초록 ▼

Methods and systems for the production of linear alkylbenzenes are described herein. The methods and systems incorporate the novel use of a high shear device to promote dispersion and mixing of one or more olefins (e.g. propylene) with an aromatic. The high shear device may allow for lower reaction

Methods and systems for the production of linear alkylbenzenes are described herein. The methods and systems incorporate the novel use of a high shear device to promote dispersion and mixing of one or more olefins (e.g. propylene) with an aromatic. The high shear device may allow for lower reaction temperatures and pressures and may also reduce reaction time with existing catalysts.

대표청구항 ▼

1. A method of producing a linear alkylbenzene, the method comprising: a) introducing one or more olefins into an aromatic stream to form a reactant stream; andb) subjecting said reactant stream to a shear rate of greater than about 20,000s−1 and to a high shear mixing at a tip speed of at least abo

1. A method of producing a linear alkylbenzene, the method comprising: a) introducing one or more olefins into an aromatic stream to form a reactant stream; andb) subjecting said reactant stream to a shear rate of greater than about 20,000s−1 and to a high shear mixing at a tip speed of at least about 23 m/s in a high shear device to form gas bubbles having a mean diameter of less than 100 nm to produce a high shear product stream, wherein the high shear device comprises at least one generator comprising a rotor and a complementarily-shaped stator; andc) separating linear alkylbenzene from the high shear product stream, wherein said linear alkylbenzene is formed at a temperature in the range of from about 0° C. to about 60° C. 2. The method of claim 1 further comprising contacting the aromatic stream with a catalyst before (a), contacting the high shear product with a catalyst after (b), or both. 3. The method of claim 1 further comprising combining a catalyst with at least one selected from the group consisting of the one or more olefins, the aromatic stream, the reactant stream and the high shear product stream. 4. The method of claim 2 wherein the catalyst comprises a Lewis acid. 5. The method of claim 1 wherein the linear alkylbenzene comprises dodecylbenzene. 6. The method of claim 1 further comprising introducing the high shear product to a fluid or fixed bed containing an alkylation catalyst. 7. The method of claim 3, wherein the catalyst is selected from the group consisting of aluminum halides, titanium halides, zirconium halides, iron halides, vanadium halides, chromium halides, and combinations thereof. 8. The method of claim 1 wherein the linear alkylbenzene has the formula: wherein R is an alkyl group having from 1 to 20 carbon atoms and R may be branched or unbranched. 9. The method of claim 1 wherein the olefin comprises from 2 to 10 carbon atoms. 10. The method of claim 1 wherein the aromatic stream comprises at least one selected from the group consisting of benzene, toluene, phenol, aniline, xylene and ethylbenzene. 11. The method of claim 1 wherein the high shear product stream comprises a dispersion of olefin-containing bubbles. 12. The method of claim 11 wherein the olefin-containing bubbles have an average bubble diameter of less than about 5 μm. 13. The method of claim 11 wherein the olefin-containing bubbles have a submicrometer average bubble diameter. 14. The method of claim 1 wherein (c) comprises stripping. 15. The method of claim 1 further comprising recycling at least a portion of the high shear product stream to the high shear device, introducing at least a portion of the high shear product stream into another high shear device, or both. 16. The method of claim 1 wherein the high shear device comprises at least two generators. 17. The method of claim 3 wherein the catalyst is selected from the group consisting of hydrofluoric acid and aluminum chloride. 18. The method of claim 1 wherein (b) comprises subjecting the reactant stream to high shear mixing at a tip speed of at least about 40 m/s.