The invention relates to a composition which is self-adhesive to the hard tooth tissue, comprising: (A) 5 to 75 percent by weight of one or more mono or higher functional ethylenically unsaturated compounds which additionally have an acid functional group, wherein one of said compounds has a P—OH gr
The invention relates to a composition which is self-adhesive to the hard tooth tissue, comprising: (A) 5 to 75 percent by weight of one or more mono or higher functional ethylenically unsaturated compounds which additionally have an acid functional group, wherein one of said compounds has a P—OH group, for instance a phosphoric, phosphonic or phosphinic acid group; (B) 2 to 50 percent by weight of one or more mono or higher functional ethylenically unsaturated compounds without any acid functional group; (C) 22.8 to 85 percent by weight of filling material(s), comprising at least one filling material that may react with component (A) in the sense of causing a ion exchange, neutralization, salt formation and/or chelate formation reaction; (D) 0.1 to 8 percent by weight of one or more initiators and optionally activators; (E) 0.1 to 20 percent by weight of further additives, for example, modifiers, wherein the weight ration in % of component (A) relative to component (B) ranges from 21 to 90: 10 to 79.
대표청구항▼
1. A self-adhesive dental material comprising: (A) from 5 to 75% by weight of one or more mono- or polyfunctional ethylenically unsaturated compounds which additionally possess at least one acid-functional group, at least one of the compounds containing at least one P—OH group,(B) from 2 to 50% by w
1. A self-adhesive dental material comprising: (A) from 5 to 75% by weight of one or more mono- or polyfunctional ethylenically unsaturated compounds which additionally possess at least one acid-functional group, at least one of the compounds containing at least one P—OH group,(B) from 2 to 50% by weight of one or more mono- or polyfunctional ethylenically unsaturated compounds without an acid-functional group,(C) from 22.8 to 85% by weight of filler(s), including at least one filler capable of reacting with component (A) in an ion exchange, neutralization, acid-forming and/or chelate-forming reaction,(D) from 0.1 to 8% by weight of one or more initiators and, if desired, activators,(E) from 0.1 to 20% by weight of additional additives and/or modifiers, the weight ratio in % of component (A) to component (B) being in the range from 21 to 90:10 to 79, andwith the proviso that the self-adhesive dental composition does not comprise added water. 2. The self-adhesive dental material of claim 1, wherein the monomer in component (A) having at least one P—OH group is present in a concentration of at least 5% by weight based on the constituents (A) to (E). 3. The self-adhesive dental material of claim 1, wherein the polymerizable groups of component (A) comprise acrylic, methacrylic, vinyl and/or styryl groups and the acid groups are selected from the group consisting of carboxylic acid residues, acid residues of phosphorus, sulfur, boron, and combinations thereof. 4. The self-adhesive dental material of claim 1, wherein the polymerizable groups of component (B) comprise acrylic, methacrylic, vinyl and/or styryl groups. 5. The self-adhesive dental material of claim 1, wherein component (C) comprises fillers which are inert toward the acid functions of component (A). 6. The self-adhesive dental material of claim 1, wherein component (D) is selected from photoinitiators and/or redox initiator systems. 7. The self-adhesive dental material of claim 1, wherein component (E) is selected from the group consisting of plasticizers, organic pigments, inorganic pigments, dyes, stabilizers, heavy metal scavengers, thixotropic assistants, ion donor substances, bactericidal substances, and antibiotic substances. 8. The self-adhesive dental material of claim 1, wherein the self-adhesive dental material is a filling material, fissure sealant, cement or core buildup material. 9. A method of producing a self-adhesive dental material comprising a) preparing hard dental tissue, b) directly applying the self-adhesive dental material of claim 1 into the preparation, and c) curing the self-adhesive dental material, in which no pretreatment steps are carried out before step b). 10. The self-adhesive dental composition of claim 1 wherein component (C) is present in an amount of from 40 to 85% by weight. 11. The self-adhesive dental material of claim 1 wherein the dental material has a water absorbency of less than 50 μg/mm3. 12. The self-adhesive dental material of claim 11 wherein the dental material has a water absorbency of less than 40 μg/mm3. 13. The self-adhesive dental material of claim 12 wherein the dental material has a water absorbency of less than 30 μg/mm3. 14. The self-adhesive dental material of claim 1 wherein the dental material has a flexural strength of greater than 30 MPa. 15. The self-adhesive dental material of claim 14 wherein the dental material has a flexural strength of greater than 40 MPa. 16. The self-adhesive dental material of claim 1 wherein the one or more mono- or polyfunctional ethylenically unsaturated compounds which additionally possess at least one acid-functional group are compounds selected from the group consisting of 4-(meth)acryloyl-oxyethyltrimellitic acid, butenetricarboxylic acid, bis-4,6-and/or bis-2,5-(meth)acryloyloxyethyltrimellitic acid, phosphoric esters of hydroxyethyl (meth)acryl ate (HEMA), glyceryl di(meth)acrylate and/or pentaerythrityl tri(meth)acrylate, chloro- and/or bromo-phosphoric esters of bisphenol A glycidyl (meth)acrylate. 17. The self-adhesive dental material of claim 1 wherein the one or more mono- or polyfunctional ethylenically unsaturated compounds which additionally possess at least one acid-functional group are oligomers and/or polymers of compounds selected from the group consisting of 4-(meth)acryloyl-oxyethyltrimellitic acid, butenetricarboxylic acid, bis-4,6- and/or bis-2,5-(meth)acryloyloxyethyltrimellitic acid, phosphoric esters of hydroxyethyl (meth)acrylate (HEMA), glyceryl di(meth)acrylate and/or pentaerythrityl tri(meth)acrylate, chloro- and/or bromo-phosphoric esters of bisphenol A glycidyl (meth)acrylate. 18. The self-adhesive dental material of claim 1 wherein the one or more mono- or polyfunctional ethylenically unsaturated compounds without an acid-functional group are acrylic and/or methacrylic esters of mono-, di- and/or higher polyfunctional alcohols. 19. The self-adhesive dental material of claim 18 wherein the acrylic and/or methacrylic esters are selected from the group consisting of methyl (meth)acrylate, butyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, lauryl (meth)acrylate, 2-hydroxyethyl (meth)acrylate, 2 hydroxypropyl (meth)acrylate, glyceryl 1,3-di(meth)acrylate (GDMA), glyceryl 1,2-di(meth)acrylate, cyclohexyl (meth)acrylate, phenyl (meth)acrylate, isobornyl (meth)acrylate, ethylene glycol di(meth)acrylate, 1,4-butanediol di(meth)acrylate, triethylene glycol di(meth)acrylate (TEGDMA), 1,6-hexanediol di(meth)acrylate, 1,12 dodecanediol di(meth)acrylate, trimethylolpropane tri(meth)acrylate, pentaerythrityl tetra(meth)acrylate, and dipentaerythrityl hexa(meth)acrylate. 20. The self-adhesive dental material of claim 1 wherein the one or more mono- or polyfunctional ethylenically unsaturated compounds without an acid-functional group are urethane (meth)acrylates. 21. The self-adhesive dental material of claim 20 wherein the urethane (meth)acrylate is 7,7,9 trimethyl-4,13-dioxo-5,12-diazahexadecane-1,16-dioxydi(meth)acrylate. 22. The self-adhesive dental material of claim 20 wherein the urethane (meth)acrylate has a molecular weight in the range from 70 to 5000 g/mol. 23. The self-adhesive dental material of claim 22 wherein the urethane (meth)acrylate has a molecular weight in the range from 90 to 2500 g/mol. 24. The self-adhesive dental material of claim 23 wherein the urethane (meth)acrylate has a molecular weight in the range from 100 to 1000 g/mol. 25. The self-adhesive dental material of claim 1 wherein the one or more initiators are organic peroxide compounds selected from the group consisting of lauroyl peroxide, benzoyl peroxide, p-chlorobenzoyl peroxide, and p-methylbenzoyl peroxide. 26. The self-adhesive dental material of claim 1 wherein component (D) comprises an activator selected from the group consisting of N,N-bis(hydroxyalkyl) -3,5-xylidines, N,N-bis(hydroxyalkyl)-3,5-di-t-butylanilines, N,N-bis(hydroxyalkyl) -3,4,5-trimethylaniline, sodium benzenesulfinate, sodium para-toluenesulfinate, barbituric acids, and malonylsulfamides. 27. The self-adhesive dental material of claim 26 wherein the malonylsulfamides are selected from the group consisting of 2,6-dimethyl-4-isobutylmalonylsulfamide, 2,6-diisobutyl-4-propylmalonylsulfamide, 2,6-dibutyl-4-propylmalonylsulfamide, 2,6 dimethyl-4-ethylmalonylsulfamide, and 2,6-dioctyl-4-isobutylmalonylsulfamide. 28. The self-adhesive dental material of claim 1 further comprising a heavy metal compound. 29. The self-adhesive dental material of claim 28 wherein the heavy metal compound is a soluble organic compound. 30. The self-adhesive dental material of claim 28 wherein the heavy metal compound comprises a metal selected from the group consisting of Ce, Fe, Cu, Mn, Co, Sn, and Zn. 31. The self-adhesive dental material of claim 1 wherein the additional additives and/or modifiers comprise bactericidal or antibiotic substances. 32. The self-adhesive dental material of claim 31 wherein the bactericidal or antibiotic substances are selected from the group consisting of chlorhexidine, pyridinium salts, β-lactam antibiotics, cephalosporins, tetracyclines, chloramphenicol, fosfomycin, antibacterial macrolides, and polypeptide antibiotics. 33. The self-adhesive dental composition of claim 7 wherein the composition consists essentially of components (A), (B), (C), (D), and (E). 34. The self-adhesive dental composition of claim 33 wherein the composition consists of components (A), (B), (C), (D), and (E). 35. A self-adhesive dental material comprising: (A) from 5 to 75% by weight of one or more mono- or polyfunctional ethylenically unsaturated compounds which additionally possess at least one acid-functional group, at least one of the compounds containing at least one P—OH group,(B) from 2 to 50% by weight of one or more mono- or polyfunctional ethylenically unsaturated compounds without an acid-functional group,(C) from 22.8 to 85% by weight of filler(s), including at least one filler capable of reacting with component (A) in an ion exchange, neutralization, acid-forming and/or chelate-forming reaction,(D) from 0.1 to 8% by weight of one or more initiators and, if desired, activators,wherein the one or more initiators comprise a redox initiator system comprising: a barbituric acid, a thiobarbituric acid, or a combination thereof;a peroxodisulfate compound, a peroxodiphosphate compound, or a combination thereof;a sulfinic acid compound; anda copper compound, and(E) from 0.1 to 20% by weight of additional additives and/or modifiers, the weight ratio in % of component (A) to component (B) being in the range from 21 to 90:10 to 79. 36. A self-adhesive dental material comprising: (A) from 5 to 75% by weight of one or more mono- or polyfunctional ethylenically unsaturated compounds which additionally possess at least one acid-functional group, at least one of the compounds containing at least one P—OH group,(B) from 2 to 50% by weight of one or more mono- or polyfunctional ethylenically unsaturated compounds without an acid-functional group,(C) from 22.8 to 85% by weight of filler(s), including at least one basic glass powder having a high fraction of divalent and trivalent ions,(D) from 0.1 to 8% by weight of one or more initiators and, if desired, activators, and(E) from 0.1 to 20% by weight of additional additives and/or modifiers, the weight ratio in % of component (A) to component (B) being in the range from 21 to 90:10 to 79, andwith the proviso that the self-adhesive dental composition does not comprise added water. 37. The self-adhesive dental material of claim 36 wherein the at least one basic glass powder having a high fraction of divalent and trivalent ions is selected from the group consisting of a borate glass, a phosphate glass, and a fluoroaluminosilicate glass. 38. The self-adhesive dental material of claim 37 wherein the at least one basic glass powder having a high fraction of divalent and trivalent ions is a fluoroaluminosilicate glass. 39. A method of treating a hard tooth substance, the method comprising: mixing together components (A), (B), (C), (D), and (E) of a self-adhesive dental material according to claim 1;applying the mixed self-adhesive dental material to the hard tooth substance; andcuring the applied self-adhesive dental material. 40. The method of claim 39 wherein applying comprises applying the mixed self-adhesive dental material to the hard tooth substance without pretreatment of the hard tooth substance. 41. The method of claim 40 wherein the cured self-adhesive dental material has an adhesion to the hard tooth substance of at least 2 MPa. 42. The method of claim 41 wherein the hard tooth substance comprises enamel. 43. The method of claim 41 wherein the hard tooth substance comprises dentine.
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