초록 ▼

A composition and method of storing and releasing fuel gas such as hydrogen, methane or natural gas is provided which utilizes lightly crosslinked high density polyethylene pellets. Fuel gas is stored by placing the pellets in a reaction chamber which is heated to a temperature slightly above the cr

A composition and method of storing and releasing fuel gas such as hydrogen, methane or natural gas is provided which utilizes lightly crosslinked high density polyethylene pellets. Fuel gas is stored by placing the pellets in a reaction chamber which is heated to a temperature slightly above the crystalline melting point of the pellets, followed by the introduction of fuel gas into the chamber. The fuel gas permeates the pellets and becomes contained therein upon cooling of the pellets under pressure. The fuel gas may be stored indefinitely in the pellets at ambient temperature. When release of the fuel gas is desired, the pellets are incrementally metered into a discharge chamber and are heated to a temperature above the crystalline melting point of the pellets under a pressure from about 5 to 200 psi such that the fuel gas is released from the pellets for use. The expended pellets may then be recycled for further fuel gas storage.

대표청구항 ▼

What is claimed is: 1. A method of storing a quantity of fuel gas comprising: providing lightly crosslinked high density polyethylene pellets; placing said pellets in a reaction chamber, said reaction chamber including heating and cooling elements therein; introducing fuel gas into said chamber und

What is claimed is: 1. A method of storing a quantity of fuel gas comprising: providing lightly crosslinked high density polyethylene pellets; placing said pellets in a reaction chamber, said reaction chamber including heating and cooling elements therein; introducing fuel gas into said chamber under pressure while heating said chamber to a temperature slightly above the crystalline melting point of said pellets such that said fuel gas permeates said pellets; and cooling said chamber below the melting point of said pellets under pressure such that said fuel gas is contained in said pellets. 2. The method of claim 1 wherein said chamber is heated to a temperature between about 132° C. and 170° C. 3. The method of claim 1 wherein said chamber is heated to a temperature of about 150° C. 4. The method of claim 1 wherein said polyethylene pellets have an initial diameter of between about 1/16 inch and 3/16 inch. 5. The method of claim 1 wherein said polyethylene pellets have a density of between about 0.95 to 0.97 g/cm3. 6. The method of claim 1 wherein said polyethylene pellets have a melt index of from about 0.2 to 2.0. 7. The method of claim 1 wherein said lightly crosslinked high density polyethylene pellets have been crosslinked by chemical grafting, gamma irradiation, or electron bombardment. 8. The method of claim 1 wherein said chamber is maintained at a pressure between about 50 to 4000 psi during introduction of said fuel gas. 9. The method of claim 1 including storing said pellets containing fuel gas therein at ambient temperature and pressure. 10. The method of claim 1 wherein said fuel gas is selected from hydrogen, methane, and natural gas. 11. Lightly crosslinked high density polyethylene pellets including fuel gas therein formed by the method of claim 1. 12. A method of using a composition comprising lightly crosslinked high density polyethylene pellets having fuel gas contained therein comprising releasing said fuel gas stored in said pellets by incrementally placing said pellets in a discharge chamber including heating and cooling elements therein and heating said discharge chamber to a temperature slightly above the crystalline melting point of the pellets such that said fuel gas is released. 13. The method of claim 12 wherein said fuel gas is released under a pressure of between about 5 to 200 psi. 14. The method of claim 12 wherein said fuel gas is released under a pressure of less than or equal to about 50 psi. 15. The method of claim 12 including cooling said chamber to ambient temperature and recovering the pellets. 16. The method of claim 12 including reusing said recovered high density polyethylene pellets for further fuel gas storage. 17. A composition comprising lightly crosslinked high density polyethylene pellets having a useful amount of fuel gas contained therein.