Separator-electrode unit for lithium-ion batteries, method for the production and use thereof in lithium batteries
원문보기
IPC분류정보
국가/구분 |
United States(US) Patent
등록
|
국제특허분류(IPC7판) |
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출원번호 |
UP-0846951
(2010-07-30)
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등록번호 |
US-7858222
(2011-02-24)
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우선권정보 |
DE-102 38 943(2002-08-24) |
발명자
/ 주소 |
- Hennige, Volker
- Hying, Christian
- Hoerpel, Gerhard
- Augustin, Sven
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출원인 / 주소 |
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대리인 / 주소 |
Oblon, Spivak, McClelland, Maier & Neustadt, L.L.P.
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인용정보 |
피인용 횟수 :
0 인용 특허 :
10 |
초록
▼
The present invention relates to separator-electrode units for lithium batteries and also to a process for their production. The separator-electrode units comprise a porous electrode which is useful as a positive electrode (cathode) or negative electrode (anode) in a lithium battery and a separator
The present invention relates to separator-electrode units for lithium batteries and also to a process for their production. The separator-electrode units comprise a porous electrode which is useful as a positive electrode (cathode) or negative electrode (anode) in a lithium battery and a separator layer applied to this electrode and are characterized in that the separator-electrode units comprise a purely inorganic separator layer which comprises at least two fractions of metal oxide particles which differ from each other in their average particle size and/or in the metal. More particularly, the separator layer comprises metal oxide particles having an average particle size (Dg) which is greater than the average pore size (d) of the pores of the porous positive electrode that are bonded together by metal oxide particles having a particle size (Dk) which is smaller than the pores of the porous electrode. The separator-electrode unit of the invention has the advantage that it is simple to manufacture as one component and, since the step of laminating the separator onto the electrode can be omitted, that it can comprise a large variation of materials. In addition, a separator-electrode unit according to the invention possesses excellent mechanical stability and a very low separator thickness, which is why it can even be used in lithium high energy batteries.
대표청구항
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What is claimed is: 1. A process for producing a separator-electrode unit comprising an inorganic separator layer which comprises at least two fractions of metal oxide particles which differ from each other in their average particle size and/or in the metal, the separator layer comprising metal oxi
What is claimed is: 1. A process for producing a separator-electrode unit comprising an inorganic separator layer which comprises at least two fractions of metal oxide particles which differ from each other in their average particle size and/or in the metal, the separator layer comprising metal oxide particles having an average particle size (Dg) which is greater than the average pore size (d) of the pores of the porous electrode that are adhered together by metal oxide particles having an average particle size (Dk) which is smaller than the pores of the porous electrode, which process comprises: forming a porous inorganic coating separator layer on a porous electrode substrate capable of functioning as a positive (cathode) or negative (anode) electrode in a lithium battery by applying a suspension which comprises metal oxide particles in a sol and solidifying the inorganic separator layer on the electrode by at least one thermal treatment, the suspension comprising metal oxide particles having an average particle size (Dg) which is greater than the average pore size (d) of the pores of the porous electrode, wherein the separator-electrode unit comprises a porous electrode and a separator layer applied to said porous electrode. 2. A process according to claim 1, wherein the metal oxide particles or the metal oxide particles having an average particle size (Dg) which is greater than the average pore size (d) of the pores of the porous electrode are Al2O3 and/or ZrO2 particles. 3. A process according to claim 1, wherein the metal oxide particles have an average particle size of less than 3 μm. 4. A process according to claim 1, wherein the suspension is applied to the substrate by printing on, pressing on, pressing in, rolling on, knifecoating on, brushing on, dipping, spraying or pouring on. 5. A process according to claim 1, wherein the suspension has a weight ratio of metal oxide particles to sol in the range from 1:1000 to 2:1. 6. A process according to claim 1, wherein the suspension comprises at least one sol of the elements Al, Zr or Si or a mixture of said sols and is produced by suspending the metal oxide particles in at least one of said sols. 7. A process according to claim 6, wherein the sols are particulate sols. 8. A process according to claim 6, wherein the sols are polymeric sols. 9. A process according to claim 6, wherein the sols are obtained by hydrolyzing at least one alkoxide compound of the elements Al, Zr or Si with water or an acid or a combination of said compounds. 10. A process according to claim 1, wherein the suspension further comprises pyrogenic silica to adjust the viscosity of the suspension. 11. A process according to claim 10, wherein the silica mass fraction of the suspension is in the range from 0.1 to 10% by weight. 12. A process according to claim 1, wherein the suspension applied to the electrode is solidified by heating to 50-500° C. 13. A process according to claim 12, wherein the heating is effected at a temperature of from 200 to 280° C. for from 0.5 to 10 minutes. 14. A process according to claim 1, wherein the solidifying of the suspension applied to the electrode is followed by the application to the separator-electrode unit of a layer of shutdown particles which melt at a desired shutdown temperature to create a shutdown mechanism. 15. A process according to claim 14, wherein the layer of shutdown particles is formed by applying a suspension of shutdown particles having an average particle size which is greater than the average pore size of the separator layer in a sol, water, solvent or solvent mixture. 16. A process according to claim 15, wherein the suspension of shutdown particles further comprises an adhesion promoter.
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