초록 ▼

Provided herein are polyamine precursors useful in the manufacture of epoxy resins. Use of a polyamine precursor according to the invention provides an epoxy resin formulation having an increased working time over prior art amines used for curing epoxies. Increased working times translate to the abi

Provided herein are polyamine precursors useful in the manufacture of epoxy resins. Use of a polyamine precursor according to the invention provides an epoxy resin formulation having an increased working time over prior art amines used for curing epoxies. Increased working times translate to the ability to manufacture composites which could not be made using conventional epoxy curing agents, such as composite blades for wind-driven turbines. Such polyamines are also useful in polyurea formulations for lengthening reaction time, thus allowing more flow of applied polyurea coatings prior to gellation.

대표청구항 ▼

What is claimed is: 1. A polyamine composition having the structure: wherein L is an oxyalkoxo group having the structure: —O—R1—O— in which R1 comprises at least one of 2-methyl propylene; 2,2-dimethyl propylene; and mixtures thereof; and wherein R1 may further c

What is claimed is: 1. A polyamine composition having the structure: wherein L is an oxyalkoxo group having the structure: —O—R1—O— in which R1 comprises at least one of 2-methyl propylene; 2,2-dimethyl propylene; and mixtures thereof; and wherein R1 may further comprise a group selected from the group consisting of: C1 to C5 alkylene; —CH2CH2—O—CH2CH2—; —CH2CH2CH2—O—CH2CH2CH2—; including mixtures of two or more of the foregoing polyamines. 2. A process for preparing a cured epoxy (poly-(etheralkanolamine)) resin comprising the steps of: a) providing a polyamine composition according to claim 1; b) providing a polyfunctional epoxy precursor; and c) contacting said polyfunctional epoxy precursor and said polyamine with one another. 3. A process for preparing a polyurea comprising the steps of: a) providing an organic di-isocyanate; b) providing at least one polyamine composition according to claim 1; and c) contacting said organic di-isocyanate and said polyamine with one another. 4. A process for preparing a cured epoxy (poly-(etheralkanolamine)) resin comprising the steps of: a) providing an amine mixture comprising a polyamine composition according to claim 1, and one or more materials selected from the group consisting of: N-amino ethylpiperazine; diethylenetriamine; triethylenetetramine; tetraethylenepentamine; 2-methylpentamethylene;1,3-pentanediamine ; trimethylhexamethylene diamine; a polyamide hardener; a polyamidoamine hardener; a Mannich-base hardener; bis(aminomethyl)cyclohexylamine; isophorone diamine; menthane diamine; bis(p-aminocyclohexyl)methane; 2,2′-dimethyl bis(p-aminocyclohexyl) methane; dimethyldicyclohexylmethane; 1,2-diaminocyclohexane; 1,4-diaminocyclohexane; meta-xylene diamine; norbornanediamine; meta-phenylene diamine; diaminodiphenylsulfone; methylene dianiline; JEFFAMINE® D-230 amine; JEFFAMINE® D-400 amine; JEFFAMINE® T-403 amine; and diethyltoluenediamine; b) providing an polyfunctional epoxy; and c) contacting said polyfunctional epoxy precursor and said polyamine with one another. 5. A process for preparing a polyurea comprising the steps of: a) providing an organic di-isocyanate; b) providing a polyamine according to claim 1 in admixture with at least one material selected from the group consisting of: N-aminoethylpiperazine; diethylenetriamine; triethylenetetramine; tetraethylenepentamine; 2-methylpentamethylene diamine;1,3-pentanediamine; trimethylhexamethylene diamine; polyamide hardeners; polyamidoamine hardeners; Mannich-base hardeners; bis(aminomethyl) cyclohexylamine; isophorone diamine; menthane diamine; bis(p-aminocyclohexyl) methane (“PACM”); 2,2′-dimethyl bis(p-aminocyclohexyl) methane;dimethyldicyclohexylmethane; 1,2-diaminocyclohexane; 1,4-diaminocyclohexane; meta-xylene; norbornanediamine; meta-phenylene diamine; diaminodiphenylsulfone; methylene dianiline; JEFFAMINE® D-230 amine; JEFFAMINE® D-400 amine; JEFFAMINE® T-403 amine; and diethyltoluenediamine; and c) contacting said organic di-isocyanate and said polyamine with one another. 6. The polyamine composition of claim 1, wherein the R1 further comprises at least one of a C1 to C5 alkylene and mixtures thereof. 7. The polyamine composition of claim 1, wherein the R1 further comprises at least one of —CH2CH2—O—CH2CH2—; —CH2CH2CH2—O—CH2CH2CH2—; and mixtures thereof. 8. The polyamine composition of claim 1, wherein the R1 further comprises at least one of the following: including mixtures of two or more of the foregoing polyamines.