IPC분류정보
국가/구분 |
United States(US) Patent
등록
|
국제특허분류(IPC7판) |
|
출원번호 |
UP-0705631
(2007-02-14)
|
등록번호 |
US-7771520
(2010-08-30)
|
발명자
/ 주소 |
|
대리인 / 주소 |
|
인용정보 |
피인용 횟수 :
4 인용 특허 :
9 |
초록
▼
A hydrogen separation membrane and its associated method of fabrication. The hydrogen separation membrane has a first material layer that is permeable to atomic hydrogen. The first material has a first catalytic ability to disassociate molecular hydrogen into atomic hydrogen. Complex particles are a
A hydrogen separation membrane and its associated method of fabrication. The hydrogen separation membrane has a first material layer that is permeable to atomic hydrogen. The first material has a first catalytic ability to disassociate molecular hydrogen into atomic hydrogen. Complex particles are applied to the first material layer, either to produce a second layer or to act as a barrier between the first layer and a subsequent layer. The complex particles are hollow bucky structure, filled bucky structures or core particles coated with a hydrogen permeable metal. The complex particles prevent material from opposite sides of the hydrogen separation membrane from interdiffusing over time. Consequently, palladium based materials and Group V based materials can be used on opposite sides of the hydrogen separation membrane. This produces a hydrogen separation membrane that is more permeable to hydrogen in one direction than it is in the opposite direction.
대표청구항
▼
What is claimed is: 1. A separation membrane for separating pure hydrogen gas from a mixed gas at a predetermined operating temperature, said separation membrane comprising: a first layer of a palladium alloy that is permeable to atomic hydrogen at said operating temperature, said first layer havin
What is claimed is: 1. A separation membrane for separating pure hydrogen gas from a mixed gas at a predetermined operating temperature, said separation membrane comprising: a first layer of a palladium alloy that is permeable to atomic hydrogen at said operating temperature, said first layer having a first exposed surface, wherein said first layer has a first catalytic ability to disassociate molecular hydrogen into atomic hydrogen at said first exposed surface; a second layer containing complex particles, wherein said complex particles have both hydrogen impermeable material and hydrogen permeable metal that is permeable to atomic hydrogen at said operating temperature, said hydrogen permeable metal being selected from a group consisting of vanadium, niobium, tantalum, and alloys thereof, said second layer having a second exposed surface, wherein said second layer of material has a second catalytic ability to disassociate molecular hydrogen into atomic hydrogen at said second exposed surface. 2. The membrane according to claim 1, wherein said first catalytic ability to dissociate molecular hydrogen into atomic hydrogen is greater than said second catalytic ability. 3. The membrane according to claim 1, wherein said complex particles contain inert cores that are at least partially coated with said hydrogen permeable metal. 4. The membrane according to claim 1, wherein said complex particles contain carbon bucky structures that are at least partially filled with said hydrogen permeable metal. 5. A separation membrane for separating pure hydrogen gas from a mixed gas at a predetermined operating temperature, said separation membrane comprising: a first layer of a palladium alloy that is permeable to atomic hydrogen at said operating temperature, said first layer having a first exposed surface, wherein said first material has a first catalytic ability to disassociate molecular hydrogen into atomic hydrogen at said first exposed surface; a second layer of a hydrogen permeable metal that is permeable to atomic hydrogen at said operating temperature, said hydrogen permeable metal being selected from a group consisting of vanadium, niobium, tantalum, and alloys thereof, said second layer having a second exposed surface, wherein said second layer is affixed to said first layer along an interface, and wherein said second layer has a second catalytic ability to disassociate molecular hydrogen into atomic hydrogen at said second exposed surface; and complex particles present proximate said interface that inhibit interdiffusion between said palladium alloy and said hydrogen permeable metal over time. 6. The separation membrane according to claim 5, wherein said first catalytic ability to dissociate molecular hydrogen into atomic hydrogen is at least twice as great as said second catalytic ability at said operating temperature. 7. The separation membrane according to claim 5, wherein said complex particles are particles having an inert core coated with said hydrogen permeable metal. 8. The separation membrane according to claim 5, wherein said complex particles are hollow carbon structures that are filled with said hydrogen permeable metal. 9. A method of fabricating a hydrogen separation membrane, comprising the steps of: providing a palladium alloy layer that is permeable to atomic hydrogen, wherein said palladium alloy layer has a first catalytic ability to disassociate molecular hydrogen into atomic hydrogen; applying a complex particle layer to said palladium alloy layer, wherein said complex particle layer has particles containing both hydrogen impermeable material and a hydrogen permeable metal selected from a group consisting of vanadium, niobium, tantalum and alloys thereof, and wherein said complex particle layer is permeable to atomic hydrogen and has a second catalytic ability to disassociate molecular hydrogen into atomic hydrogen; wherein said hydrogen impermeable material in each of said particles inhibits intermigration of said hydrogen permeable layer and said hydrogen permeable metal over time. 10. The method according to claim 9, wherein said hydrogen impermeable material in each of said particles is selected from a group consisting of stainless steel, ceramics, carbon buckytubes and carbon buckyballs. 11. The method according to claim 9, wherein each of said particles includes an inert core coated with said hydrogen permeable metal. 12. The method according to claim 9, wherein said particles include an inert shell filled with said hydrogen permeable metal. 13. The method according to claim 9, wherein said first catalytic ability to disassociate molecular hydrogen is at least twice as great as said second catalytic ability. 14. A method of fabricating a hydrogen separation membrane, comprising the steps of: providing a first material layer that is permeable to atomic hydrogen, wherein said first material has a first catalytic ability to disassociate molecular hydrogen into atomic hydrogen; applying particles to said first material layer, wherein said particles are filled with a hydrogen permeable metal; applying a second material layer over said particles, wherein said second material layer is permeable to atomic hydrogen and has a second catalytic ability to disassociate molecular hydrogen into atomic hydrogen; wherein said particles inhibit intermigration of said first material layer and said second material layer over time. 15. The method according to claim 14, wherein said particles are selected from a group consisting of stainless steel particles, ceramic particles, carbon buckytubes and carbon buckyballs. 16. The method according to claim 14, wherein said particles are coated with a hydrogen permeable metal. 17. The method according to claim 14, wherein said first catalytic ability to disassociate molecular hydrogen is at least twice as great as said second catalytic ability. 18. The method according to claim 14, wherein said second catalytic ability to disassociate molecular hydrogen is at least twice as great as said first catalytic ability. 19. The method according to claim 14, wherein said first material layer and said second material layer are dissimilar layers, containing different hydrogen permeable metals.
※ AI-Helper는 부적절한 답변을 할 수 있습니다.