Hydroprocessing bulk catalyst and methods of making thereof
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01J-031/00
B01J-021/00
B01J-027/049
B01J-027/24
B01J-037/20
출원번호
US-0625394
(2009-11-24)
등록번호
US-8420565
(2013-04-16)
발명자
/ 주소
Mironov, Oleg
Kuperman, Alexander E.
출원인 / 주소
Chevron U.S.A. Inc.
인용정보
피인용 횟수 :
11인용 특허 :
3
초록▼
A hydroprocessing bulk catalyst is provided. A process to prepare hydroprocessing bulk catalysts is also provided. The hydroprocessing catalyst has the formula (Rp)i(Mt)a(Lu)b(Sv)d(Cw)e(Hx)f(Oy)g(Nz)h, wherein M is at least at least a “d” block element metal; L is also at least a “d” block element m
A hydroprocessing bulk catalyst is provided. A process to prepare hydroprocessing bulk catalysts is also provided. The hydroprocessing catalyst has the formula (Rp)i(Mt)a(Lu)b(Sv)d(Cw)e(Hx)f(Oy)g(Nz)h, wherein M is at least at least a “d” block element metal; L is also at least a “d” block element metal, but different from M; t, u, v, w, x, y, z representing the total charge for each of the components (M, L, S, C, H, O and N, respectively); R is optional and in one embodiment, R is a lanthanoid element metal; 0=i=1; pi+ta+ub+vd+we+xf+yg+zh=0; 0b; 0b/a=5; 0.5(a+b)=d=5(a+b); 0e=11(a+b); 0f=7(a+b); 0g=5(a+b); 0h=2(a+b). The catalyst has an X-ray powder diffraction pattern with at least three diffractions peak located at 2-θ angles of greater than 25°. In one embodiment, the catalyst is prepared by forming at least a sulfided catalyst precursors from at least two “d” block element metals; and mixing the catalyst precursor with a hydrocarbon compound to form the hydroprocessing catalyst composition. In another embodiment, the catalyst is prepared by the thermal decomposition of an oil dispersible sulfur containing organic metal precursor upon contact with a hydrocarbon oil, generating a slurry catalyst. In yet another embodiment, the catalyst is prepared from an in-situ or ex-situ sulfidation of “d block element metal precursors in a solvent carrier.
대표청구항▼
1. A process for preparing a catalyst composition comprising: i) providing at least two metal precursors of different element metals, with at least one of the metal precursors being an oil dispersible sulfur containing organic compound, wherein at least two metal precursors of the different element
1. A process for preparing a catalyst composition comprising: i) providing at least two metal precursors of different element metals, with at least one of the metal precursors being an oil dispersible sulfur containing organic compound, wherein at least two metal precursors of the different element metals are selected from nickel naphthenate, titanium dithiocarbamate, titanyl sulfate, zinc alkyl dithiocarbamate, zinc alkyl phosphorodithioate, zinc mercaptobenzothiazole, zinc dibenzyldithiocarbamate, copper dithiocarbamate, manganese acetate, zinc dialkyldithiophosphate, and combinations thereof; andiii) combining the metal precursors with a hydrocarbon compound to transform the precursors into a catalyst composition having formula (Rp)i(Mt)a(Lu)b(Sv)d(Cw)e(Hx)f(Oy)g(Nz)h, whereinR is optional and is at least a lanthanoid element metal or an alkaline earth metal;M is at least an element metal selected from the group consisting of titanium, chromium, iron, cobalt, nickel, copper, zinc and manganese;L is at least an element metal different from the element metal M and is selected from the group consisting of titanium, chromium, iron, coal, nickel, copper, and zinc;0<=i<=1,0
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이 특허에 인용된 특허 (3)
Chen,Kaidong; Reynolds,Bruce E., Highly active slurry catalyst composition.
Jiao, Ling; Chabot, Julie; Nguyen, Joseph V.; Dunckley, Christopher Paul; Yang, Shuwu; Maris, Erin P.; Mironov, Oleg; Reynolds, Bruce Edward; Kuperman, Alexander E., Hydroprocessing catalysts and methods for making thereof.
Mironov, Oleg; Kuperman, Alexander E.; Bhaduri, Rahul Shankar; Chabot, Julie; Yang, Shuwu; Jiao, Ling; Nguyen, Joseph V.; Reynolds, Bruce Edward, Hydroprocessing catalysts and methods for making thereof.
Mironov, Oleg; Kuperman, Alexander E.; Chabot, Julie; Yang, Shuwu; Nguyen, Joseph V.; Jiao, Ling; Reynolds, Bruce Edward; Brait, Axel; Kwik, Kenneth; Kotun, Modinat, Hydroprocessing catalysts and methods for making thereof.
Nguyen, Joseph V.; Chabot, Julie; Jiao, Ling; Dunckley, Christopher Paul; Yang, Shuwu; Maris, Erin P.; Mironov, Oleg; Reynolds, Bruce Edward; Kuperman, Alexander E., Hydroprocessing catalysts and methods for making thereof.
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