초록 ▼

The present invention relates to a process for producing a multilayer film comprising at least one polyethylene (except high pressure polyethylene) and polypropylene layer, wherein the adhesion between the polyethylene and polypropylene is enhanced without the use of any tie layer by processing the

The present invention relates to a process for producing a multilayer film comprising at least one polyethylene (except high pressure polyethylene) and polypropylene layer, wherein the adhesion between the polyethylene and polypropylene is enhanced without the use of any tie layer by processing the film with a freezing time of less than ten seconds.

대표청구항 ▼

1. A process for producing a multi-layer film or sheet containing at least one polyethylene layer adjacent to at least one polypropylene layer comprising: feeding polypropylene to a first extruder of an coextrusion film unit;feeding polyethylene to a second extruder of the coextrusion film unit;coex

1. A process for producing a multi-layer film or sheet containing at least one polyethylene layer adjacent to at least one polypropylene layer comprising: feeding polypropylene to a first extruder of an coextrusion film unit;feeding polyethylene to a second extruder of the coextrusion film unit;coextruding the polypropylene and the polyethylene through a die to form a molten extrudate;blowing the molten extrudate into a film; andcooling the film to form a multi-layer film, wherein a freezing time of the extrudate is less than 10 seconds and the polyethylene is not a low density polyethylene produced by a high pressure polymerisation process,wherein the polyethylene is produced with a metallocene catalyst having the general formula: R(THI)2MQZ-2 wherein THI is a tetrahydrogenated indenyl group which may be substituted or not, R is a substituted or unsubstituted C1-C4 alkylidene radical, a dialkyl germanium, a dialkyl silicon, a diaryl silicon, a di-alkoxysilane, a diphenoxysilane, or an alkyl phosphine or amine radical bridging two tetrahydrogenated indenyl groups, Q is a hydrocarbyl radical, hydrocarboxy radical having 1-20 carbon atoms or halogen and can be the same or different from each other, M is a group 4, 5 or 6 transition metal, and Z is the valence of the transition metal. 2. The process of claim 1, wherein the freezing time of the extrudate is less than 9 seconds. 3. The process of claim 1, wherein the freezing time of the extrudate is less than 8 seconds. 4. The process of claim 1, wherein the freezing time of the extrudate is less than 7 seconds. 5. The process of claim 1, wherein the freezing time of the extrudate is less than 6 seconds. 6. The process of claim 1, wherein M is a group IVb transition metal. 7. The process of claim 1, wherein M is zirconium. 8. The process of claim 1, wherein R is a substituted or unsubstituted C1-C4 alkylidene radical. 9. Films or sheets obtainable by the process of claim 1.