초록 ▼

To provide an adhesive composition which shows high adhesion with a glass substrate and has excellent heat resistance, moisture resistance and moist heat resistance, an adhesive optical film comprising an adhesive layer made of the adhesive composition, which shows high adhesion between the adhesive

To provide an adhesive composition which shows high adhesion with a glass substrate and has excellent heat resistance, moisture resistance and moist heat resistance, an adhesive optical film comprising an adhesive layer made of the adhesive composition, which shows high adhesion between the adhesive layer and an optical film and effectively suppresses the occurrence of adhesive residue and lack of adhesive and also has excellent heat resistance, moisture resistance and moist heat resistance, and an image display device comprising the adhesive optical film, the adhesive optical film comprises an optical film 1, an adhesive layer 3 made of a water dispersible adhesive composition comprising, as raw monomers, an alkyl (meth)acrylate ester whose alkyl group has 4 to 18 carbon atoms, a carboxyl group-containing vinyl monomer, a phosphoric acid group-containing vinyl monomer, and a copolymerizable vinyl monomer which is optionally copolymerizable with the above monomers, wherein a carboxyl group concentration is from 0.05 to 1.50 mmol/g and a phosphoric acid group concentration is from 0.01 to 0.45 mmol/g in the raw monomers, an under coat layer 2 containing an oxazoline group-containing polymer, and being interposed between the optical film 1 and the adhesive layer 3, and the adhesive optical film is applied onto an image display device.

대표청구항 ▼

What is claim is: 1. An adhesive composition comprising, as raw monomers, an alkyl (meth)acrylate ester whose alkyl group has 4 to 18 carbon atoms, a carboxyl group-containing vinyl monomer, a phosphoric acid group-containing vinyl monomer represented by the following general formula (1), and a cop

What is claim is: 1. An adhesive composition comprising, as raw monomers, an alkyl (meth)acrylate ester whose alkyl group has 4 to 18 carbon atoms, a carboxyl group-containing vinyl monomer, a phosphoric acid group-containing vinyl monomer represented by the following general formula (1), and a copolymerizable vinyl monomer which is optionally copolymerizable with the above monomers, wherein with respect to a proportion of the raw monomers, an amount of the alkyl (meth) acrylate ester is from 60 to 99 parts by weight based on 100 parts by weight of the total amount of the raw monomers, and a total proportion of the carboxyl group-containing vinyl monomer, the phosphoric acid group-containing vinyl monomer and the copolymerizable vinyl monomer is from 1 to 40 parts by weight based on 100 parts by weight of the total amount of the raw monomers, and a carboxyl group concentration is from 0.05 to 1.50 mmol/g and a phosphoric acid group concentration is from 0.01 to 0.45 mmol/g in the raw monomers: in the general formula (1), R1 represents a hydrogen atom or a methyl group, R2 represents a polyoxyalkylene group represented by the following general formula (2), and X represents a phosphoric acid group or a salt thereof represented by the following general formula (3) in the general formula (2), n represents an integer of 1 to 4, and m represents an integer of 2 or more, and in the general formula (3), M1 and M2 each independently represents a hydrogen atom or a cation. 2. The adhesive composition according to claim 1, wherein with respect to the proportion of the raw monomers, the amount of the alkyl (meth)acrylate ester is from 60 to 99 parts by weight, the amount of carboxyl group-containing vinyl monomer is from 0.5 to 15 parts by weight, the amount of the phosphoric acid group-containing vinyl monomer is from 0.5 to 20 parts by weight, and the proportion of the copolymerizable vinyl monomer is 39 parts by weight or less, based on 100 parts by weight of the total amount of the raw monomers. 3. The adhesive composition according to claim 1, which further contains, as the copolymerizable vinyl monomer, an alkoxysilyl group-containing vinyl monomer, the amount being from 0.001 to 1 parts by weight based on 100 parts by weight of the total amount of the raw monomers. 4. The adhesive composition according to claim 1, which is a water dispersible adhesive composition. 5. An adhesive optical film comprising an optical film, an adhesive layer laminated on at least one surface of the optical film, and an under coat layer interposed between the optical film and the adhesive layer, the adhesive layer being made of an adhesive composition comprising, as raw monomers, an alkyl (meth)acrylate ester whose alkyl group has 4 to 18 carbon atoms, a carboxyl group-containing vinyl monomer, a phosphoric acid group-containing vinyl monomer represented by the following general formula (1), and a copolymerizable vinyl monomer which is optionally copolymerizable with the above monomers, wherein with respect to the proportion of the raw monomers, the amount of the alkyl (meth)acrylate ester is from 60 to 99 parts by weight based on 100 parts by weight of the total amount of the raw monomers, and the total proportion of the carboxyl group-containing vinyl monomer, the phosphoric acid group-containing vinyl monomer and the copolymerizable vinyl monomer is from 1 to 40 parts by weight based on 100 parts by weight of the total amount of the raw monomers, and the carboxyl group concentration is from 0.05 to 1.50 mmol/g and the phosphoric acid group concentration is from 0.01 to 0.45 mmol/g in the raw monomers, the under coat layer has the oxazoline group-containing polymer: in the general formula (1), R1 represents a hydrogen atom or a methyl group, R2 represents a polyoxyalkylene group represented by the following general formula (2), and X represents a phosphoric acid group or a salt thereof represented by the following general formula (3), in the general formula (2), n represents an integer of 1 to 4, and m represents an integer of 2 or more, and in the general formula (3), M1 and M2 each independently represents a hydrogen atom or a cation. 6. The adhesive optical film according to claim 5, wherein, in the adhesive composition, with respect to the proportion of the raw monomers, the amount of the alkyl (meth)acrylate ester is from 60 to 99 parts by weight, the amount of the carboxyl group-containing vinyl monomer is from 0.5 to 15 parts by weight, the amount of the phosphoric acid group-containing vinyl monomer is from 0.5 to 20 parts by weight, and the amount of the copolymerizable vinyl monomer is 39 parts by weight or less, based on 100 parts by weight of the total amount of the raw monomers. 7. The adhesive optical film according to claim 5, wherein the adhesive composition further contains, as the copolymerizable vinyl monomer, an alkoxysilyl group-containing vinyl monomer, the amount being from 0.001 to 1 parts by weight based on 100 parts by weight of the total amount of the raw monomers. 8. The adhesive optical film according to claim 5, wherein the adhesive composition is a water dispersible adhesive composition. 9. The adhesive optical film according to claim 5, wherein the under coat layer is made of a mixture of an oxazoline group-containing polymer and a compound having a plurality of carboxyl groups. 10. The adhesive optical film according to claim 5, wherein the oxazoline group-containing polymer has a principal chain being an acryl skeleton, and has an oxazoline group in a side chain of the principal chain. 11. The adhesive optical film according to claim 9, wherein the compound having a plurality of carboxyl groups has a number average molecular weight of 1000 or more. 12. An adhesive optical film, comprising: an adhesive layer, the adhesive layer being made of an adhesive composition comprising, as raw monomers, an alkyl (meth) acrylate ester whose alkyl group has 4 to 18 carbon atoms, a carboxyl group-containing vinyl monomer, a phosphoric acid group-containing vinyl monomer represented by the following general formula (1), and a copolymerizable vinyl monomer which is optionally copolymerizable with the above monomers, wherein with respect to a proportion of the raw monomers, an amount of the alkyl (meth) acrylate ester is from 60 to 99 parts by weight based on 100 parts by weight of a total amount of the raw monomers, and a total proportion of the carboxyl group-containing vinyl monomer, the phosphoric acid group-containing vinyl monomer and the copolymerizable vinyl monomer is from 1 to 40 parts by weight based on 100 parts by weight of the total amount of the raw monomers, and a carboxyl group concentration is from 0.05 to 1.50 mmol/g and a phosphoric acid group concentration is from 0.01 to 0.45 mmol/g in the raw monomers: in the general formula (1), R1 represents a hydrogen atom or a methyl group, R2 represents a polyoxyalkylene group represented by the following general formula (2), and X represents a phosphoric acid group or a salt thereof represented by the following general formula (3) in the general formula (2), n represents an integer of 1 to 4, and m represents an integer of 2 or more, and in the general formula (3), M1 and M2 each independently represents a hydrogen atom or a cation. 13. An image display device, comprising: at least one adhesive optical film having an adhesive layer, the adhesive layer being made of an adhesive composition comprising, as raw monomers, an alkyl (meth) acrylate ester whose alkyl group has 4 to 18 carbon atoms, a carboxyl group-containing vinyl monomer, a phosphoric acid group-containing vinyl monomer represented by the following general formula (1), and a copolymerizable vinyl monomer which is optionally copolymerizable with the above monomers, wherein with respect to a proportion of the raw monomers, an amount of the alkyl (meth) acrylate ester is from 60 to 99 parts by weight based on 100 parts by weight of a total amount of the raw monomers, and a total proportion of the carboxyl group-containing vinyl monomer, the phosphoric acid group-containing vinyl monomer and the copolymerizable vinyl monomer is from 1 to 40 parts by weight based on 100 parts by weight of the total amount of the raw monomers, and a carboxyl group concentration is from 0.05 to 1.50 mmol/g and a phosphoric acid group concentration is from 0.01 to 0.45 mmol/g in the raw monomers: in the general formula (1), R1 represents a hydrogen atom or a methyl group, R2 represents a polyoxyalkylene group represented by the following general formula (2), and X represents a phosphoric acid group or a salt thereof represented by the following general formula (3) in the general formula (2), n represents an integer of 1 to 4, and m represents an integer of 2 or more, and in the general formula (3), M1 and M2 each independently represents a hydrogen atom or a cation. 14. An image display device comprising: an optical film; an adhesive layer laminated on at least one surface of the optical film; and at least one adhesive optical film having an under coat layer interposed between the optical film and the adhesive layer, the adhesive layer being made of an adhesive composition comprising, as raw monomers, an alkyl (meth) acrylate ester whose alkyl group has 4 to 18 carbon atoms, a carboxyl group-containing vinyl monomer, a phosphoric acid group-containing vinyl monomer represented by the following general formula (1), and a copolymerizable vinyl monomer which is optionally copolymerizable with the above monomers, wherein with respect to a proportion of the raw monomers, an amount of the alkyl (meth) acrylate ester is from 60 to 99 parts by weight based on 100 parts by weight of a total amount of the raw monomers, and a total proportion of the carboxyl group-containing vinyl monomer, the phosphoric acid group-containing vinyl monomer and the copolymerizable vinyl monomer is from 1 to 40 parts by weight based on 100 parts by weight of the total amount of the raw monomers, and a carboxyl group concentration is from 0.05 to 1.50 mmol/g and a phosphoric acid group concentration is from 0.01 to 0.45 mmol/g in the raw monomers: in the general formula (1), R1 represents a hydrogen atom or a methyl group, R2 represents a polyoxyalkylene group represented by the following general formula (2), and X represents a phosphoric acid group or a salt thereof represented by the following general formula (3) in the general formula (2), n represents an integer of 1 to 4, and m represents an integer of 2 or more, and in the general formula (3), M1 and M2 each independently represents a hydrogen atom or a cation.