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Systems and methods of manufacturing wafers are disclosed using a low EPD crystal growth process and a wafer annealing process are provided resulting in III-V/GaAs wafers that provide higher device yields from the wafer. In one exemplary implementation, there is provided a method of manufacturing a

Systems and methods of manufacturing wafers are disclosed using a low EPD crystal growth process and a wafer annealing process are provided resulting in III-V/GaAs wafers that provide higher device yields from the wafer. In one exemplary implementation, there is provided a method of manufacturing a group III based material with a low etch pit density (EPD). Moreover, the method includes forming polycrystalline group III based compounds, and performing vertical gradient freeze crystal growth using the polycrystalline group III based compounds. Other exemplary implementations may include controlling temperature gradient(s) during formation of the group III based crystal to provide very low etch pit density.

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1. A method of manufacturing a 6 inch diameter gallium arsenide wafer with a low etch pit density (EPD), the method comprising: performing a vertical gradient freeze (VGF) crystal growth process to grow a GaAs ingot, including: providing a crucible containing a seed crystal, GaAs raw material, and B

1. A method of manufacturing a 6 inch diameter gallium arsenide wafer with a low etch pit density (EPD), the method comprising: performing a vertical gradient freeze (VGF) crystal growth process to grow a GaAs ingot, including: providing a crucible containing a seed crystal, GaAs raw material, and B2O3 material, in an ampoule;providing a solid carbon substance in a lower region of the ampoule outside the crucible;sealing under vacuum the ampoule containing the solid carbon substance and the crucible;heating the sealed ampoule in a controlled manner causing the GaAs raw material to melt, the heat interacting with the solid carbon substance to produce a carbon gas which interacts with the GaAs melt through the B2O3 material;controlling a temperature gradient at a melt/crystal interface during the vertical gradient freeze crystal growth wherein the temperature gradient at the melt/crystal interface is between about 0.1 to about 2 degrees Celsius;controlling a shape of the melt/crystal interface during the vertical gradient freeze crystal growth wherein the shape is concave or convex to a melt front at no more than about ±2 mm;controlling a crystallization velocity during the vertical gradient freeze crystal growth wherein the crystallization velocity is between about 2 and about 16 mm/hour;obtaining a gallium arsenide 6 inch diameter wafer from the GaAs ingot;performing an annealing process on the gallium arsenide wafer using a single step anneal, wherein the annealing process comprises controlling a heating rate during the annealing between 900 to 1050 degrees Celsius over 10 to 48 hours, as well as controlling a cooling rate during the annealing wherein the cooling rate is to room temperature in 6 to 24 hours, and removing a portion of the surface of the gallium arsenide wafer, such that the annealing and the surface removal steps provide gallium arsenide crystals having less than a total of 50 light point defects, and a light point defect density of less than about 1 per square centimeter per wafer, with a particle size of equal to or greater than about 0.3 micrometers;wherein, as a result of a combination of the vertical gradient steps, the crystallization control steps and the annealing process, gallium arsenide crystals are reproducibly provided having an etch pit density that is achieved without use of contact or external gas source supplied doping techniques and is less than 600 per square centimeter. 2. A method for manufacture a 6 inch diameter gallium arsenide wafer with a low etch pit density (EPD), the method comprising: forming polycrystalline gallium based compounds; andperforming vertical gradient freeze (VGF) crystal growth to grow a GaAs ingot using the polycrystalline gallium based compounds, wherein the step of performing comprises: providing a crucible containing a seed crystal, GaAs raw material, and B2O3 material, in an ampoule;providing a solid carbon substance in a lower region of the ampoule outside the crucible;sealing under vacuum the ampoule containing the solid carbon substance and the crucible;heating the sealed ampoule in a controlled manner causing the GaAs raw material to melt, the heat interacting with the solid carbon substance to produce a carbon gas which interacts with the GaAs melt through the B2O3 material;controlling a temperature gradient at a melt/crystal interface during the vertical gradient freeze crystal growth wherein the temperature gradient at the melt/crystal interface is between about 0.1 to about 2 degrees Celsius;controlling a shape of the melt/crystal interface during the vertical gradient freeze crystal growth wherein the shape is concave or convex to a melt front at no more than about ±2 mm,controlling a crystallization velocity during the vertical gradient freeze crystal growth wherein the crystallization velocity is between about 2 and about 16 mm/hour;controlling melt/crystal interface during formation of the gallium based crystal such that the gallium based crystal has an etch pit density of less than about 600 per square centimeter;obtaining a polycrystalline gallium arsenide substrate from the GaAs ingot;annealing the polycrystalline gallium arsenide based substrate using a single step annealing process, wherein the annealing process comprises controlling a heating rate during the annealing between 900 to 1050 degrees Celsius over 10 to 48 hours, as well as controlling a cooling rate during the annealing wherein the cooling rate is to room temperature in 6 to 24 hours; andremoving a portion of the surface of the polycrystalline gallium based substrate to form a polycrystalline gallium arsenide based substrate having a light point defect density of less than about 1 per square centimeter per polycrystalline gallium arsenide based substrate with a particle size of equal to or greater than about 0.3 micrometers;wherein, as a result of the VGF crystal growth, the annealing and the surface removal steps, gallium arsenide crystals having less than a total of 50 light point defects are achieved.