초록

A process for slurry hydroprocessing, which involves preconditioning a slurry catalyst for activity improvement in vacuum residuum hydroprocessing units Preconditioning the slurry catalyst raises its temperature, thereby reducing shock on the catalyst slurry as it enters the hydroprocessing reactor.

대표청구항 ▼

What is claimed is: 1. A process for the hydroprocessing of heavy oil feedstocks having at least one hydroprocessing reaction stage and employing an active slurry catalyst in oil, wherein the slurry catalyst is preconditioned in a preconditioning unit with hydrogen prior to introducing the catalyst

What is claimed is: 1. A process for the hydroprocessing of heavy oil feedstocks having at least one hydroprocessing reaction stage and employing an active slurry catalyst in oil, wherein the slurry catalyst is preconditioned in a preconditioning unit with hydrogen prior to introducing the catalyst into the hydroprocessing reaction stage to be in contact with heavy oil feedstocks, wherein the slurry catalyst comprises Group VIII and Group VI metal compounds, the slurry catalyst in oil were previously sulfided to create the active catalyst in a light hydrocarbon oil or a vacuum gas oil. 2. The process of claim 1, wherein conditions in the preconditioning unit comprise a temperature in the range from 400° F. to 1000° F. 3. The process of claim 2, wherein the conditions in the preconditioning unit comprise a temperature in the range from 500° to 800° F. 4. The process of claim 3, wherein the conditions in the preconditioning unit comprise a temperature in the range from 600° F. to 700° F. 5. The process of claim 1, wherein conditions in the preconditioning unit comprise a pressure in the range from 100 to 3000 psi. 6. The process of claim 5, wherein conditions in the preconditioning unit comprise a pressure in the range from 300 to 2500 psi. 7. The process of claim 6, wherein conditions in the preconditioning unit comprise a pressure in the range from 500 to 2000 psi. 8. The process of claim 1, wherein the preconditioning unit has a hydrogen flow rate in the preconditioning unit is in the range from 2500 to 7500 scf/bbl. 9. The process of claim 8, wherein the hydrogen flow rate is in the range from 5000 to 6000 scf/bbl. 10. The process of claim 1, wherein the slurry catalyst has a residence time in the preconditioning unit from 1.5 to 3 hours. 11. The process of claim 1, wherein the slurry catalyst is synthesized from Group VIII and Group VI metal compounds, ammonia, hydrogen sulfide, hydrogen, a small amount of water, and a light hydrocarbon or vacuum gas oil, forming a slurry catalyst in oil. 12. A process for the hydroprocessing of heavy oil feedstock having at least one reaction stage and employing an active slurry catalyst in oil, the process comprising: passing compounds comprising Group VIII and Group VIB metals to a catalyst synthesis unit, where they are contacted with ammonia, hydrogen sulfide gas, a hydrocarbon stream which is a light hydrocarbon oil or a vacuum gas oil, hydrogen and a small amount of water to sulfide the catalyst forming an active slurry catalyst in oil, the oil comprising ammonium sulfate; passing the active slurry catalyst in oil to a preconditioning unit wherein the slurry catalyst is preconditioned by being into contact with hydrogen at a rate from 2500 to 7500 scf/bbl; contacting the heavy oil feedstock with a hydrogen stream and the preconditioned slurry catalyst slurry in hydroprocessing unit under hydroprocessing conditions; and recovering from the hydroprocessing unit a product stream, along with a stream comprising spent slurry hydroprocessing catalyst and unconverted hydrocarbon feed. 13. The process of claim 12, further comprising: passing the stream comprising spent slurry hydroprocessing catalyst and unconverted hydrocarbon feed to a deoiling unit, where it is combined with a solvent, products and gases then being recovered, as well as a stream comprising spent slurry catalyst. 14. The process of claim 13, further comprising: passing the stream comprising spent slurry catalyst to a metals recovery unit, where it is contacted with an ammonium leach solution, generating ammonium sulfate and compounds comprising Group VIII and Group VIB metals. 15. The process of claim 14, wherein the Group VIII metal is nickel and the Group VIB metal is molybdenum. 16. The process of claim 12, wherein the slurry catalyst is preconditioned at a temperature in the range from 400° F. to 1000° F. 17. The process of claim 16, wherein the slurry catalyst is preconditioned under a pressure in the range from 100 to 3000 psi. 18. The process of claim 17, wherein the slurry catalyst is preconditioned under a pressure in the range from 300 to 2500 psi. 19. The process of claim 12, wherein the slurry catalyst is preconditioned for a residence time ranging from 1.5 to 3 hours. 20. The process of claim 12, wherein the hydroprocessing conditions are selected from the group consisting of hydrocracking, hydrotreating, hydrodesulfurization, hydrodenitrification, and hydrodemetallization.