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A catalyst composition is provided that includes a catalytic metal secured to a substrate, and the substrate is mesoporous and has pores that are templated. A catalyst composition includes a catalytic metal secured to a mesoporous substrate. The mesoporous substrate is a reaction product of a reacti

A catalyst composition is provided that includes a catalytic metal secured to a substrate, and the substrate is mesoporous and has pores that are templated. A catalyst composition includes a catalytic metal secured to a mesoporous substrate. The mesoporous substrate is a reaction product of a reactive solution, a solvent, a modifier, and a templating agent. A method for controlling nitrous oxide emissions including the catalyst composition comprising introducing a regeneration fuel into an exhaust stream upstream relative to the catalyst composition and heating the exhaust stream upstream relative to the catalyst composition. When the regeneration fuel is introduced the air/fuel ratio λ of an air/fuel mixture of a lean burn exhaust is greater than 1.

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1. A method of controlling nitrous oxide emissions in an exhaust emitted from a lean internal combustion engine that operates using fuel with a lean air/fuel mixture and produces a lean air/fuel mixture in the exhaust having an air/fuel ratio λ greater than 1, comprising: providing a catalytic conve

1. A method of controlling nitrous oxide emissions in an exhaust emitted from a lean internal combustion engine that operates using fuel with a lean air/fuel mixture and produces a lean air/fuel mixture in the exhaust having an air/fuel ratio λ greater than 1, comprising: providing a catalytic converter comprising a catalytic metal secured to a substrate that has templated pores within an exhaust stream produced by the internal combustion engine, wherein sulfur species from the exhaust deposit on the catalytic converter;introducing into the exhaust stream, upstream from the catalytic converter a predetermined amount of a regeneration fuel for a resident time period in order to oxidize the sulfur species and de-sulfate the catalytic converter until the air/fuel ratio λ of the exhaust lean air/fuel mixture is greater than 1 after introduction of the regenerating fuel; andheating the exhaust upstream relative to the catalytic converter to a temperature above a range of exhaust temperatures over which the internal combustion operates thereby heating the catalytic metal and the substrate. 2. The method of claim 1, further comprising providing a diesel particulate filter upstream or downstream relative to the catalytic converter. 3. The method of claim 2, further comprising regenerating the diesel particulate filter by heating the diesel particulate filter. 4. The method of claim 3, wherein the step of regenerating the diesel particulate filter comprises simultaneously introducing the regeneration fuel for desulfation of the catalytic converter and heating the catalytic converter. 5. The method of claim 4, wherein the step of regenerating the diesel particulate filter comprises heating the exhaust upstream relative to the diesel particulate filter. 6. The method of claim 1, wherein the regeneration fuel is one of diesel, ultra low sulfur diesel fuel, biodiesel, gasoline, kerosene, ethanol or any combination thereof. 7. The method of claim 6, wherein a sufficient amount of ultra low sulfur diesel is introduced so that the composition of exhaust includes more than about 1700 ppm of the ultra low sulfur diesel fuel. 8. The method of claim 1, wherein the step of heating the exhaust and the catalytic converter comprises heating the exhaust to a temperature of about 650° C. 9. The method of claim 1, further comprising the step of monitoring a parameter associated with the exhaust stream indicating that the catalytic converter needs to be desulfated. 10. The method of claim 9, wherein the monitoring step comprises monitoring the level of nitrous oxide emissions of the catalytic converter. 11. The method of claim 1, wherein the steps of introducing the regeneration fuel and heating the exhaust stream are performed at predetermined timed intervals. 12. The method of claim 1, wherein the steps of introducing the regeneration fuel and heating the exhaust stream are performed in response to detecting a parameter associated with the exhaust stream indicating that the catalytic converter requires desulfation. 13. A system for controlling nitrous oxide emissions exhausted from a lean burn internal combustion engine that produces a lean air/fuel mixture in an exhaust having an air/fuel ratio λ greater than 1, comprising: a catalytic converter comprising a catalytic metal secured to a substrate that has templated pores that is positioned within an exhaust stream produced by the internal combustion engine and the catalytic converter is positioned downstream relative to the internal combustion engine and wherein sulfur species from the exhaust deposit on the catalytic converter;an injector mechanism for introducing a regeneration fuel into the exhaust stream upstream relative to the catalytic converter to oxidize the sulfur species and de-sulfate the catalytic converter until the air/fuel ratio λ of the exhaust lean air/fuel mixture is greater than 1 after introduction of the regenerating fuel; and,a heat source positioned upstream relative to the catalytic converter that is activated when the injector mechanism is introducing the regeneration fuel into the exhaust stream to heat the exhaust stream above a range of exhaust temperatures over which the internal combustion engine operates thereby heating the catalytic metal and the substrate. 14. The system of claim 13, further comprising a diesel particulate filter positioned in the exhaust stream upstream relative to the catalytic converter. 15. The system of claim 14, wherein the heat source is positioned upstream relative to the diesel particulate filter and the injector mechanism is positioned between the diesel particulate filter and the catalytic converter. 16. The system of claim 14, wherein the heat source is positioned between the diesel particulate filter. 17. The system of claim 15, wherein the heat source and injector mechanism are activated to simultaneously regenerate the diesel particulate filter and desulfate the catalytic converter. 18. The system of claim 13, further comprising one or more controllers for activating the heat source and the injector mechanism. 19. The system of claim 18, further comprising a detector for detecting an exhaust stream parameter indicating that the catalytic converter requires desulfation and the detector transmits signals indicative of the parameter wherein the controller activates the heat source and injector mechanism for desulfation of the catalytic converter responsive to signals indicating that desulfation is required. 20. The system of claim 13, wherein the heat source and the injector mechanism are activated at predetermined time intervals over a resident time period. 21. The system of claim 13, wherein the regeneration fuel is an ultra low sulfur diesel, ethanol, kerosene or gasoline or a combination thereof. 22. The system of claim 13, wherein the catalytic metal comprises silver, gold, palladium or platinum. 23. The system of claim 22, wherein the substrate comprises alumina. 24. The system of claim 13, wherein the pores are periodically spaced. 25. The system of claim 13, wherein the pores have a periodicity in a range from about 50 Angstrom to about 130 Angstrom. 26. The system of claim 13, wherein the pores have an average diameter of less than 50 nanometers. 27. A method for desulfating a catalytic converter comprising a catalytic metal secured to a substrate that has templated pores and is disposed in an exhaust stream downstream relative to a lean burn internal combustion engine that produces a lean air/fuel mixture in the exhaust having an air/fuel ratio λ greater than 1, and wherein sulfur species from the exhaust deposit on the catalytic converter, the method comprising: introducing into the exhaust stream, upstream from the catalytic converter a predetermined amount of a regeneration fuel for a resident time period in order to oxidize the sulfur species and de-sulfate the catalytic converter wherein the air/fuel ratio λ of the exhaust lean air/fuel mixture does drop below 1 after introduction of the regenerating fuel, andheating the exhaust upstream relative to the catalytic converter to a temperature above a range of exhaust temperatures over which the internal combustion operates thereby heating the catalytic metal and the substrate. 28. The method of claim 27, further comprising providing a diesel particulate filter upstream or downstream relative to the catalytic converter. 29. The method of claim 28, further comprising regenerating the diesel particulate filter by heating the filter. 30. The method of claim 29, wherein the step of regenerating the diesel particulate filter, introducing the regeneration fuel for desulfation of the catalytic converter and heating the catalytic converter are performed simultaneously. 31. The method of claim 30, wherein the step of regenerating the diesel particulate filter comprises heating the exhaust upstream relative to the diesel particulate filter. 32. The method of claim 27, wherein the regeneration fuel is diesel, ultra low sulfur diesel fuel, biodiesel, gasoline, kerosene, ethanol or any combination thereof. 33. The method of claim 27, further comprising the step of monitoring a parameter associated with the exhaust stream indicating that the catalytic converter needs to be desulfated. 34. The method of claim 33, wherein the monitoring step comprises monitoring the level of nitrous oxide emissions of the catalytic converter.