product with a catalyst composition comprising a zeolite under conditions sufficient to form a reaction product containing gasoline boiling range hydrocarbons. 46. The process of claim 45, wherein the aqueous solution contains corn syrup. 47. The process of claim 45, wherein the hydrogenation catalyst comprises a supported ruthenium catalyst. 48. The process of claim 45, wherein the conditions sufficient to form a hydrogenated product comprises a temperature n the range of from about 80.degree. C. to about 300.degree.C. and a pressure in the range of from about 100 to about 1000 psig. 49. A process in accordance with claim 45 wherein said zeolite is selected from the group consisting of ZSM-5, ZSM-8, ZSM-11, ZSM-12, ZSM-35, ZSM-38 and combinations thereof. 50. A process in accordance with claim 45 wherein said zeolite is ZSM-5. 51. A process in accordance with claim 45 wherein said zeolite is modified by steam treatment. 52. The process in accordance with claim 45 further comprising a step of modifying a zeolite by acid treatment prior to a step of contacting the hydrogenated product with a catalyst composition comprising said zeolite. 53. A composition produced by the process of claim 45. 54. A process comprising: contacting a mixture comprising a hydrogenated carbohydrate-containing compound and a hydrocarbon with a catalyst composition comprising a zeolite under a reaction conditions sufficient to form a reaction product containing gasoline boiling range hydrocarbons. 55. The process of claim 54, wherein the hydrogenated carbohydrate-containing compound is sorbitol. 56. The process of claim 54, wherein said hydrogenated carbohydrate-containing compound is lactic acid. 57. The process of claim 54, wherein said hydrocarbon comprises isopentane. 58. The process of claim 54, wherein said hydrogenated carbohydrate-containing compound is selected from the group consisting of ketones, epoxides, diols, glycols, furans, and organic acids. 59. A product produced by the process of claim 54. 60. The process of claim 54, wherein the condition sufficient to form a reaction product containing gasoline boiling range hydrocarbons comprises a temperature in the range of about 200.degree.C. to about 600.degree.C. and a pressure in the range of from about 1 to about 100 psig. 61. The process of claim 54, wherein the reaction conditions comprise a pressure in the range of from about 20 to about 200 psig. 62. A process in accordance with claim 54 wherein said zeolite is selected from the group consisting of ZSM-5, ZSM-8, ZSM-11, ZSM-12, ZSM-35, ZSM-38, and combinations thereof. 63. A process in accordance with claim 54 wherein said zeolite is ZSM-5. 64. A process in accordance with claim 54 wherein said zeolite is modified by steam treatment. 65. The process in accordance with claim 54 further comprising a step of modifying a zeolite by acid treatment prior to a step of contacting a mixture comprising a hydrogenated carbohydrate-containing compound with a catalyst composition comprising said zeolite. 66. The process in accordance with claim 54 further comprising a step of modifying a zeolite by a metal cation prior to a step of contacting a mixture comprising a hydrogenated carbohydrate-containing compound with a catalyst composition comprising said zeolite. 67. The process in accordance with claim 66 wherein said metal cation is selected from the group consisting of zinc, gallium, and nickel.
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