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A dental restorative composition comprises: (A) polymerizable monomer(s) selected from hydroxyethyl (meth)acrylate phosphate, hydroxypropyl (meth)acrylate phosphate, hydroxybutyl (meth)acrylate phosphate, dipentaerythritol penta(meth)acrylate phosphate, pentaerythritol tri(meth)acrylate phosphate, p

A dental restorative composition comprises: (A) polymerizable monomer(s) selected from hydroxyethyl (meth)acrylate phosphate, hydroxypropyl (meth)acrylate phosphate, hydroxybutyl (meth)acrylate phosphate, dipentaerythritol penta(meth)acrylate phosphate, pentaerythritol tri(meth)acrylate phosphate, phenyl (meth)acryloxyethyl phosphate, and a combination thereof; (B) polymerizable monomer(s) having a molecular weight of 100-250, at least one hydroxyl group, and at least one ethylenically unsaturated group; (C) polymerizable monomer(s) having a molecular weight of 270-900, at least two ethylenically unsaturated groups and no acidic functional group; (D) photo-initiator(s); and (E) filler(s) each having a mean particle size of more than 0.005 microns and less than 70 microns. The weight ratio of (A+B):(C) ranges from 30:70 to 90:10, and the composition has a shear bond strength of at least 10MPa to both dentin and enamel after being light-cured.

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1. A single-part, light-curable, self-adhering dental restorative composition consisting essentially of: (A) one or more first polymerizable monomers consisting of (A1) a first phosphate selected from the group consisting of hydroxyethyl (meth)acrylate phosphate, hydroxypropyl (meth)acrylate phospha

1. A single-part, light-curable, self-adhering dental restorative composition consisting essentially of: (A) one or more first polymerizable monomers consisting of (A1) a first phosphate selected from the group consisting of hydroxyethyl (meth)acrylate phosphate, hydroxypropyl (meth)acrylate phosphate, hydroxybutyl (meth)acrylate phosphate, dipentaerythritol penta(meth)acrylate phosphate, pentaerythritol tri(meth)acrylate phosphate, phenyl (meth)acryloxyethyl phosphate, and a combination thereof, and optionally (A2) a second phosphate selected from the group consisting of glyceryldi(meth)acrylate phosphate, bis {hydroxyethyl (meth)acrylate} phosphate, and a combination thereof;(B) one or more second polymerizable monomers having a molecular weight of 100-250, at least one hydroxyl group, and at least one ethylenically unsaturated group;(C) one or more third polymerizable monomers having a molecular weight of 270-900, at least two ethylenically unsaturated groups and no acidic functional group;(D) a photo-initiator system having at least one photo-initiator;(E) one or more fillers each having a mean particle size of more than 0.005 microns and less than 70 microns;(F) optionally one or more ingredients selected from the group consisting of: a colorant, a stabilizer, a UV absorber, a solvent, a fluoride-releasing compound, an antimicrobial additive, and a surfactant;wherein the weight ratio of (A+B) : (C) ranges from 30:70 to 90:10; andthe composition has a shear bond strength of at least 10MPa to both dentin and enamel after being light-cured. 2. The self-adhering dental restorative composition of claim 1 wherein the weight ratio of (A+B) : (C) ranges from 45:55 to 75:25. 3. The self-adhering dental restorative composition of claim 1 wherein the concentration of component (A) in the restorative composition, excluding fillers, is in the range of 15-40% by weight, and the concentration of component (B) in the restorative composition, excluding fillers, is in the range of 20-50% by weight. 4. The self-adhering dental restorative composition of claim 1 wherein the ethylenically unsaturated groups in (B) and (C) are each selected from the group consisting of acrylate, methacrylate, acrylamide, methacrylamide, and vinyl groups, or any combination thereof. 5. The self-adhering dental restorative composition of claim 1 wherein the one or more first polymerizable monomers (A) includes at least one second phosphate (A2). 6. The self-adhering dental restorative composition of claim 5 wherein the concentration of component (A) in the restorative composition, excluding fillers, is in the range of 10-50% by weight, and the concentration of component (B) in the restorative composition, excluding fillers, is in the range of 15-60% by weight. 7. The self-adhering dental restorative composition of claim 1 wherein the one or more fillers are non-reactive towards the one or more first polymerizable monomers. 8. The self-adhering dental restorative composition of claim 1 wherein component (E) comprises: (E1) one or more first fillers having a mean particle size of more than 4.5 microns and less than 70 microns; (E2) one or more second fillers having a mean particle size of more than 0.25microns, but no more than 4.5 microns; and (E3) one or more third fillers having a mean particle size of 0.005-0.25 microns. 9. The self-adhering dental restorative composition of claim 8 wherein the one or more first fillers (E1) have a mean particle size of more than 10 microns. 10. The self-adhering dental restorative composition of claim 8 wherein the one or more first fillers (E1) are a polymeric filler comprising 5-100% by weight of a polymeric matrix and 0-95% by weight of at least one inorganic filler. 11. The self-adhering dental restorative composition of claim 10 wherein the polymeric filler comprises 10-50% by weight of the polymeric matrix and 50-90% by weight of the at least one inorganic filler. 12. The self-adhering dental restorative composition of claim 11 wherein the polymeric matrix comprises crosslinked (meth)acrylate(s), and wherein the mean particle size of the inorganic filler(s) is in the range of 0.005-20 microns. 13. The self-adhering dental restorative composition of claim 12 wherein the mean particle size of the inorganic filler(s) is in the range of 0.01-4.5 microns. 14. The self-adhering dental restorative composition of claim 8 wherein the one or more second fillers (E2) have a mean particle size of 0.3-2.0 microns. 15. The self-adhering dental restorative composition of claim 1 wherein the total concentration of the one or more fillers in the restorative composition is in the range from 40-95% by weight. 16. The self-adhering dental restorative composition of claim 1 wherein the shear bond strength is at least 12 MPa to both dentin and enamel. 17. A method of using the self-adhering dental restorative composition of claim 1 comprises: (i) applying the self-adhering dental restorative composition to tooth structure without first treating the tooth structure with an etchant, a primer and/or an adhesive; and(ii) subsequently hardening the composition by light-curing the composition. 18. A dental restorative kit comprising the self-adhering dental restorative composition of claim 1 and an instruction of how to use the composition, wherein the instruction teaches to restore a dental cavity by first applying the single-part, light-curable, self-adhering dental restorative composition directly to the dental cavity without first treating the dental cavity with an etchant, a primer and/or an adhesive. 19. A single-part, light-curable, self-adhering dental restorative composition consisting essentially of: (A) one or more first polymerizable monomers consisting of (A1) a first phosphate selected from the group consisting of hydroxyethyl (meth)acrylate phosphate, hydroxypropyl (meth)acrylate phosphate, hydroxybutyl (meth)acrylate phosphate, dipentaerythritol penta(meth)acrylate phosphate, pentaerythritol tri(meth)acrylate phosphate, phenyl (meth)acryloxyethyl phosphate, and a combination thereof, and optionally (A2) a second phosphate selected from the group consisting of glyceryldi(meth)acrylate phosphate, bis {hydroxyethyl (meth)acrylate} phosphate, and a combination thereof;(B) one or more second polymerizable monomers having a molecular weight of 100-250, at least one hydroxyl group, and at least one ethylenically unsaturated group;(C) one or more third polymerizable monomers having a molecular weight of 270-900, at least two ethylenically unsaturated groups and no acidic functional group;(D) a photo-initiator system having at least one photo-initiator;(E1) one or more first fillers that are a polymeric filler having a mean particle size of more than 4.5 microns and less than 70 microns comprising 5-100% by weight of a crosslinked polymeric matrix and 0-95% by weight of at least one inorganic filler having a mean particle size in the range of 0.005-20 microns;(E2) one or more second fillers having a mean particle size of more than 0.25microns, but no more than 4.5 microns; and(E3) one or more third fillers having a mean particle size of 0.005-0.25microns;(F) optionally one or more ingredients selected from the group consisting of: a colorant, a stabilizer, a UV absorber, a solvent, a fluoride-releasing compound, an antimicrobial additive, and a surfactant;wherein the weight ratio of (A+B) : (C) ranges from 30:70 to 90:10;the concentration of component (A) in the restorative composition, excluding fillers, is in the range of 10-50% by weight;the concentration of component (B) in the restorative composition, excluding fillers, is in the range of 15-60% by weight; andthe composition has a shear bond strength of at least 10MPa to both dentin and enamel after being light-cured. 20. The self-adhering dental restorative composition of claim 19 wherein: (E1) the polymeric filler has a mean particle size of more than 10 microns and less than 60 microns comprising 10-30% by weight of a crosslinked poly(meth)acrylate polymeric matrix and 70-90% by weight of at least one inorganic filler having a mean particle size in the range of 0.01-4.5microns;the weight ratio of (A+B) : (C) ranges from 30:70 to 80:20; andthe concentration of component (A) in the restorative composition, excluding fillers, is in the range of 10-45% by weight. 21. The self-adhering dental restorative composition of claim 20 wherein: (E1) the at least one inorganic filler has a mean particle size in the range of 0.01-2.0microns;(E2) the one or more second fillers have a mean particle size of more than 0.25microns, but no more than 2.0 microns; and(E3) the one or more third fillers have a mean particle size of 0.01-0.25microns. 22. The single-part, light-curable, self-adhering dental restorative composition of claim 19 wherein the one or more first polymerizable monomers (A) includes at least one second phosphate (A2). 23. A method of using the self-adhering dental restorative composition of claim 19 comprises: (i) applying the self-adhering dental restorative composition to tooth structure without first treating the tooth structure with an etchant, a primer and/or an adhesive; and(ii) subsequently hardening the composition by light-curing the composition.