A process for producing a separator-electrode assemblies (SEAs) which comprises a porous electrode useful as a positive or negative electrode in a lithium battery and a separator layer applied to this electrode wherein the separator layer being an inorganic separator layer comprising at least two fr
A process for producing a separator-electrode assemblies (SEAs) which comprises a porous electrode useful as a positive or negative electrode in a lithium battery and a separator layer applied to this electrode wherein the separator layer being an inorganic separator layer comprising at least two fractions of metal oxide particles different from each other in their average particle size and/or in the metal, and the electrode having active mass particles that are bonded together and to a current collector by an inorganic adhesive; and the separator-electrode assembly comprises no organic polymer binder. The process comprising form the porous electrode by applying a suspension comprising active mass particles suspended in a sol or a dispersion of nanoscale active mass particles in a solvent and solidifying the suspension.
대표청구항▼
1. A process for producing a separator-electrode assembly comprising a porous electrode useful as a positive (cathode) or negative (anode) electrode in a lithium battery and a separator layer applied to this electrode, wherein the separator-electrode assembly comprising a current collector; a porous
1. A process for producing a separator-electrode assembly comprising a porous electrode useful as a positive (cathode) or negative (anode) electrode in a lithium battery and a separator layer applied to this electrode, wherein the separator-electrode assembly comprising a current collector; a porous electrode on the current collector; and a separator layer applied to the porous electrode; the separator-electrode assembly (SEA) has an inorganic separator layer comprising at least two fractions of metal oxide particles different from each other in their average particle size and/or in the metal, and an electrode whose active mass particles are bonded together and to a current collector by an inorganic, electroconductive adhesive and the separator-electrode assembly comprises no organic polymer binder; wherein the process comprises forming the porous electrode by applying a suspension comprising active mass particles suspended in a sol or a dispersion of nanoscale active mass particles in a solvent and solidifying the suspension to form an all-inorganic porous electrode layer on the current collector by at least one thermal treatment, and forming the porous inorganic coating separator layer on the electrode substrate thus produced by applying a suspension comprising metal oxide particles in a sol and solidifying the inorganic separator layer on the electrode by at least one thermal treatment. 2. The process according to claim 1, wherein the suspension used for producing the porous electrode layer of the positive electrode comprises active mass particles selected from particles comprising at least one of the elements Co, Ni, Mn, V, Fe or P, or the suspension used for producing the porous electrode layer of the negative electrode comprises active mass particles selected from particles comprising at least one of the elements C, Si, Nb, Ti, Mo or W. 3. The process according to claim 1, wherein active mass particles having an average particle size in the range from 0.1 to 20 μm are used. 4. The process according to claim 1, wherein the suspension for producing a positive electrode layer is produced using a sol comprising at least one of the elements Co, Ni, Mn, V, Fe, P or a compound selected from titanium suboxide, titanium nitride, titanium carbide, doped and undoped tin oxide, indium-tin oxide (ITO) and doped or undoped zinc oxide, and the suspension for producing a negative electrode layer is produced using a sol comprising at least one of the elements Nb, Ti, Mo, W or a compound selected from titanium suboxide, titanium nitride, titanium carbide, doped or undoped tin oxide, indium tin-oxide (ITO) and doped or undoped zinc oxide, or the suspension for producing a positive electrode layer is produced using a dispersion of nanoscale particles having an average primary particle size of less than 50 nm comprising at least one of the elements Co, Ni, Mn, V, Fe or P or a compound selected from titanium suboxide, titanium nitride, titanium carbide, doped and undoped tin oxide, indium-tin oxide (ITO) and doped or undoped zinc oxide, and the suspension for producing a negative electrode layer is produced using a dispersion of nanoscale particles having an average primary particle size of less than 50 nm comprising at least one of the elements C, Si, Nb, Ti, Mo or W or a compound selected from titanium suboxide, titanium nitride, titanium carbide, doped and undoped tin oxide, indium-tin oxide (ITO) and doped or undoped zinc oxide, and the suspension is applied to the current collector by printing on, pressing on, pressing in, rolling on, knifecoating on, brushing on, dipping, spraying or pouring on. 5. The process according to claim 1, wherein the electrode layer is produced using a suspension wherein the weight ratio of active mass particle to sol or suspension comprising nanoscale active mass particles is in the range from 1:100 to 2:1. 6. The process according to claim 1, wherein the suspension applied to the current collector is solidified by heating to a temperature in the range from 50 to 700° C. 7. The process according to claim 6, wherein the heating is effected at a temperature of 300 to 500° C. for 0.1 to 10 minutes. 8. The process according to claim 1, wherein the separator layer is produced using a suspension comprising metal oxide particles having an average particle size (Dg) greater or smaller than the average pore size (d) of the pores of the porous electrode, agents being additionally present in the suspension to raise the viscosity of the suspension in particles having an average particle size Dg smaller than the average pore size d of the porous electrode are present, and the suspension for producing the separator layer is applied to the substrate by printing on, pressing on, pressing in, rolling on, knifecoating on, brushing on, dipping, spraying or pouring on. 9. The process according to claim 1, wherein Al2O3 and/or ZrO2 particles are used for producing the suspension as metal oxide particles or as metal oxide particles having an average particle size (Dg) greater or smaller than the average pore size (d) of the pores of the porous positive electrode. 10. The process according to claim 1, wherein the suspension used for producing the separator layer comprises at least one sol of the elements Al, Zr or Si or a mixture thereof and is produced by suspending the metal oxide particles in at least one of these sols. 11. The process according to claim 1, wherein the sols are obtained by hydrolyzing at least one alkoxide compound of the respective elements with water or an acid or a combination thereof. 12. The process according to claim 1, wherein the suspension applied to the electrode is solidified by heating to a temperature in the range from 50-700° C. 13. The process according to claim 12, wherein the heating is effected at a temperature of 300 to 500° C. from 0.1 to 10 minutes. 14. The process according to claim 1, wherein the solidifying of the suspension applied to the electrode is followed by the application to the separator-electrode assembly of a further layer of shutdown particles which melt at a desired shutdown temperature to create a shutdown mechanism. 15. The process according to claim 1, wherein the separator layer comprises metal oxide particles having an average particle size (Dg) greater or smaller than the average pore size (d) of the pores of the porous electrode which are adhered together by metal oxide particles having a particle size (Dk) smaller than the pores of the porous positive or negative electrode, the separator layer forming a layer penetrating less than 20 Dg into the pores when metal oxide particles having an average particle size (Dg) smaller than the average pore size (d) of the pores of the porous electrode are present. 16. The process according to claim 1, wherein the separator layer has a thickness (z) which is less than 100 Dg and not less than 1.5 Dg. 17. The process according to claim 1, wherein the metal oxide particles having an average particle size (Dg) greater or smaller than the average pore size (d) of the pores of the porous positive or negative electrode have an average particle size (Dg) of less than 10 μm. 18. The process according to claim 1, wherein the separator layer has a porosity in the range from 30 to 70%. 19. The process according to claim 1, wherein the electroconducting inorganic adhesive has an average particle size in the range from 1 to 100 nm. 20. The process according to claim 1, wherein the assembly is bendable down to a radius down to 1 cm without damage.
Penth Bernd,DEX ; Hying Christian,DEX ; Duda Mark,DEX ; Hoerpel Gerhard,DEX ; Kuehnle Adolf,DEX, Catalytically active permeable composite material, method for producing said composite material, and use of the same.
Dasgupta Sankar (c/o The Electrofuel Manufacturing Company Ltd. 21 Hanna Avenue Toronto ; Ontario CAX M6K 1W9 ) Jacobs James K. (69 Albany Avenue Toronto ; Ontario CAX), Composite electrode for a lithium battery.
Katusic,Stipan; Michael,Guenther; Kress,Peter; Zimmermann,Guido; Gutsch,Andreas; Varga,Geoffrey J., Doped zinc oxide powder, process for its preparation, and its use.
Alexander Dardin DE; Klaus Hedrich DE; Stephan Massoth DE; Boris Eisenberg DE; Stephan Fengler DE, Engine oil composition with reduced deposit-formation tendency.
Hying, Christian; Horpel, Gerhard; Penth, Bernd, Ion-conducting composite which is permeable to matter, method for producing said composite, and use of the same.
Penth Bernd,DEX ; Hoerpel Gerhard,DEX ; Hying Christian,DEX, Method for separating mixtures of substances using a material pervious to said substances.
Penth Bernd,DEX ; Hying Christian,DEX ; Hoerpel Gerhard,DEX ; Schmidt Friedrich Georg,DEX, Permeable composite material, method for producing said composite material, and use of the same.
Penth, Bernd; Hying, Christian; Hoerpel, Gerhard; Schmidt, Friedrich Georg, Permeable composite material, method for producing said composite material, and use of the same.
Auer,Emmanuel; Biberbach,Peter; Gross,Michael; Gutsch,Andreas; Prid철hl,Markus; Ruth,Karsten; Staab,Edwin, Process and apparatus for the thermal treatment of pulverulent substances.
Sano, Atsushi; Otsuki, Keitaro; Miyaki, Yosuke; Takahashi, Takeshi; Inoue, Tohru; Higuchi, Akiji, Active material and method of manufacturing active material.
Sano, Atsushi; Otsuki, Keitaro; Miyaki, Yosuke; Takahashi, Takeshi; Higuchi, Akiji, Active material and positive electrode and lithium-ion second battery using same.
Sano, Atsushi; Otsuki, Keitaro; Miyaki, Yosuke; Takahashi, Takeshi; Higuchi, Akiji, Active material and positive electrode and lithium-ion second battery using same.
※ AI-Helper는 부적절한 답변을 할 수 있습니다.