Embodiments of the present disclosure include a catalyst for the conversion of CO and/or hydrocarbons in an exhaust stream including a Sn compound selected from the group consisting of a binary composition comprising Sn and Ti, a ternary composition comprising Sn, Ti and Zr, and mixtures of any ther
Embodiments of the present disclosure include a catalyst for the conversion of CO and/or hydrocarbons in an exhaust stream including a Sn compound selected from the group consisting of a binary composition comprising Sn and Ti, a ternary composition comprising Sn, Ti and Zr, and mixtures of any thereof. In those embodiments, the binary composition may include Sn(X)Ti(y)O2, wherein x+y=1, 0.85y0. In other embodiments of the present disclosure, the Sn compound includes a ternary composition including Sn(a)Ti(b)Zr(c)O2, wherein a is 0.25, b is 0.25 and c is 0.5. Certain embodiments of this disclosure include a method for the conversion of CO in an exhaust stream, including contacting an exhaust stream containing CO with the catalyst described above containing a Sn compound. In other embodiments, the exhaust stream includes hydrocarbons.
대표청구항▼
1. A method for the conversion of CO in an exhaust stream, comprising: contacting an exhaust stream containing CO with a catalyst, the catalyst made from the addition of a Sn compound is a ternary composition comprising Sn, Ti and Zr, wherein the ternary composition comprises Sn(a)Ti(b)Zr(c)O2, wher
1. A method for the conversion of CO in an exhaust stream, comprising: contacting an exhaust stream containing CO with a catalyst, the catalyst made from the addition of a Sn compound is a ternary composition comprising Sn, Ti and Zr, wherein the ternary composition comprises Sn(a)Ti(b)Zr(c)O2, wherein a is 0.25, b is 0.25 and c is 0.5. 2. The method of claim 1, wherein the ternary composition comprises a srilankite crystal phase. 3. A method for the conversion of CO in an exhaust stream, comprising: contacting an exhaust stream containing CO with a catalyst, the catalyst comprising a Sn compound selected from the group consisting of a binary composition comprising Sn and Ti, and a ternary composition comprising Sn, Ti and Zr, and mixtures of any thereof, wherein the Sn compound comprises a composition defined by a region of a phase diagram between Zr0.5Sn0.25Ti0.25O2 and, Sn1-xTixO2, where x is greater than or equal to 0 and less than 0.85; the catalyst further comprising a catalyst component selected from the group consisting of Pt, Pd, one or more base metals, and combinations of any thereof, wherein the base metal is selected from the group consisting of Cu, Fe, Ni, W, V, Cr, Mn, Co, and mixtures of any thereof. 4. A method for the conversion of CO in an exhaust stream according to claim 3, wherein the binary composition comprises Sn(x)Ti(y)O2, wherein x+y=1, 0.85>y>0. 5. The method of claim 4, wherein 0.5>y>0.05. 6. The method of claim 4, wherein the binary composition comprises a rutile crystal phase. 7. The method of claim 3, wherein x is greater than or equal to 0.05 and less than 0.85. 8. The method of claim 3, wherein the Sn compound comprises a composition defined by a region of a phase diagram between Zr0.5Sn0.25T0.25O2 and rutile Sn1-x,TixO2 where 0.05x>0.05. 18. A method for the conversion of CO in an exhaust stream, comprising: contacting an exhaust stream containing CO with a catalyst, the catalyst comprising a Sn compound selected from the group consisting of a binary composition comprising Sn and Ti, and a ternary composition comprising Sn, Ti and Zr, and mixtures of any thereof, wherein the catalyst further comprises a zeolite. 19. The method of claim 18, wherein the zeolite is selected from the group consisting of ZSM-5, ZSM-11, ZSM-12, ZSM-18, ZSM-23, MCM-zeolites, mordenite, faujasite, ferrierite, zeolite beta, and mixtures thereof.
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이 특허에 인용된 특허 (5)
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