IPC분류정보
국가/구분 |
United States(US) Patent
등록
|
국제특허분류(IPC7판) |
|
출원번호 |
US-0743204
(2008-11-20)
|
등록번호 |
US-8198372
(2012-06-12)
|
우선권정보 |
EP-07425740 (2007-11-22) |
국제출원번호 |
PCT/EP2008/065922
(2008-11-20)
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§371/§102 date |
20100722
(20100722)
|
국제공개번호 |
WO2009/065895
(2009-05-28)
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발명자
/ 주소 |
- Comino, Giovanni
- Manzoni, Claudia
- Stanga, Milena
- Albano, Margherita
|
출원인 / 주소 |
|
대리인 / 주소 |
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인용정보 |
피인용 횟수 :
0 인용 특허 :
16 |
초록
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Vulcanizable fluoroelastomer compositions comprising: A) a fluoroelastomer matrix based on vinylidene fluoride (VDF) with a Mooney viscosity (1+10) at 121° C. of less than 35 MU (Mooney Units) measured according to ASTM standard D 1646; andB) a semi-crystalline fluoropolymer, in an amount of from 20
Vulcanizable fluoroelastomer compositions comprising: A) a fluoroelastomer matrix based on vinylidene fluoride (VDF) with a Mooney viscosity (1+10) at 121° C. of less than 35 MU (Mooney Units) measured according to ASTM standard D 1646; andB) a semi-crystalline fluoropolymer, in an amount of from 20% to 70% by weight relative to the total weight of A)+B), the semi-crystalline fluoropolymer being constituted of tetrafluoroethylene (TFE) homopolymers and copolymers of TFE with one or more monomers containing at least one unsaturation of ethylenic type, in an amount of from 0.01 to 10 mol %, said semi-crystalline fluoropolymer having a mean particle size between 10 and 400 nm.
대표청구항
▼
1. Vulcanizable fluoroelastomer compositions comprising: A) a fluoroelastomer matrix based on vinylidene fluoride (VDF) with a Mooney viscosity (1+10) at 121° C. of less than 35 MU (Mooney Units) measured according to ASTM standard D 1646;B) a semi-crystalline fluoropolymer, in an amount of from 20%
1. Vulcanizable fluoroelastomer compositions comprising: A) a fluoroelastomer matrix based on vinylidene fluoride (VDF) with a Mooney viscosity (1+10) at 121° C. of less than 35 MU (Mooney Units) measured according to ASTM standard D 1646;B) a semi-crystalline fluoropolymer, in an amount of from 20% to 70% by weight relative to the total weight of A)+B), the semi-crystalline fluoropolymer being chosen from tetrafluoroethylene (TFE) homopolymers and copolymers of TFE with one or more monomers containing at least one unsaturation of ethylenic type, in an amount of from 0.01 to 10 mol %, said semi-crystalline fluoropolymer having a mean particle size between 10 and 400 nm. 2. Vulcanizable fluoroelastomer compositions according to claim 1, in which the fluoroelastomers of the fluoroelastomer matrix A) are copolymers in which VDF is copolymerized with at least one comonomer selected from the group consisting of: C2-C8 perfluoroolefins;C2-C8 chloro- and/or bromo- and/or iodo-fluoroolefins;(per)fluoroalkyl vinyl ethers (PAVE) CF2 ═CFORf, in which Rf is a C1-C6 (per)fluoroalkyl;(per)fluorooxyalkyl vinyl ethers CF2 ═CFOX, in which X is: a C1-C12 ((per)fluoro)oxyalkyl containing one or more ether groups;(per)fluorodioxoles of formula: in which each of the groups Rf3, Rf4, Rf5 and Rf6, which are identical to or different from each other, is independently a fluorine atom or a C1-C6 perfluoroalkyl group optionally comprising one or more oxygen atoms;(per)fluoromethoxyvinyl ethers (hereinbelow: MOVE) having the general formula: CFX2═CX2OCF2OR″f (I-Ba) in which R″f is selected from the group consisting of linear or branched C1-C6 (per)fluoroalkyls; cyclic C5-C6 (per)fluoroalkyls; and linear or branched C2-C6 (per)fluorooxyalkyls, containing from one to three oxygen atoms, and X2 =F or H;non-fluorinated C2-C8 olefins (Ol). 3. Vulcanizable fluoroelastomer compositions according to claim 1, in which the fluoroelastomers A) have the following composition selected from the group consisting of compositions (a), (b), (c), (d) and (e), 100% being the sum of the molar percentages of the monomers: (a) vinylidene fluoride (VDF) 35-85%, hexafluoropropylene (HFP) 10-45%, tetrafluoroethylene (TFE) 0-30%, perfluoroalkyl vinyl ether (PAVE) 0-15%,(b) vinylidene fluoride (VDF) 50-80%, perfluoroalkyl vinyl ether (PAVE) 5-50%, tetrafluoroethylene (TFE) 0-30%;(c) vinylidene fluoride (VDF) 20-30%, non-fluorinated C2-C8 olefins (Ol) 10-30%, hexafluoropropylene (HFP) and/or perfluoroalkyl vinyl ether (PAVE) 18-27%, tetrafluoroethylene (TFE) 10-30%,(d) tetrafluoroethylene (TFE) 33-75%, perfluoroalkyl vinyl ether (PAVE) 15-45%, vinylidene fluoride (VDF) 5-30%, hexafluoropropylene (HFP) 0-30%, and(e) vinylidene fluoride (VDF) 35-85%, (per)fluoromethoxyvinyl ether (MOVE) 5-40%, perfluoroalkyl vinyl ether (PAVE) 0-30%, tetrafluoroethylene (TFE) 0-40%, hexafluoropropylene (HFP) 0-30%. 4. Vulcanizable fluoroelastomer compositions according to claim 1, in which the fluoroelastomer matrix also comprises monomer units derived from a bis-olefin having the general formula: in which: R1, R2, R3, R4, R5 and R6, which are identical to or different from each other, are H or C1-C5 alkyls;Z is a linear or branched C1-C18 alkylene or cycloalkylene radical optionally containing oxygen atoms, or a (per)fluoropolyoxyalkylene radical. 5. Vulcanizable fluoroelastomer compositions according to claim 4, in which the amount of bis-olefin-based units is between 0.01 mol % and 1.0 mol % per 100 mol of the other monomer units constituting the base structure of the fluoroelastomer. 6. Vulcanizable fluoroelastomer compositions according to claim 1, in which the ethylenically unsaturated comonomers are of hydrogenated or fluorinated type. 7. Vulcanizable fluoroelastomer compositions according to claim 6, in which the hydrogenated comonomers are selected from the group consisting of: ethylene, propylene, acrylic monomers, and styrene monomers. 8. Vulcanizable fluoroelastomer compositions according to claim 6, in which the fluorinated comonomers are selected from the group consisting of: C2-C8 perfluoroolefins;C2-C8 chloro- and/or bromo- and/or iodo-fluoroolefins;(per)fluoroalkyl vinyl ethers (hereinbelow: PAVE) CF2═CFORf, in which Rf is a C1-C6 (per)fluoroalkyl;(per)fluorooxyalkyl vinyl ethers CF2═CFOX, in which X is: a C1-C12 ((per)fluoro)oxyalkyl containing one or more ether groups;(per)fluorodioxoles of formula: in which each of the groups Rf3, Rf4, Rf5 and Rf6, which are identical to or different from each other, is independently a fluorine atom or a C1-C6 perfluoroalkyl group optionally comprising one or more oxygen atoms;(per)fluoromethoxyvinyl ethers (hereinbelow: MOVE) having the general formula: CFX2═CX2OCF2OR″f (I-Ba) in which R″f is chosen from linear or branched C1-C6 (per)fluoroalkyls; cyclic C5-C6 (per)fluoroalkyls; and linear or branched C2-C6 (per)fluorooxyalkyls, containing from one to three oxygen atoms, and X2=F or H;non-fluorinated C2-C8 olefins (Ol); andhydrogenated C2-C8 fluoroolefins and perfluoroalkylethylenes CH2═CH—Rf, in which Rf is a C1-C6 perfluoroalkyl. 9. Vulcanizable fluoroelastomer compositions according to claim 1, in which the semi-crystalline (per)fluoropolymer is covered with a shell of a semi-crystalline (per)fluoropolymer containing bromine and/or iodine atoms in the chain, derived from brominated and/or iodinated comonomers, in an amount of from 0.1 mol % to 10 mol % relative to the total number of moles of base monomer units in the core+shell semi-crystalline (per)fluoropolymer. 10. Vulcanizable fluoroelastomer compositions according to claim 1, comprising vulcanization coagents and vulcanization compound ingredients. 11. A method for producing extruded articles comprising extruding the vulcanizable fluoroelastomer compositions of claim 1. 12. Vulcanized products obtained by vulcanization of the compositions according to claim 1.
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