A polyethylene production process, comprising contacting ethylene and a polymerization catalyst under suitable reaction conditions to yield a polymerization product stream, separating a light gas stream from the polymerization product stream, wherein the light gas stream comprises ethane and unreact
A polyethylene production process, comprising contacting ethylene and a polymerization catalyst under suitable reaction conditions to yield a polymerization product stream, separating a light gas stream from the polymerization product stream, wherein the light gas stream comprises ethane and unreacted ethylene, contacting the light gas stream with an absorption solvent system, wherein at least a portion of the ethylene from the light gas stream is absorbed by the absorption solvent system, removing unabsorbed gases of the light gas stream from contact with the absorption solvent system to form a waste gas stream, and recovering ethylene from the absorption solvent system.
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1. A polyethylene production process, comprising: contacting ethylene and a polymerization catalyst under suitable reaction conditions to yield a polymerization product stream;separating a light gas stream from the polymerization product stream, wherein the light gas stream comprises ethane and unre
1. A polyethylene production process, comprising: contacting ethylene and a polymerization catalyst under suitable reaction conditions to yield a polymerization product stream;separating a light gas stream from the polymerization product stream, wherein the light gas stream comprises ethane and unreacted ethylene;contacting the light gas stream with an absorption solvent system, wherein the absorption solvent system comprises copper chloride, aniline, and N-methylpyrrolidone, and wherein at least a portion of the unreacted ethylene from the light gas stream is absorbed by the absorption solvent system;removing unabsorbed gases of the light gas stream from contact with the absorption solvent system to form a waste gas stream;recovering unreacted ethylene from the absorption solvent system to yield recovered ethylene; andcontacting the recovered ethylene and the polymerization catalyst,wherein the light gas stream further comprises isobutane and wherein at least a portion of the isobutane from the light as stream is absorbed by the absorption solvent system. 2. The process of claim 1, wherein the contacting the light gas stream with the absorption solvent system comprises pressurizing the light gas stream and the absorption solvent system to a pressure in a range of from about 50 psige to about 250 psig. 3. The process of claim 1. whwerein the recovering unreacted ethylene from the absorption solvent system comprises depressurizing the absorption solvent system having absorbed unreacted ethylene to a pressure in a range of from about 5 psig to about 30 psig. 4. The process of claim 1, further comprising combusting the waste gas stream, wherein the waste gas stream comprises ethane. 5. The process of claim 4, wherein the waste gas steam comprises less than 5% unreacted ethylene by weight. 6. The process of claim 1, wherein the contacting the light gas stream with the absorption solvent system occurs at a temperature within the range of from about 0° C. to about 250° C. 7. A polyethylene production process, comprising: contacting ethylene and a polymerization catalyst under suitable reaction conditions to yield a polymerization product stream;separating a light gas stream from the polymerization product stream, wherein the light gas stream comprises ethane and unreacted ethylene;contacting the light as stream with an absorption solvent system, wherein the absorption solvent system comprises copper chloride, aniline, and N-methylpyrolidone, and wherein at least a portion of the unreacted ethylene from the light gas stream is absorbed by the absorption solvent system;removing unabsorbed gases of the light gas stream from contact with the absorption solvent system to form a waste gas stream;recovering unreacted ethylene from the absorption solvent system to yield recovered ethylene; andcontacting the recovered ethylene and the polymerization catalyst; andfurther comprising removing at least a portion of elemental oxygen or oxygen-containing compounds from the light gas stream before contacting the light gas stream with the absorption solvent system. 8. The process of claim 7, wherein recovering unreacted ethylene from the absorption solvent system comprises depressurizing the absorption solvent system having absorbed unreacted ethylene to a pressure in a range of from about 5 psig to about 30 psig. 9. The process of claim 7, wherein the contacting the light gas stream with the absorption solvent system occurs at a temperature within the range of from about 0° C. to about 250° C. 10. The process of claim 7, wherein the contacting the light gas stream with the absorption solvent system comprises pressurizing the light gas stream and the absorption solvent system to a pressure in a range of from about 50 psig to about 250 psig. 11. The process of claim 7, further comprising combusting the waste gas stream, wherein the waste gas stream comprises ethane. 12. The process of claim 11, wherein the waste gas stream comprises less than 5% unreacted ethylene by weight. 13. A polyethylene production process, comprising: contacting ethylene and a polymerization catalyst in a polymerization reactor under suitable reaction conditions to yield a polymerization product stream;separating a light gas stream from the polymerization product stream, wherein the light gas stream comprises ethane and unreacted ethylene;contacting the light gas stream with an absorption solvent system in an absorption vessel, wherein at least a portion of the unreacted ethylene from the light gas stream is absorbed by the absorption solvent system to yield a composition comprising a complex of the absorption solvent system and unreacted ethylene; andremoving the unabsorbed gases of the light gas stream from contact with the absorption solvent system; andfurther comprising recovering unreacted ethylene from the absorption solvent system within the absorption vessel. 14. The process of claim 13, wherein the absoption solvent system comprises copper chloride, aniline, and N-methylpyrrolidone. 15. The process of claim 13, wherein the contacting the light gas stream with the absorption solvent system comprises pressurizing the absorption vessel to a pressure in a range of from about 50 psig to about 250 psig. 16. The process of claim 13, wherein the recovering unreacted ethylene from the absoption solvent system comprises depressurizing the absorption vessel to a pressure in a range of from about 5 psig to about 30 psig. 17. The process of claim 13, wherein the contacting the light gas stream with the absorption solvent system in the absorption vessel occurs at a temperature within the range of from about 0° C. to about 250° C. 18. A polyethylene production process, comprising: contacting ethylene and a polymerization catalyst in a polymerization reactor under suitable reaction conditions to yield a polymerization product stream;separating a light gas stream from the polymerization product stream, wherein the light gas stream comprises ethane and unreacted ethylene;contacting the light gas stream with an absorption solvent system in an absorption vessel, wherein at least a portion of the unreacted ethylene from the light gas stream is absorbed by the absorption solvent system to yield a composition comprising a complex of the absorption solvent system and unreacted ethylene; andremoving the unabsorbed gases of the light gas stream from contact with the absorption solvent system; andfurther comprising removing at least a portion of elemental oxygen or oxygen-containing compounds from the light gas stream before introducing the light gas stream into the absorption vessel. 19. The process of claim 18, wherein the contacting the light gas stream with the absorption solvent system in the absorption vessel occurs at a temperature within the range of from about 0° C. to about 250° C. 20. A polyethylene production system, comprising: a feed stream comprising ethylene, wherein the feed stream is characterized by introduction into a polymerization reactor;a polymerization product stream, wherein the polymerization product stream is characterized by emission from the polymerization reactor and introduction into a separator;a light gas stream comprising unreacted ethylene, wherein the light gas stream is characterized by emission from the separator, the light gas stream having been separated from the polymerization product stream, wherein the light gas stream is characterized by introduction into an absorption reactor comprising an absorption solvent system;an absorbent-ethylene conjugant, wherein the absorbent-ethylene conjugant is characterized by formation within the absorption reactor by absorption of at least a portion of the unreacted ethylene by the absorption solvent system; anda waste gas stream comprising ethane, wherein the waste gas stream is characterized by emission from the absorption reactor, wherein the waste gas stream comprises components of the light gas stream that are not absorbed by the absorption solvent system; andfurther comprising a recovered unreacted ethylene stream, wherein the recovered unreacted ethylene stream is characterized by emission from the absorption reactor and reintroduction into the polymerization reactor. 21. The system of claim 20, wherein recovery of the recovered unreacted ethylene from the absorbent-ethylene conjugant occurs via a pressure reduction. 22. The system of claim 20, wherein the absorption solvent system comprises copper chloride, aniline, and N-methylpyrrolidone. 23. A polyethylene production system, comprising: a polymerization reactor, wherein the polymerization reactor is configured to receive a feed stream comprising ethylene, and wherein the polymerization reactor is configured to emit a polymerization product stream;a separator, wherein the separator is configured to receive the polymerization product stream and to emit a light gas stream comprising unreacted ethylene, wherein the light gas stream has been separated from the polymerization product stream; andan absorption reactor comprising an absorption solvent system, wherein the absorption reactor is configured to receive the light gas stream, to form an absorbent-ethylene conjugant by absorption of at least a portion of the unreacted ethylene by the absorption solvent system, and to emit a waste gas stream comprising ethane, wherein the waste gas stream comprises components of the light gas stream that are not absorbed by the absorption solvent system, and wherein the absorption reactor is further configured to emit a recovered unreacted ethylene stream, and wherein the polymerization reactor is further configured to receive the recovered unreacted ethylene stream. 24. The system of claim 23, wherein the recovered unreacted eethylene is recovered from the absorbent-ethylene conjugant via a pressure reduction. 25. The system of claim 23, wherein the recovered unreacted ethylene is recovered from the absorbent-ethylene conjugant via a pressure reduction. 26. The system of claim 23, wehrein the absorption solvent system comprises copper chloride, aniline, and N-methylpyrrolidone. 27. A polyethylene production process, comprising: contacting ethylene and a polymerization catalyst under suitable reaction conditions to yield a polymerization product stream;separating a light gas stream from the polymerization product stream, wherein the light gas stream comprises ethane and unreacted ethylene;removing at least a portion of elemental oxygen or oxygen-containing compounds from the light gas stream before contacting the light gas stream with an absorption solvent system;contacting the light gas stream with the absorption solvent system, wherein at least a portion of the unreacted ethylene from the light gas stream is absorbed by the absorption solvent system;removing unabsorbed gases of the light gas stream from contact with the absorption solvent system to form a waste gas stream;recovering unreacted ethylene from the absorption solvent system to yield recovered ethylene; andcontacting the recovered ethylene and the polymerization catalyst. 28. The process of claim 27, wherein the contacting the light gas stream with the absorption solvent system occurs at a temperature within the range of from about 0° C. to about 250° C. 29. The process of claim 27, wherein the absorption solvent system comprises copper chloride, aniline, and N-methylpyrrolidone. 30. The process of claim 29, wherein the contacting the light gas stream with the absorption solvent system comprises pressurizing the light gas stream and the absorption solvent system to a pressure in a range of from about 50 psig to about 250 psig.
Mehra Yuv R. (The Woodlands TX) Stodghill Robert H. (Houston TX), Absorption process for rejection of reactor byproducts and recovery of monomers from waste gas streams in olefin polymer.
Soon-Haeng Cho KR; Sang-Sup Han KR; Jong-Nam Kim KR; Kuck-Tack Chue KR; Venkateswarlu Choudary Nettem IN; Kumar Brakash IN, Adsorbents and methods for the separation of ethylene and propylene and/or unsaturated hydrocarbons from mixed gases.
Hottovy John D. (Bartlesville OK) Lawrence Frederick C. (Bartlesville OK) Lowe Barry W. (Bartlesville OK) Fangmeier James S. (Bartlesville OK), Apparatus and method for producing ethylene polymer.
Cymbaluk Ted H. (Seabrook TX) Nowack Gerhard P. (Bartlesville OK) Johnson Marvin M. (Bartlesville OK), Copper (I) carboxylate-containing olefin complexing reagents.
Cymbaluk Ted H. (Seabrook TX) Nowack Gerhard P. (Bartlesville OK) Johnson Marvin M. (Bartlesville OK), Copper (I) carboxylate-containing olefin complexing reagents.
Yang, Qing; Jayaratne, Kumudini C.; Jensen, Michael D.; McDaniel, Max P.; Martin, Joel L.; Thorn, Matthew G.; Lanier, Jerry T.; Crain, Tony R., Dual metallocene catalysts for polymerization of bimodal polymers.
Hottovy John D. ; Hensley Harvey D. ; Przelomski David J. ; Cymbaluk Teddy H. ; Franklin ; III Robert K. ; Perez Ethelwoldo P., High solids slurry polymerization.
Jenkins ; III John M. (So. Charleston WV) Jones Russell L. (Chapel Hill NC) Jones Thomas M. (So. Charleston WV) Beret Samil (Danville CA), Method for fluidized bed polymerization.
Cymbaluk Ted H. (Bartlesville OK) Tabler Donald C. (Fort Collins CO) Johnson Marvin M. (Bartlesville OK) Nowack Gerhard P. (Bartlesville OK), Method for preparing olefin complexing reagents and use thereof.
Cymbaluk Ted H. (Bartlesville OK) Tabler Donald C. (Fort Collins CO) Johnson Marvin M. (Bartlesville) Nowack Gerhard P. (Bartlesville OK), Method for preparing olefin complexing reagents and use thereof.
Hanson Donald O. (Bartlesville OK), Process and apparatus for separating diluents from solid polymers utilizing a two-stage flash and a cyclone separator.
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